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Shinozaki, Ayako*; Komatsu, Kazuki*; Kagi, Hiroyuki*; Fujimoto, Chikako*; Machida, Shinichi*; Sano, Asami; Hattori, Takanori
Journal of Chemical Physics, 148(4), p.044507_1 - 044507_8, 2017/01
Times Cited Count:9 Percentile:42.42(Chemistry, Physical)Pressure-response on the crystal structure of deuterated -glycine was investigated at room temperature, using powder and single-crystal X-ray diffraction, and powder neutron diffraction measurements under high pressure. No phase change was observed up to 8.7 GPa, although anisotropy of the lattice compressibility was found. Neutron diffraction measurements indicated the distance of the intermolecular DO bond along with the -axis increase with compression up to 6.4 GPa. The distance of another DO bond along with the -axis decreased with increasing pressure, and became the shortest intermolecular hydrogen bond above 3 GPa. In contrast, the lengths of the bifurcated N-DO and C-DO hydrogen bonds, which are formed between the layers of the -glycine molecules along the -axis, decreased significantly with increasing pressure. The decrease of the intermolecular distances resulted in the largest compressibility of the -axis, compared to the other two axes. Hirshfeld analysis suggested that the reduction of the void region size, rather than shrinkage of the strong N-DO hydrogen bonds, occurred with compression.
Komatsu, Kazuki*; Shinozaki, Ayako*; Machida, Shinichi*; Matsubayashi, Takuto*; Watanabe, Mao*; Kagi, Hiroyuki*; Sano, Asami; Hattori, Takanori
Acta Crystallographica Section B; Structural Science, Crystal Engineering and Materials (Internet), 71(1), p.74 - 80, 2015/02
Times Cited Count:19 Percentile:79.64(Chemistry, Multidisciplinary)Magnesium dichloride decahydrate (MgCl10HO) and its deuterated counterpart (MgCl10DO) are identified for the first time by in-situ powder synchrotron X-ray and spallation neutron diffraction. These substances are crystallized from a previously unidentified nanocrystalline compound, which originates from an amorphous state at low temperature. A combination of a recently developed autoindexing procedure and the charge-flipping method reveals that the crystal structure of MgCl 10HO consists of an ABCABC... sequence of Mg(HO) octahedra. The Cl anions and remaining water molecules unconnected to the Mg cations bind the octahedra, similar to other water-rich magnesium dichloride hydrates. The D positions in MgCl10DO, determined by the difference Fourier methods using the neutron powder diffraction patterns at 2.5 GPa, show the features such as bifurcated hydrogen bonds and tetrahedrally coordinated O atoms.
Moriyama, Shinichi; Kobayashi, Takayuki; Isayama, Akihiko; Terakado, Masayuki; Sawahata, Masayuki; Suzuki, Sadaaki; Yokokura, Kenji; Shimono, Mitsugu; Hasegawa, Koichi; Hiranai, Shinichi; et al.
Nuclear Fusion, 49(8), p.085001_1 - 085001_7, 2009/07
Times Cited Count:21 Percentile:61.72(Physics, Fluids & Plasmas)In the gyrotron development in JT-60U ECRF system, output power of 1.5 MW for 1 s has been achieved at 110 GHz. It is the world highest power oscillation 1 s. In addition to the carefully designed cavity and collector in view of thermal stress, an RF shield for the adjustment bellows, and a low-dielectric-loss DC break enabled this achievement. Power modulation technique by anode voltage control was improved to obtain high modulation frequency and 5 kHz has been achieved for NTM stabilizing experiments. Long pulse demonstration of 0.4 MW, 30 s injection to the plasma has been achieved with real time control of anode/cathode-heater. It has been confirmed that the temperature of cooled components were saturated and no evidence of damage were found. An innovative antenna having wide range of beam steering capability with linearly-moving-mirror concept has been designed for long pulse. Beam profile and mechanical strength analyses shows the feasibility of the antenna.
Moriyama, Shinichi; Kobayashi, Takayuki; Isayama, Akihiko; Terakado, Masayuki; Sawahata, Masayuki; Suzuki, Sadaaki; Yokokura, Kenji; Shimono, Mitsugu; Hasegawa, Koichi; Hiranai, Shinichi; et al.
Proceedings of 22nd IAEA Fusion Energy Conference (FEC 2008) (CD-ROM), 8 Pages, 2008/10
In the gyrotron development in JT-60U ECRF system, output power of 1.5 MW for 1 s has been achieved at 110 GHz. It is the world highest power oscillation 1 s. In addition to the carefully designed cavity and collector in view of thermal stress, an RF shield for the adjustment bellows, and a low-dielectric-loss DC break enabled this achievement. Power modulation technique by anode voltage control was improved to obtain high modulation frequency and 5 kHz has been achieved for NTM stabilizing experiments. Long pulse demonstration of 0.4 MW, 30 s injection to the plasma has been achieved with real time control of anode/cathode-heater. It has been confirmed that the temperature of cooled components were saturated and no evidence of damage were found. An innovative antenna having wide range of beam steering capability with linearly-moving-mirror concept has been designed for long pulse. Beam profile and mechanical strength analyses shows the feasibility of the antenna.
