Comprehensive extraction study using -dioctylthiodiglycolamic acid; Effect of S donor on metal extraction

Shimojo, Kojiro; Fujiwara, Iori*; Saito, Takumi*; Oshima, Tatsuya*

Analytical Sciences, 40(8), p.1429 - 1436, 2024/08

https://doi.org/10.1007/s44211-024-00577-9

Extraction ability of -dioctylthiodiglycolamic acid (T-DODGAA), a soft-base sulfur donor ligand with an amide group and a carboxylic acid connected by a thioether chain, for 56 metal ions have been comprehensively investigated and compared with that of N,N-dioctyldiglycolamic acid (DODGAA) with an etheric oxygen atom, a hard-base donor. The p of the thiodiglycolamic acid framework was determined to be 3.71 0.06 in water (0.1 M LiCl, 25C ) by potentiometric titration, indicating that T-DODGAA is a slightly weaker acid than DODGAA (p = 3.54 0.03). T-DODGAA can quantitatively extract various metal ions from the 56 metal ions through a proton-exchange reaction. T-DODGAA provided higher extraction performance than DODGAA for Hf(IV), Cr(III), Fe(III), Ni(II), Cu(II), Pd(II), Ag(I), Au(III), Hg(II), Al(III), and Ga(III), especially for soft metal ions. Furthermore, to demonstrate the practical feasibility of T-DODGAA for hydrometallurgy and metal recycling, we performed selective separation tests of rare metal ions such as Sc(III), Ni(II), Co(II), Pd(II), Au(III), In(III), and Ga(II) in metal-mixed extraction systems.

Effect of water for the oxygen adsorption on surface of PtCo catalysts

Cui, Y.-T.*; Harada, Yoshihisa*; Niwa, Hideharu*; Oshima, Masaharu*; Hatanaka, Tatsuya*; Nakamura, Naoki*; Ando, Masaki*; Yoshida, Toshihiko*; Ishii, Kenji*; Matsumura, Daiju

NanotechJapan Bulletin (Internet), 11(4), 6 Pages, 2018/08

no abstracts in English

A Comprehensive extraction study using a mono-alkylated diglycolamic acid extractant; Comparison between a secondary amide group and a tertiary amide group

Sugita, Tsuyoshi; Fujiwara, Iori*; Okamura, Hiroyuki; Oshima, Tatsuya*; Baba, Yoshinari*; Naganawa, Hirochika; Shimojo, Kojiro

Solvent Extraction Research and Development, Japan, 24(2), p.61 - 69, 2017/05

http://www.solventextraction.gr.jp/serdj/jurnalpdf/vol24(2)/24_61.pdf

We investigated an influence of amide group in diglycolamic acid-type extractants on extraction property of metal ions. The extraction characteristics of -dodecyldiglycolamic acid (CDGAA), with a secondary amide group, for 56 metal ions have been investigated, and compared with those of -dioctyldiglycolamic acid (DODGAA) with a tertiary amide group. Compared with DODGAA, CDGAA has a poor extraction performance and separation ability for rare-earth metal ions, except for Sc(III). However, CDGAA tended to provide better extraction for relatively small-sized metal ions than DODGAA. In addition, it was found that CDGAA enables the selective removal of Hg(II) from aqueous solutions containing various divalent metal ions.

Extraction behavior of rare-earth elements using a mono-alkylated diglycolamic acid extractant

Shimojo, Kojiro; Fujiwara, Iori*; Fujisawa, Kiyoshi*; Okamura, Hiroyuki; Sugita, Tsuyoshi; Oshima, Tatsuya*; Baba, Yoshinari*; Naganawa, Hirochika

Solvent Extraction Research and Development, Japan, 23(2), p.151 - 159, 2016/05

http://doi.org/10.15261/serdj.23.151

Liquid-liquid extraction of rare-earth (RE) cations has been investigated using -dodecyldiglycolamic acid (CDGAA) with a secondary amide group, and compared with that using -dioctyldiglycolamic acid (DODGAA) with a tertiary amide group. CDGAA enables quantitative transfer of all RE cations from moderately acidic solution, while being selective toward the heavier RE cations, and performs better than typical carboxylic-acid-type extractants. However, CDGAA provides low extraction performance and separation ability for RE cations compared with DODGAA because of the weaker basicity of the amide oxygen. Slope analysis demonstrated that RE transfer with CDGAA proceeded through a proton-exchange reaction, forming a 1:3 complex, RE(CDGAA). Structural characterization by X-ray diffraction revealed that three -butyldiglycolamic acid (CDGAA) molecules coordinated to the La central ion in a tridentate fashion and the La primary coordination sphere consisted of three oxygen atoms from the amide group, three oxygen atoms from the ether group, and three oxygen atoms from the carboxy group.

