Online solid-phase extraction-inductively coupled plasma-quadrupole mass spectrometric quantification of Sr using Sr/Sr isotope dilution method

Yanagisawa, Kayo*; Odashima, Mizuki*; Matsueda, Makoto; Furukawa, Makoto*; Takagai, Yoshitaka*

Talanta, 244, p.123442_1 - 123442_7, 2022/07

https://doi.org/10.1016/j.talanta.2022.123442

The determination of a low concentration of Sr was achieved by the combination of online SPE-ICP-QMS and ID method using Sr/Sr ratio. No requirement of radioactive standard material and the preparation process of the calibration curve was in the quantification process and data acquisition can be in one-shot sample injection. The proposed method allowed the rapid (within 15 min/sample) quantification of Sr in the presence of significant interferences such as isobaric Zr and other elements. The LOD for Sr was 5.6 Bq/L for a 10 mL injection and this could be improved by simply increasing the sample volume injected.