Yamasaki, Chisato*; Murakami, Katsuhiko*; Fujii, Yasuyuki*; Sato, Yoshiharu*; Harada, Erimi*; Takeda, Junichi*; Taniya, Takayuki*; Sakate, Ryuichi*; Kikugawa, Shingo*; Shimada, Makoto*; et al.
Nucleic Acids Research, 36(Database), p.D793 - D799, 2008/01
Times Cited Count:51 Percentile:71.25(Biochemistry & Molecular Biology)Here we report the new features and improvements in our latest release of the H-Invitational Database, a comprehensive annotation resource for human genes and transcripts. H-InvDB, originally developed as an integrated database of the human transcriptome based on extensive annotation of large sets of fulllength cDNA (FLcDNA) clones, now provides annotation for 120 558 human mRNAs extracted from the International Nucleotide Sequence Databases (INSD), in addition to 54 978 human FLcDNAs, in the latest release H-InvDB. We mapped those human transcripts onto the human genome sequences (NCBI build 36.1) and determined 34 699 human gene clusters, which could define 34 057 protein-coding and 642 non-protein-coding loci; 858 transcribed loci overlapped with predicted pseudogenes.
Suzuki, Sadaaki; Seki, Masami; Shinozaki, Shinichi; Sato, Fumiaki; Hiranai, Shinichi; Ishii, Kazuhiro*; Hasegawa, Koichi; Moriyama, Shinichi
JAEA-Technology 2007-055, 27 Pages, 2007/09
In the experiments featuring lower hybrid range of frequency (LHRF) system in JT-60U, carbon grills were attached to the plasma-facing part of the antenna in order to avoid the damage by the excessive heat load from the plasma. However some electric discharge traces were found there in the observation after the experiments. To avoid such discharges, improvements of the arc detector and the protection interlock by visible picture detection were tackled. In the arc detector, the amplification circuit was improved in order to obtain shorter response time and higher resolution of optical detection. Moreover, in visible picture detection, a new function of RF-on/off control utilizing PC image processing was added to distinguish the light of the arc from one of the plasma. This report summarizes improvement of the protection interlock device in a LHRF heating system.
Terakado, Masayuki; Shimono, Mitsugu; Sawahata, Masayuki; Shinozaki, Shinichi; Igarashi, Koichi; Sato, Fumiaki; Wada, Kenji; Seki, Masami; Moriyama, Shinichi
JAEA-Technology 2007-053, 28 Pages, 2007/09
The electron cyclotron heating (ECH) system at 110 GHz are injected to JT-60U plasmas with pulse modulation at dozens to hundreds of Hz in order to measure heat conductivity of the plasma to investigate plasma confinement. The JT-60U ECH system has a unique feature to realize the pulse modulation by controlling the anode voltage of the triode gyrotron without chopping the main acceleration voltage. The typical depth of the modulation is 80 % at the modulation frequency range of 12.2 Hz to 500 Hz. However in the JT-60SA, higher modulation frequency of some kHz will be required to stabilize neoclassical tearing mode (NTM). The modulation techniques have been investigated and the modulation frequency of 3.5 kHz with the modulation depth of 84 % has been achieved. The modulation frequency up to 3 kHz is available in the pulse widths of the practical operation. As a next step, replacement of the parts in the anode voltage divider circuit is planned to achieve higher modulation frequency.
Ishii, Kazuhiro; Seki, Masami; Shinozaki, Shinichi; Hasegawa, Koichi; Hiranai, Shinichi; Suzuki, Sadaaki; Sato, Fumiaki; Moriyama, Shinichi; Yokokura, Kenji
JAEA-Technology 2007-036, 30 Pages, 2007/07
The lower hybrid (LH) antenna in JT-60U has interaction with plasmas because it should be close to them in order to inject effectively radio frequency (RF) power into them. As a result, it has been a serious problem that the antenna mouth made of stainless steels was damaged due to excessive heat loads of plasmas and RF breakdowns. To solve the problem, a heat-resistant LH antenna was developed tipping carbon grills with fairly high heat resistance on the antenna mouth, and therefore reduction in damages on the mouth was expected. Power injection into plasmas was firstly performed with the heat-resistant antenna. RF conditioning was done carefully in the initial phase because RF breakdown due to outgassing from the grills might be occurred. After sufficient degassing was done through RF conditioning, RF power of about 1.6 MW 10 sec injection was successfully injected to plasmas. Moreover it was demonstrated that it had comparably high plasma current drive capability (about 1.6 10 A/W/m), required as a current drive LH antenna.
