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論文

Reverse austenite transformation behavior in a tempered martensite low-alloy steel studied using ${it in situ}$ neutron diffraction

友田 陽*; Gong, W.*; Harjo, S.; 篠崎 智也*

Scripta Materialia, 133, p.79 - 82, 2017/05

AA2017-0349.pdf:2.43MB

 被引用回数:24 パーセンタイル:74.12(Nanoscience & Nanotechnology)

The microstructure evolution during reverse transformation of a Cr-Ni-Mo steel consisting of tempered lath martensite and Cr carbide was examined using ${it in situ}$ neutron diffraction at high temperatures. The microstructural change from a reversed coarse-grained structure to a fine-grained polygonal structure by further annealing was monitored through a decrease in the diffraction intensity caused by primary extinction and the full width at half maximum. This result is different from that for a bainite steel, showing good coincidence with the observations using electron back scatter diffraction.

論文

Encapsulating mobile proton carriers into structural defects in coordination polymer crystals; High anhydrous proton conduction and fuel cell application

犬飼 宗弘*; 堀毛 悟史*; 板倉 智也*; 篠崎 良太*; 荻原 直希*; 梅山 大樹*; Nagarker, S.*; 西山 裕介*; Malon, M.*; 林 灯*; et al.

Journal of the American Chemical Society, 138(27), p.8505 - 8511, 2016/07

 被引用回数:135 パーセンタイル:95.46(Chemistry, Multidisciplinary)

We describe encapsulation of mobile proton carriers into defect sites in non-porous coordination polymers. The proton carriers are encapasulated with high mobility and provide high proton conductivity at 150$$^{circ}$$C under anhydrous condition. The high proton conductivity and non-porous nature allow power generation by fuel cell in which CPs are used as electrolyte. To observe defects and mobile proton carriers, we carried out solid-state NMR, XAFS, XRD, and ICP-AES/EA. On the basis of these analyses, we elucidated that the defect sites provide space for mobile uncoordinated H$$_{3}$$PO$$_{4}$$, H$$_{2}$$PO$$_{4}$$$$^{-}$$, and H$$_{2}$$O. These mobile carriers play a key role to expand proton hopping path and promote the mobility of all protons in coordination frameworks, leading to high proton conductivity and fuel cell power generation.

論文

Spin-chirality-driven ferroelectricity on a perfect triangular lattice antiferromagnet

三田村 裕幸*; 綿貫 竜太*; 金子 耕士; 小野崎 紀道*; 天羽 祐太*; 橘高 俊一郎*; 小林 理気*; 志村 恭通*; 山本 勲*; 鈴木 和也*; et al.

Physical Review Letters, 113(14), p.147202_1 - 147202_5, 2014/10

 被引用回数:22 パーセンタイル:75.33(Physics, Multidisciplinary)

Magnetic field ($$B$$) variation of the electrical polarization $$P$$$$_{c}$$ ($${parallel}$$c) of the perfect triangular lattice antiferromagnet RbFe (MoO$$_4$$)$$_2$$ is examined up to the saturation point of the magnetization for B$${perp}c$$. $$P$$$$_{c}$$ is observed only in phases for which chirality is predicted in the in-plane magnetic structures. No strong anomaly is observed in $$P$$$$_{c}$$ at the field at which the spin modulation along the c axis exhibits a discontinuity to the commensurate state. These results indicate that ferroelectricity in this compound originates predominantly from triangular-spin chirality. The obtained field-temperature phase diagrams of ferroelectricity well agree with those theoretically predicted for the spin chirality of a Heisenberg spin triangular lattice antiferromagnet.

論文

The H-Invitational Database (H-InvDB); A Comprehensive annotation resource for human genes and transcripts

山崎 千里*; 村上 勝彦*; 藤井 康之*; 佐藤 慶治*; 原田 えりみ*; 武田 淳一*; 谷家 貴之*; 坂手 龍一*; 喜久川 真吾*; 嶋田 誠*; et al.

Nucleic Acids Research, 36(Database), p.D793 - D799, 2008/01

 被引用回数:51 パーセンタイル:71.25(Biochemistry & Molecular Biology)

ヒトゲノム解析のために、転写産物データベースを構築した。34057個のタンパク質コード領域と、642個のタンパク質をコードしていないRNAを見いだすことができた。

報告書

Development of the in-core fission chamber

Shirayama, S.*; Nozaki, S.*

PNC TJ201 74-28, 10 Pages, 1974/10

PNC-TJ201-74-28.pdf:0.44MB

None

口頭

Q&Pプロセスにおける相変態と炭素分配に及ぼすオーフォミングの影響

Gong, W.*; Harjo, S.; 柴田 曉伸*; 友田 陽*; 篠崎 智也*; 辻 伸泰*

no journal, , 

Quenching and partitioning (Q&P) process is an effective approach to control the amount and stability of retained austenite. Our previous study confirmed that carbon partitioning and isothermal transformation simultaneously occurred below martensitic transformation starting (Ms) temperature. In order to deepen the understanding on controlling microstructures through Q&P processes, the effect of ausforming on phase transformation and carbon partitioning during the Q&P process were investigated by the use of in-situ neutron diffraction in the present study.

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