Neutron diffraction study on the deuterium composition of nickel deuteride at high temperatures and high pressures

Saito, Hiroyuki*; Machida, Akihiko*; Hattori, Takanori; Sano, Asami; Funakoshi, Kenichi*; Sato, Toyoto*; Orimo, Shinichi*; Aoki, Katsutoshi*

Physica B; Condensed Matter, 587, p.412153_1 - 412153_6, 2020/06

https://doi.org/10.1016/j.physb.2020.412153

The site occupancy of deuterium (D) atoms in face-centered-cubic nickel (fcc Ni) was measured along a cooling path from 1073 to 300 K at an initial pressure of 3.36 GPa via in situ neutron powder diffraction. Deuterium atoms predominantly occupy the octahedral (O) sites and slightly occupy the tetrahedral (T) sites of the fcc metal lattice. The O-site occupancy increases from 0.4 to 0.85 as the temperature is lowered from 1073 to 300 K. Meanwhile, the T-site occupancy remains c.a. 0.02. The temperature-independent behavior of the T-site occupancy is unusual, and its process is not yet understood. From the linear relation between the expanded lattice volume and D content, a D-induced volume expansion of 2.09(13) atom was obtained. This value is in agreement with the values of 2.14-2.2 atom previously reported for Ni and Ni Fe alloy.

Hexagonal close-packed iron hydride behind the conventional phase diagram

Machida, Akihiko*; Saito, Hiroyuki*; Hattori, Takanori; Sano, Asami; Funakoshi, Kenichi*; Sato, Toyoto*; Orimo, Shinichi*; Aoki, Katsutoshi*

Scientific Reports (Internet), 9(1), p.12290_1 - 12290_9, 2019/08

https://doi.org/10.1038/s41598-019-48817-7

Hexagonal close-packed iron hydride, hcp FeHx, is absent from the conventional phase diagram of the Fe-H system, although hcp metallic Fe exists stably over extensive temperature () and pressure () conditions, including those corresponding to the Earth's inner core. X-ray and neutron diffraction measurements at temperatures ranging from 298 to 1073 K and H pressures ranging from 4 to 7 GPa revealed that the hcp hydride was formed for FeH compositions when . Hydrogen atoms occupied the octahedral interstitial sites of the host metal lattice both partially and randomly. The hcp hydride exhibited a H-induced volume expansion of 2.48(5) /H-atom, which was larger than that of the face-centered cubic (fcc) hydride. The hcp hydride showed an increase in with , whereas the fcc hydride showed a corresponding decrease. The present study provides guidance for further investigations of the Fe-H system over an extensive -- region.

Site occupancy of interstitial deuterium atoms in face-centred cubic iron

Machida, Akihiko; Saito, Hiroyuki; Sugimoto, Hidehiko*; Hattori, Takanori; Sano, Asami; Endo, Naruki*; Katayama, Yoshinori; Iizuka, Riko*; Sato, Toyoto*; Matsuo, Motoaki*; et al.

Nature Communications (Internet), 5, p.5063_1 - 5063_6, 2014/09

https://doi.org/10.1038/ncomms6063

Iron hydride FeH, is thermodynamically stable only at high hydrogen pressure of several GPa. To investigate the hydrogenation process and hydrogen state in iron hydride, it is necessary to carry out the in-situ measurement under high pressure and high temperature. In this study, we performed the in-situ neutron diffraction measurement of Fe-D system using the high pressure neutron diffractometer PLANET in the MLF, J-PARC, and determined the deuterium occupying sites and occupancies in fcc-FeD. We found the minor occupation of tetrahedral sites under high pressure and high temperature. We considered the mechanism of the minor occupation based on the Quantum-mechanical calculation.

Syntheses of novel metal hydrides under high pressure and high pressure with the aid of synchrotron radiation X-ray diffraction measurement

Saito, Hiroyuki; Takagi, Shigeyuki*; Aoki, Katsutoshi; Orimo, Shinichi*

Hoshako, 27(1), p.10 - 19, 2014/01

no abstracts in English

Synthesis and formation process of AlCuH; A New class of interstitial aluminum-based alloy hydride

Saito, Hiroyuki; Takagi, Shigeyuki*; Endo, Naruki; Machida, Akihiko; Aoki, Katsutoshi; Orimo, Shinichi*; Katayama, Yoshinori

APL Materials (Internet), 1(3), p.032113_1 - 032113_7, 2013/09

https://doi.org/10.1063/1.4821632

Formation process of perovskite-type hydride LiNiH; synchrotron radiation X-ray diffraction study

