Suppression of electrolytic corrosion at accelerator cooling-water facility by changing of rust inhibitors; Reduction of rust and cost

Dei, Tatsumi; Suganuma, Kazuaki; Fujirai, Kosuke; Suzuki, Katsuo; Suzuki, Hiroshi*; Nakata, Morihiro*; Hosokawa, Hideaki*; Onose, Yuichiro*; Watanabe, Yasuhiro; Shinozaki, Shinichi; et al.

JAEA-Technology 2026-003, 27 Pages, 2026/03

JAEA-Technology-2026-003.pdf:1.3MB

Accelerator cooling-water facility cannot prevent electrolytic corrosion because the systems consist of several different kinds of metals. We have confirmed that the electrolytic corrosion certainly occurs between oxygen-free copper and carbon steel, and cannot be suppressed by the rust inhibitor used so far. We have chosen a new rust inhibitor and confirmed that the new rust inhibitor can prevent the corrosion progression of carbon steel as well as oxygen-free copper. Moreover, using the new rust inhibitor brings about saving water and the cost reduction of the inhibitors.

Real-time stress visualization of hydrogels enabled by supramolecularly switched stretch-induced phase separation

Noh, S.*; Sugawara, Akihide*; Ishihara, Naoaki*; Konishi, Takashi*; Ueda, Yuki; Motokawa, Ryuhei; Takashima, Yoshinori*; Uyama, Hiroshi*

Advanced Science (Internet), p.e76110_1 - e76110_15, 2026/00

https://doi.org/10.1002/advs.76110

Particle arrangements and optical changes induced by the water swelling of melanin-like polydopamine layers

Watanabe, Taku*; Maejima, Yui*; Ueda, Yuki; Motokawa, Ryuhei; Takabatake, Ai*; Takeda, Shinichi*; Fudoji, Hiroshi*; Kishikawa, Keiki*; Koori, Michinari*

Langmuir, 41(34), p.22762 - 22773, 2025/09

https://doi.org/10.1021/acs.langmuir.5c01855

The assembled structures of melanin particles, i.e., colloidal particles coated with a melanin-like polydopamine (PDA) layer, create vivid structural colors. While the thickness of the PDA layer influences the particle arrangement and optical properties, the underlying mechanism has remained controversial. We demonstrate that the water swelling characteristics of PDA are crucial factors governing the dispersion and aggregation of these particles in solution. Detailed comparisons between dry and wet conditions revealed that the PDA layer readily absorbs water molecules, which leads to significant swelling in the thicker layers. The swelling of the PDA layers determined whether the particles remained dispersed or partially aggregated in the water, ultimately controlling the particle arrangement in the dry state once the water evaporated. These findings provide insights into the self-assembly of colloidal particles and offer a strategy for tuning the periodic particle order. This feature is pivotal for various applications in optical and sensing technologies.

Start-up of a test equipment for corrosion evaluation using copper thin film

Suganuma, Kazuaki; Sekiyama, Yoshio*; Honda, Tomoyuki*; Dei, Tatsumi; Suzuki, Katsuo; Fujirai, Kosuke; Suzuki, Hiroshi*; Nakata, Morihiro*; Hosokawa, Hideaki*; Watanabe, Yasuhiro; et al.

Proceedings of 21st Annual Meeting of Particle Accelerator Society of Japan (Internet), p.738 - 740, 2024/10

https://www.pasj.jp/web_publish/pasj2024/proceedings/PDF/THP0/THP061.pdf

In the J-PARC accelerator, the inner surface of the copper tubes that make up most of the coolant pipes is corroded. Generally, additives are added to the coolant to prevent corrosion, but the accelerator is in a radiation environment and additives cannot be used in the coolant to avoid impurities in the coolant become polluted by radiation. For example, in materials research in the nuclear field, there is a lot of research on strong acidic or strong alkaline solutions and corrosion resistant materials, but there is little literature on corrosion protection studies of purified water and copper materials. In general, we believe this is because the use of purified water and copper together in a radiation environment is limited. Corrosion testing of purified water and copper materials is unique to accelerators. The use of a thin copper film was considered as a possible method. In this case, we report on the current status of a new initiative, testing with copper thin films.

Present status of JAEA-Tokai tandem accelerator facility

Matsui, Yutaka; Nakamura, Masahiko; Kutsukake, Kenichi; Kabumoto, Hiroshi; Asozu, Takuhiro; Otokawa, Yoshinori; Ikekame, Takuma; Nakagawa, Sohei; Kato, Yuta; Ishizaki, Nobuhiro; et al.

