Selective adsorption of Pd(II) over Ag(I) in nitric acid solutions using nitrogen-donor-type adsorbents

Suzuki, Tomoya*; Otsubo, Ukyo*; Ogata, Takeshi*; Shiwaku, Hideaki; Kobayashi, Toru; Yaita, Tsuyoshi; Matsuoka, Mitsuaki*; Murayama, Norihiro*; Narita, Hirokazu*

Separation and Purification Technology, 308, p.122943_1 - 122943_7, 2023/03

https://doi.org/10.1016/j.seppur.2022.122943

HNO leaching is used in recycling Pd metal from spent products that primarily contain Ag, and most Pd residues are separated from solutions containing Ag(I). However, a small amount of Pd(II) often remains in these Ag(I) solutions. Therefore, the separation of Pd(II) and Ag(I) in HNO solutions is essential to promote efficient Pd recycling. In this study, the separation of Pd(II) and Ag(I) in HNO solutions was investigated using four N-donor-type adsorbents functionalized with amine (R-Amine), iminodiacetic acid (R-IDA), pyridine (R-Py), or bis-picolylamine (R-BPA). R-Amine, R-IDA, and R-Py selectively adsorbed Pd(II) over Ag(I), Cu(II), Ni(II), and Fe(III) from HNO solutions (0.3-7 M), but R-Amine exhibited a lower Pd adsorption efficiency. In contrast, 90% of Pd(II), Ag(I), and Cu(II) were adsorbed by R-BPA over the entire range of HNO concentrations. Structural analyses of the adsorbed metal ions using Fourier transform infrared spectroscopy and extended X-ray absorption fine structure spectroscopy revealed the separation mechanisms of the N-donor-type adsorbents. Pd(II) adsorption on R-IDA, R-Py, and R-BPA occurred via Pd(II) coordination of the functional groups (iminodiacetic acid, pyridine, and bis-picolylamine, respectively), whereas that on R-Amine occurred via anion exchange of NO with [Pd(NO)]. The coordinative adsorption mechanisms resulted in the higher Pd(II) adsorption behaviors of R-IDA, R-Py, and R-BPA. HCl (5.0 M) and thiourea (0.1 M) eluents desorbed 83% of Pd(II) from R-IDA and 95% from R-Py, respectively. R-Py was the most effective Pd(II) adsorbent based on adsorption selectivity and desorption efficiency.

Unique anion-exchange properties of 3,3'-diaminobenzidine resulting in high selectivity for rhodium(III) over palladium(II) and platinum(IV) in a concentrated hydrochloric acid solution

Suzuki, Tomoya*; Ogata, Takeshi*; Tanaka, Mikiya*; Kobayashi, Toru; Shiwaku, Hideaki; Yaita, Tsuyoshi; Narita, Hirokazu*

Analytical Sciences, 35(12), p.1353 - 1360, 2019/12

https://doi.org/10.2116/analsci.19P204

no abstracts in English

Speciation of ruthenium(III) chloro complexes in hydrochloric acid solutions and their extraction characteristics with an amide-containing amine compound

Suzuki, Tomoya*; Ogata, Takeshi*; Tanaka, Mikiya*; Kobayashi, Toru; Shiwaku, Hideaki; Yaita, Tsuyoshi; Narita, Hirokazu*

Metals, 8(7), p.558_1 - 558_10, 2018/07

AA2018-0670.pdf:2.11MB

https://doi.org/10.3390/met8070558

The refining of platinum group metals is based mainly on solvent extraction methods, whereas Ru is selectively recovered by distillation as RuO. Replacement of distillation byextraction is expected to simplify the purification process. To develop an effective extraction system for Ru, we analyzed the Ru species in HCl with UV-Vis and EXAFS spectroscopies, and we examined the properties of Ru extracted with N-2-ethylhexyl-bis(N-di-2-ethylhexyl-ethylamide) amine (EHBAA). EXAFS and UV-Vis spectra of Ru in HCl solutions revealed that the predominant Ru species in 0.5-10 M HCl solutions changed from [RuCl(HO)] to [RuCl] with the HCl concentration. The extraction percentages of Ru in the EHBAA system increased with increasing HCl concentration, reached 80% at [HCl] = 5 M, and decreased athigher HCl concentrations. EXAFS analysis of the extracted complex indicated that the Ru had 5 Cl and 1 HO in its inner coordination sphere. The similarity of the dependence on HCl concentrations of the extraction in the EHBAA system and the distribution profile of [RuCl(HO)] on [RuCl(HO)] suggested that the EHBAA extracted the pentachlorido species.

Development of structures for ITER toroidal field coil in Japan

Iguchi, Masahide; Chida, Yutaka; Takano, Katsutoshi; Kawano, Katsumi; Saito, Toru; Nakajima, Hideo; Koizumi, Norikiyo; Minemura, Toshiyuki*; Ogata, Hiroshige*; Ogawa, Tsuyoshi*; et al.