Recovery of radiation degradation on inverted metamorphic triple-junction solar cells by light soaking

Shibata, Yuichi*; Imaizumi, Mitsuru*; Sato, Shinichiro; Oshima, Takeshi; Ooka, Sachiyo*; Takamoto, Tatsuya*

Proceedings of 11th International Workshop on Radiation Effects on Semiconductor Devices for Space Applications (RASEDA-11) (Internet), p.65 - 68, 2015/11

Radiation response is one of the important properties for space solar cells. It should be well understood so as to accurately predict their degradation in orbit and also to improve their radiation tolerance. Recently, a phenomenon, recovery from the radiation degradation by light soaking, on inverted metamorphic (IMM) triple-junction (3J) solar cells was found out. In this work, the light soaking annealing effects on electron irradiated IMM 3J solar cells are reported. IMM 3J solar cells irradiated with 1 MeV electrons with the fluence of 310 e/cm showed the recovery of open-circuit voltage, Voc, up to 43 mV after light (AM0, 1 sun) soaking of 3 hours. The increment of the electroluminescence intensity for InGaP in the IMM 3J cells due to the light soaking suggests that the Voc recovery occurs in InGaP top-cell rather than GaAs middle-cell or InGaAs bottom-cell.

Development of space solar sheet with inverted triple-junction cells

Yamaguchi, Hiroshi*; Ijichi, Ryo*; Suzuki, Yoshiyuki*; Ooka, Sachiyo*; Shimada, Keiji*; Takahashi, Naoki*; Washio, Hidetoshi*; Nakamura, Kazuyo*; Takamoto, Tatsuya*; Imaizumi, Mitsuru*; et al.

Proceedings of 42nd IEEE Photovoltaic Specialists Conference (PVSC-42) (CD-ROM), p.2407 - 2411, 2015/06

https://doi.org/10.1109/PVSC.2015.7356138

Cross section measurements of the radioactive Pd and stable Pd nuclei at J-PARC/MLF/ANNRI

Nakamura, Shoji; Kimura, Atsushi; Kitatani, Fumito; Ota, Masayuki; Furutaka, Kazuyoshi; Goko, Shinji*; Hara, Kaoru; Harada, Hideo; Hirose, Kentaro; Kin, Tadahiro*; et al.

Nuclear Data Sheets, 119, p.143 - 146, 2014/05

https://doi.org/10.1016/j.nds.2014.08.040

We have started the measurements of the neutron-capture cross sections for stable Pd nuclei as well as the radioactive Pd. The neutron-capture cross-section measurements by the time-of flight method were performed using an apparatus called "Accurate Neutron-Nucleus Reaction measurement Instrument (ANNRI)" installed at the neutron Beam Line No.4 of the Materials and Life science experimental Facility (MLF) in the J-PARC. The neutron-capture cross sections of Pd and Pd have been measured in the neutron energy range from thermal to 300 eV. Some new information was obtained for resonances of these Pd nuclei.

Measurements of capture rays from the neutron resonances of Se and Se at the J-PARC/MLF/ANNRI

Hori, Junichi*; Yashima, Hiroshi*; Nakamura, Shoji; Furutaka, Kazuyoshi; Hara, Kaoru; Harada, Hideo; Hirose, Kentaro; Kimura, Atsushi; Kitatani, Fumito; Koizumi, Mitsuo; et al.

Nuclear Data Sheets, 119, p.128 - 131, 2014/05

https://doi.org/10.1016/j.nds.2014.08.036

In this work, we measured the capture rays from the neutron resonances of Se and Se. A neutron time-of-flight method was adopted for the measurements with a 4 Ge spectrometer installed at the Accurate Neutron-Nucleus Reaction measurement Instrument (ANNRI) in the J-PARC Material and Life science experimental Facility (MLF). The -ray pulse-height spectra corresponding to the 27-eV resonance of Se and the 113-, 212-, 291-, 342-, 690- and 864-eV resonances of Se were obtained by gating on the TOF regions, respectively. The relative intensities of those primary transitions were derived and compared with the previous experimental data. For the 27-eV resonance of Se, a strong primary transition to the 293-keV state was observed. As for Se, the quite differences of the decay pattern were found between the resonances.

Effect of annealing on proton irradiated AlGaN/GaN based micro-Hall sensors

Abderrahmane, A.*; Takahashi, Hiroki*; Tashiro, Tatsuya*; Ko, P. J.*; Okada, Hiroshi*; Sato, Shinichiro; Oshima, Takeshi; Sandhu, A.*

AIP Conference Proceedings 1585, p.123 - 127, 2014/02

https://doi.org/10.1063/1.4866629

The effect of annealing at 673 K on irradiated micro-Hall sensors irradiated with protons at 380 keV and fluences of 1 cm, 1 cm, 1 cm is reported. Cathodoluminescence measurements were carried out at room temperature before and after annealing and showed improvement in the band edge band emission of the GaN layer. After annealing a sensor irradiated by 1 cm the device became operational with improvements in its magnetic sensitivity. All irradiated sensors showed improvement in their electrical characteristics after annealing.

Partial recovery of the magnetoelectrical properties of AlGaN/GaN-based micro-Hall sensors irradiated with protons

Abderrahmane, A.*; Tashiro, Tatsuya*; Takahashi, Hiroki*; Ko, P. J.*; Okada, Hiroshi*; Sato, Shinichiro; Oshima, Takeshi; Sandhu, A.*

Applied Physics Letters, 104(2), p.023508_1 - 023508_4, 2014/01

https://doi.org/10.1063/1.4861902

The effect of annealing on the magnetoelectrical properties of proton-irradiated micro-Hall sensors at an energy of 380 keV and very high proton fluences was studied. Recovery of the electron mobility and a decrease in the sheet resistance of the annealed micro-Hall sensors, as well as an enhancement in their magnetic sensitivity were reported. Trap removal and an improvement in the crystal quality by removing defects were confirmed through current-voltage measurements and Raman spectroscopy, respectively.