Dai-36-Kai Tandemu Kasokuki Oyobi Sono Shuhen Gijutsu No Kenkyukai Hokokushu, p.17 - 21, 2024/06

no abstracts in English

Microbiome analysis of the restricted bacteria in radioactive element-containing water at the Fukushima Daiichi Nuclear Power Station

Warashina, Tomoro*; Sato, Asako*; Hinai, Hiroshi; Shaikhutdinov, N.*; Shagimardanova, E.*; Mori, Hiroshi*; Tamaki, Satoshi*; Saito, Motofumi*; Sanada, Yukihisa; Sasaki, Yoshito; et al.

Applied and Environmental Microbiology, 90(4), p.e02113-23_1 - e02113-23_23, 2024/04

https://doi.org/10.1128/aem.02113-23

Structural changes of polystyrene particles in subcritical and supercritical water revealed by in situ small-angle neutron scattering

Shibata, Motoki*; Nakanishi, Yohei*; Abe, Jun*; Arima, Hiroshi*; Iwase, Hiroki*; Shibayama, Mitsuhiro*; Motokawa, Ryuhei; Kumada, Takayuki; Takata, Shinichi; Yamamoto, Katsuhiro*; et al.

Polymer Journal, 55(11), p.1165 - 1170, 2023/11

https://doi.org/10.1038/s41428-023-00817-1

Polarized neutrons observed nanometer-thick crystalline ice plates in frozen glucose solution

Kumada, Takayuki; Nakagawa, Hiroshi; Miura, Daisuke; Sekine, Yurina; Motokawa, Ryuhei; Hiroi, Kosuke; Inamura, Yasuhiro; Oku, Takayuki; Oishi, Kazuki*; Morikawa, Toshiaki*; et al.

Journal of Physical Chemistry Letters (Internet), 14(34), p.7638 - 7643, 2023/08

https://doi.org/10.1021/acs.jpclett.3c01448

The structure of nano-ice crystals in rapidly frozen glucose solution was elucidated by using spin-contrast-variation small-angle neutron scattering, which distinguishes the nano-ice crystal signal from the frozen amorphous solution signal by the polarization-dependent neutron scattering. The analysis revealed that the nano-ice crystals form a planar structure with a diameter exceeding tens of nanometers and a thickness of 1 nm, which is close to the critical nucleation size. This result suggests that the glucose molecules are preferentially bound to a specific face of nano-ice crystals, and then block the crystal growth perpendicular to that face.

Present status of JAEA-Tokai tandem accelerator

Kabumoto, Hiroshi; Matsuda, Makoto; Nakamura, Masahiko; Ishizaki, Nobuhiro; Kutsukake, Kenichi; Otokawa, Yoshinori; Asozu, Takuhiro; Matsui, Yutaka; Nakagawa, Sohei; Abe, Shinichi

Proceedings of 19th Annual Meeting of Particle Accelerator Society of Japan (Internet), p.1109 - 1113, 2023/01

no abstracts in English

Development of spin-contrast-variation neutron powder diffractometry for extracting the structure factor of hydrogen atoms

Miura, Daisuke*; Kumada, Takayuki; Sekine, Yurina; Motokawa, Ryuhei; Nakagawa, Hiroshi; Oba, Yojiro; Ohara, Takashi; Takata, Shinichi; Hiroi, Kosuke; Morikawa, Toshiaki*; et al.

Journal of Applied Crystallography, 54(2), p.454 - 460, 2021/04

AA2020-0724.pdf:2.05MB

https://doi.org/10.1107/S1600576721000303

We developed a spin-contrast-variation neutron powder diffractometry technique that extracts the structure factor of hydrogen atoms, namely, the contribution of hydrogen atoms to a crystal structure factor. Crystals of L-glutamic acid were dispersed in a dpolystyrene matrix containing 4-methacryloyloxy-2,2,6,6,-tetramethyl-1-piperidinyloxy (TEMPO methacrylate) to polarize their proton spins dynamically. The intensities of the diffraction peaks of the sample changed according to the proton polarization, and the structure factor of the hydrogen atoms was extracted from the proton-polarization dependent intensities. This technique is expected to enable analyses of the structures of hydrogen-containing materials that are difficult to determine with conventional powder diffractometry.