IEEE Transactions on Applied Superconductivity, 22(3), p.4203305_1 - 4203305_5, 2012/06

https://doi.org/10.1109/TASC.2011.2177795

Japan Atomic Energy Agency (JAEA) has responsibility to procure 19 structures for ITER toroidal field (TF) coils as in-kind components. JAEA plans to use materials specified in the material section of "Codes for Fusion Facilities; Rules on Superconducting Magnet Structure (2008)" issued by the Japan Society of Mechanical Engineers (JSME) in 2008. Large forged products were produced and their mechanical properties at 4K were evaluated. In addition, the following activities have been performed; (1) to optimize the design of each weld type identified in the manufacturing sequence, (2) to qualify typical welding procedure including repair, (3) to establish welding techniques other than narrow gap TIG welding with FMYJJ1, (4) to demonstrate the manufacturing procedures through manufacture of 1-m mockups and full-scale segments of TFC structure. This paper describes the results of material qualification and industrialization activities of manufacturing processes of ITER TFC structure.

Fabrication of U-Pu-Zr metallic fuel elements for the irradiation test at experimental fast test reactor Joyo

Nakamura, Kinya*; Ogata, Takanari*; Kikuchi, Hironobu; Iwai, Takashi; Nakajima, Kunihisa; Kato, Tetsuya*; Arai, Yasuo; Uozumi, Koichi*; Hijikata, Takatoshi*; Koyama, Tadafumi*; et al.

Nihon Genshiryoku Gakkai Wabun Rombunshi, 10(4), p.245 - 256, 2011/12

https://doi.org/10.3327/taesj.J10.038

Sodium-bonded metallic fuel elements were fabricated for the first time in Japan for the irradiation test in the experimental fast test reactor JOYO. U-20Pu-10Zr fuel slugs of 200 mm in length and approximately 5 mm in diameter were fabricated in a small-scale injection casting furnace. Each fuel slug was loaded into the ferritic martenstic stainless steel (PNC-FMS) cladding tube with the sodium thermal bond, thermal insulator and reflector in a helium gas atmosphere glove box. After top-end plug welding to the cladding tube and heat treatment of the welding area, each fuel element was subjected to the sodium bonding process. After the inspection such as element length, gas plenum length and helium-leak tightness, six metallic fuel elements are transported to the JOYO site for the coming irradiation test.

Fracture analysis in crystalline rock with method of multivariate analysis

Ogata, Nobuhisa; Osawa, Hideaki; Semba, Tsuyoshi; Yanagizawa, Koichi

PNC TN7410 92-001, 48 Pages, 1992/01

PNC-TN7410-92-001.pdf:1.71MB

In order to groundwater flow in rock formation, it is essential to make a topographic and hydrogeological models and to set up the initial and boundary conditions. Hydraulic properties are considered to be dominated by various factors of fracture (i.e. width, density, network) in the crystalline rock. Investigated was relationship between the hydraulic conductivity. which is one of important factors for evaluation of groundwater flow, and the fracture properties, using the method of multivariate analysis such as multiple regression analysis and cluster analysis. A total of 56 data on hydraulic conductivity and physical parameter were used that had been obtained from 2 boreholes drilled in the granitic rock of Tono area, Gifu, in the central Japan. The results are as follows: (1)The results of these two multivariate analysis are almost consistent. The hydraulic conductivity in the granitic rock is dominated by fracture system, such as number and width of the fracture, fissure-filling minerals. (2)The classificatory structure which obtained from the cluster analysis corresponds to that from hydraulic conductivity. Different hydraulic conductivities were distributed in each cluster that is dominated by width of open fracture, filling minerals, number of intersect and predominant direction of fractures. (3)The cluster analysis also implies that fracture properties of test sections with the similar hydraulic conductivities occasionally differ among them. Hence, the classifications is must be made based on the data of fracture properties as well as hydraulic conductivities. Future studies using sufficient number of data is necessary.

Thermal-swing extraction separation of Am(III) and Eu(III) by thermosensitive gel with encapsulating ligand

Takeshita, Kenji*; Ogata, Tsuyoshi*; Nakano, Yoshio*; Matsumura, Tatsuro; Mori, Atsunori*

no journal, , 

Extraction separation of Am(III) and Eu(III) was examined by the thermal-swing extraction technique using a thermosensitive gel, NIPA (poly-N-isopropylacrylamide) copolymerized with an encapsulating ligand, TPEN derivative called TPPEN (N,N,N',N'-tetrakis(4-propenyloxy-2-pyridylmethyl)ethylenediamine). The separation of Am(III) from Eu(III) was observed in the swollen state of gel (5C) and the separation factor of Am(III) was evaluated as about 18 at pH5.2. More than 90% of Am(III) extracted into the gel was released by the volume phase transition of gel from the swollen state (5C) to the shrunken one (40C). The radiation effect of gel on the extraction of Am and Eu was tested by the irradiation of -ray (10 kGy) and the long-term adsorption of -emitter (Cm). The TPPEN-NIPA gel sustained no damage by these radiation tests. These results suggest that the thermal-swing extraction technique is applicable to the MA partitioning process indispensable for the establishment of P&T technology.

Separation behavior of Am(III) from lanthanide(III) by TPEN-NIPA Gel and the separation mechanism study

Suzuki, Shinichi; Akutsu, Kazuhiro; Yaita, Tsuyoshi; Okamoto, Yoshihiro; Ogata, Tsuyoshi*; Takeshita, Kenji*; Inaba, Yusuke*; Ikeda, Atsushi; Kobayashi, Toru; Oaki, Hiroshi*; et al.

no journal, , 

no abstracts in English