Seki, Masami; Moriyama, Shinichi; Shinozaki, Shinichi; Hasegawa, Koichi; Hiranai, Shinichi; Yokokura, Kenji; Shimono, Mitsugu; Terakado, Masayuki; Fujii, Tsuneyuki
Fusion Engineering and Design, 74(1-4), p.273 - 277, 2005/11
Times Cited Count:3 Percentile:24.22(Nuclear Science & Technology)no abstracts in English
Fujii, Tsuneyuki; Seki, Masami; Moriyama, Shinichi; Terakado, Masayuki; Shinozaki, Shinichi; Hiranai, Shinichi; Shimono, Mitsugu; Hasegawa, Koichi; Yokokura, Kenji; JT-60 Team
Journal of Physics; Conference Series, 25, p.45 - 50, 2005/00
The JT-60U electron cyclotron range of frequency (ECRF) is utilized to realize high performance plasma. Its output power is 4 MW at 110 GHz. By controlling the anode voltage of the gyrotron used in the JT-60U ECRF heating system, the gyrotoron output can be controlled. Then, the anode voltage controller was developed to modulate the injected power into plasmas. This low cost controller achieved the modulation frequency 12 - 500 Hz at 0.7 MW. This controller also extended the pulse width from 5s to 16 s at 0.5 MW. For these long pulses, temperature rise of the DC break made of Alumina ceramics is estimated. Its maximum temperature becomes 140 deg. From the analysis of this temperature rise, DC break materials should be changed to low loss materials for the objective pulse width of 30 s. The stabilization of neoclassical tearing mode (NTM) was demonstrated by ECRF heating using the real-time system in which the ECRF beams are injected to the NTM location predicted from ECE measurement every 10 ms.
Shimono, Mitsugu; Seki, Masami; Terakado, Masayuki; Igarashi, Koichi*; Ishii, Kazuhiro*; Takahashi, Masami*; Shinozaki, Shinichi; Hiranai, Shinichi; Sato, Fumiaki*; Anno, Katsuto
JAERI-Tech 2003-075, 29 Pages, 2003/09
no abstracts in English
Sato, Fumiaki*; Moriyama, Shinichi; Yokokura, Kenji; Shinozaki, Shinichi; Hiranai, Shinichi; Suzuki, Yasuo*; Seki, Masami
Heisei-14-Nendo Tokyo Daigaku Sogo Gijutsu Kenkyukai Gijutsu Hokokushu, 3 Pages, 2003/03
no abstracts in English
Ikeda, Yoshitaka; Kasugai, Atsushi; Moriyama, Shinichi; Kajiwara, Ken*; Seki, Masami; Tsuneoka, Masaki*; Takahashi, Koji; Anno, Katsuto; Hamamatsu, Kiyotaka; Hiranai, Shinichi; et al.
Fusion Science and Technology (JT-60 Special Issue), 42(2-3), p.435 - 451, 2002/09
Times Cited Count:26 Percentile:82.31(Nuclear Science & Technology)no abstracts in English
Seki, Masami; Ikeda, Yoshitaka; Maebara, Sunao; Moriyama, Shinichi; Naito, Osamu; Anno, Katsuto; Hiranai, Shinichi; Shimono, Mitsugu; Shinozaki, Shinichi; Terakado, Masayuki; et al.
Fusion Science and Technology (JT-60 Special Issue), 42(2-3), p.452 - 466, 2002/09
Times Cited Count:14 Percentile:65.6(Nuclear Science & Technology)no abstracts in English
Ikeda, Yoshitaka; Kasugai, Atsushi; Takahashi, Koji; Kajiwara, Ken; Isayama, Akihiko; Ide, Shunsuke; Terakado, Masayuki; Shinozaki, Shinichi; Yokokura, Kenji; Anno, Katsuto; et al.
Fusion Engineering and Design, 53(1-4), p.351 - 363, 2001/01
Times Cited Count:40 Percentile:92.11(Nuclear Science & Technology)no abstracts in English
Uehara, Kazuya; Ikeda, Yoshitaka; Saigusa, Mikio; Sakamoto, Keishi; Fujii, Tsuneyuki; Maebara, Sunao; Tsuneoka, Masaki; Seki, Masami; Moriyama, Shinichi; Kobayashi, Noriyuki*; et al.
Fusion Engineering and Design, 19(1), p.29 - 40, 1992/07
Times Cited Count:1 Percentile:17.26(Nuclear Science & Technology)no abstracts in English
Seki, Masami; Sawahata, Masayuki; Shinozaki, Shinichi; Hiranai, Shinichi; Suzuki, Sadaaki; Hasegawa, Koichi; Shimono, Mitsugu; Yokokura, Kenji; Ishii, Kazuhiro; Sato, Fumiaki; et al.
no journal, ,
no abstracts in English
Suzuki, Sadaaki; Hasegawa, Koichi; Shinozaki, Shinichi; Sato, Fumiaki; Hiranai, Shinichi; Ishii, Kazuhiro; Seki, Masami; Moriyama, Shinichi; Yokokura, Kenji
no journal, ,
no abstracts in English
Sawahata, Masayuki; Shimono, Mitsugu; Shinozaki, Shinichi; Terakado, Masayuki; Igarashi, Koichi; Takahashi, Masami; Seki, Masami
no journal, ,
no abstracts in English
Fujii, Tsuneyuki; Seki, Masami; Moriyama, Shinichi; Terakado, Masayuki; Suzuki, Sadaaki; Shinozaki, Shinichi; Sawahata, Masayuki; Hiranai, Shinichi; Igarashi, Koichi; Shimono, Mitsugu
no journal, ,
no abstracts in English