Sato, Ryutaro*; Saito, Hiroyuki; Endo, Naruki; Takagi, Shigeyuki*; Matsuo, Motoaki*; Aoki, Katsutoshi; Orimo, Shinichi*

Applied Physics Letters, 102(9), p.091901_1 - 091901_4, 2013/03

https://doi.org/10.1063/1.4794067

Formation of an Fe-H complex anion in YFe; Adjustment of imbalanced charge by additional Li as an electron donor

Matsuo, Motoaki*; Saito, Hiroyuki; Machida, Akihiko; Sato, Ryutaro*; Takagi, Shigeyuki*; Miwa, Kazutoshi*; Watanuki, Tetsu; Katayama, Yoshinori; Aoki, Katsutoshi; Orimo, Shinichi*

RSC Advances (Internet), 3(4), p.1013 - 1016, 2013/01

https://doi.org/10.1039/c2ra22497f

Correlation between structure of titanium additives and dehydrogenation reaction of magnesium borohydride studied by continuous observation of X-ray absorption spectroscopy

Matsumura, Daiju; Oyama, Takahiro*; Okajima, Yuka*; Nishihata, Yasuo; Li, H.-W.*; Orimo, Shinichi*

Materials Transactions, 52(4), p.635 - 640, 2011/04

https://doi.org/10.2320/matertrans.MA201018

Local structure of Ti-based additives in Mg(BH) was studied by X-ray absorption fine structure spectroscopy with conventional and dispersive mode in order to understand the correlation between the structure of the additives and dehydrogenation property of Mg(BH). Simultaneous measurement of the dehydrogenation curve and the X-ray absorption spectroscopy by the dispersive optics revealed that a part of TiCl additive is converted to TiMg(BH) ( = 00.67) just after ball milling mixture and then promptly resolved to TiB at 100-150C with the first dehydrogenation peak. TiO additive is slowly converted to lower oxidation state in wide temperature range around the second dehydrogenation peak at 350C where the main dehydrogenation reaction of Mg(BH) occurs.

Multi-millijoule, nonlinear preamplifier for high intensity femtosecond Yb:YAG chirped-pulse amplification lasers at 1030 nm

Suzuki, Masayuki; Kiriyama, Hiromitsu; Daito, Izuru; Okada, Hajime; Nakai, Yoshiki; Orimo, Satoshi; Sato, Masatoshi*; Tamaoki, Yoshinori*; Yoshii, Takehiro*; Maeda, Junya*; et al.

Applied Physics B, 97(2), p.379 - 382, 2009/10

https://doi.org/10.1007/s00340-009-3741-3

We report the highest energy broadband laser pulses at a center wavelength of 1030 nm based on optical parametric chirped-pulse amplification (OPCPA). We have demonstrated amplification of 1030 nm femtosecond laser pulses from a broadband Yb oscillator to over 6.5 mJ with a total gain of greater than 10 achieved in a single pass through only 56 mm of gain material at a 10 Hz repetition rate. The amplified spectral bandwidth of 10.8 nm affords recompression to a 230 fs pulse duration following amplification. As an alternative to the regenerative amplifier (RA) this system is one of the more promising candidates for realizing compact, high intensity, direct diode pumped, high repetition rate femtosecond Yb:YAG chirped-pulse amplification (CPA) in laser systems.

Advanced neutron shielding material using zirconium borohydride and zirconium hydride

Hayashi, Takao; Tobita, Kenji; Nakamori, Yuko*; Orimo, Shinichi*

Journal of Nuclear Materials, 386-388, p.119 - 121, 2009/04

https://doi.org/10.1016/j.jnucmat.2008.12.073

Neutron transport calculations have been carried out to assess the capability of zirconium borohydride (Zr(BH)) and zirconium hydride (ZrH) as advanced shield materials, because excellent shields can be used to protect outer structural materials from serious activation. The neutron shielding capability of Zr(BH) is lower than ZrH, even though the hydrogen density of Zr(BH) is slightly higher than that of ZrH. High-Z atoms are effective in neutron shielding as well as hydrogen atoms. The combination of steel and Zr(BH) can improve the neutron shielding capability. The combinations of (Zr(BH) + F82H) and (ZrH + F82H) can reduce the thickness of the shield by 6.5% and 19% compared to (water + F82H), respectively. The neutron flux for Zr(BH) is drastically reduced in the range of neutron energy below 100 eV compared to other materials, due to the effect of boron, which can lead to a reduction of radwaste from fusion reactors.