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Journal Articles

Rotation of complex ions with ninefold hydrogen coordination studied by quasielastic neutron scattering and first-principles molecular dynamics calculations

Omasa, Yoshinori*; Takagi, Shigeyuki*; Toshima, Kento*; Yokoyama, Kaito*; Endo, Wataru*; Orimo, Shinichi*; Saito, Hiroyuki*; Yamada, Takeshi*; Kawakita, Yukinobu; Ikeda, Kazutaka*; et al.

Physical Review Research (Internet), 4(3), p.033215_1 - 033215_9, 2022/09

Journal Articles

New application of NV centers in CVD diamonds as a fluorescent nuclear track detector

Onoda, Shinobu; Haruyama, Moriyoshi; Teraji, Tokuyuki*; Isoya, Junichi*; Kada, Wataru*; Hanaizumi, Osamu*; Oshima, Takeshi

Physica Status Solidi (A), 212(11), p.2641 - 2644, 2015/11

 Times Cited Count:11 Percentile:44.78(Materials Science, Multidisciplinary)

Journal Articles

NV centers in diamond used for detection of single ion track

Haruyama, Moriyoshi; Onoda, Shinobu; Kada, Wataru*; Teraji, Tokuyuki*; Isoya, Junichi*; Oshima, Takeshi; Hanaizumi, Osamu*

Proceedings of 11th International Workshop on Radiation Effects on Semiconductor Devices for Space Applications (RASEDA-11) (Internet), p.184 - 187, 2015/11

Journal Articles

Development of diagnostic method for deep levels in semiconductors using charge induced by heavy ion microbeams

Kada, Wataru*; Kambayashi, Yuya*; Iwamoto, Naoya*; Onoda, Shinobu; Makino, Takahiro; Koka, Masashi; Kamiya, Tomihiro; Hoshino, Norihiro*; Tsuchida, Hidekazu*; Kojima, Kazutoshi*; et al.

Nuclear Instruments and Methods in Physics Research B, 348, p.240 - 245, 2015/04

 Times Cited Count:4 Percentile:32.95(Instruments & Instrumentation)

Journal Articles

Continuous observation of polarization effects in thin SC-CVD diamond detector designed for heavy ion microbeam measurement

Kada, Wataru*; Iwamoto, Naoya; Sato, Takahiro; Onoda, Shinobu; Grilj, V.*; Skukan, N.*; Koka, Masashi; Oshima, Takeshi; Jak$v{s}$i$'c$, M.*; Kamiya, Tomihiro

Nuclear Instruments and Methods in Physics Research B, 331, p.113 - 116, 2014/07

 Times Cited Count:24 Percentile:87.22(Instruments & Instrumentation)

no abstracts in English

Journal Articles

Focused microbeam irradiation effects in transmission CVD diamond film detectors

Kada, Wataru; Kamiya, Tomihiro; Iwamoto, Naoya; Onoda, Shinobu; Grilj, V.*; Skukan, N.*; Makino, Takahiro; Koka, Masashi; Sato, Takahiro; Jak$v{s}$i$'c$, M.*; et al.

Transactions of the Materials Research Society of Japan, 38(2), p.279 - 282, 2013/07

Diamond is interested by many researchers as an excellent candidate material with advantages in the radiation-hardness. For the time-resolved detection of single-ions with several hundred MeV, transmission E detector using thin film CVD diamond is now under investigation for the futuristic utilization in a microbeam line of the AVF cyclotron at JAEA/Takasaki TIARA facility as replacing materials of the beam extraction window. In this research, a Single Crystalline (SC) 50 m thick CVD diamond film ion detector was fabricated for the investigation of the responses and radiation hardness under the focused ion microbeam irradiation. Transient Ion Beam Induced Current (TIBIC) experiment was executed by single hit irradiation of 15 MeV O$$^{4+}$$ scanning area of 50 $$mu$$m$$^2$$ and the transient signals with time width of several nano-secounds were consecutively recorded by a high speed (15 GHz) Digital Storage Oscilloscope during the irradiation. The decreases in the individual pulse height was observed by increasing the total amount of the ion dose irradiated in the focused area. These changes were recovered in temporal conversion of applied bias voltages thus trend of decrease were able to be controlled by changing bias settings and irradiation conditions during the experiments.

Journal Articles

Transmission charged-particle detectors using CVD diamond thin film for single ion hit measurement

Kada, Wataru; Sato, Takahiro; Makino, Takahiro; Onoda, Shinobu; Koka, Masashi; Oshima, Takeshi; Kamiya, Tomihiro; Grilj, V.*; Skukan, N.*; Jaksic, M.*

KEK Proceedings 2012-8, p.89 - 98, 2012/12

Transmissive particle detectors using thin-film diamond were newly developed for the individual detection of single-hit of heavy ions. Two type of the detectors were developed using poly- and single-crystalline diamond films with thickness of upper 50 $$mu$$m, which could be alternative candidate material of beam-extraction window. The detectors were irradiated at off- and on-line environment using alpha-particle sources and microbeam lines of two tandem accelerators placed at TARRI, JAEA and RBI. From point of view in the response of energy spectrum and detection efficiency, it was experimentally examined that the thin-film of single-crystalline diamond was well respond to the irradiation of single ions with energy of several MeV.

Journal Articles

Microbeam irradiation effects on transmission diamond detector

Kada, Wataru; Sato, Takahiro; Iwamoto, Naoya; Onoda, Shinobu; Grilj, V.*; Skukan, N.*; Makino, Takahiro; Koka, Masashi; Jak$v{s}$i$'c$, M.*; Oshima, Takeshi; et al.

Proceedings of 10th International Workshop on Radiation Effects on Semiconductor Devices for Space Applications (RASEDA-10) (Internet), p.70 - 73, 2012/12

Thin film CVD diamond detector is now under investigation for the utilization as a transmission detector for ionized particle in single-ion-hit by replacing materials of the beam extraction window in a microbeam line of the AVF cyclotron at JAEA/Takasaki. In this research, a spectroscopy-grade 50 $$mu$$m thick-film Single Crystalline (SC) CVD diamond detector with size of 4.6 mm $$times$$ 4.6 mm was characterized using Ion Beam Induced Charge (IBIC) and Transient Ion Beam Induced Current (TIBIC) systems. The detector was irradiated with 1-3 MeV H$$^{+}$$ and 15 MeV O$$^{4+}$$ microbeams. Significant decrease of pulse height of IBIC signals was observed at 15 MeV O$$^{4+}$$ irradiation, however, this peak degradation easily recovered in a short time by release of bias voltages. This temporal degradation effect was enhanced in areas damaged by previous ion irradiation. Therefore, the temporal peak degradation seems to be caused by the polarization effect due to charge captured by defects in diamond or/and at the surface.

Journal Articles

Anionic fluoro complex of element 105, Db

Kasamatsu, Yoshitaka*; Toyoshima, Atsushi; Asai, Masato; Tsukada, Kazuaki; Li, Z.; Ishii, Yasuo; Tome, Hayato*; Sato, Tetsuya; Kikuchi, Takahiro; Nishinaka, Ichiro; et al.

Chemistry Letters, 38(11), p.1084 - 1085, 2009/10

 Times Cited Count:16 Percentile:48.84(Chemistry, Multidisciplinary)

We report on the characteristic anion-exchange behavior of the superheavy element dubnium (Db) with atomic number Z = 105 in HF/HNO$$_{3}$$ solution at the fluoride ion concentration [F$$^{-}$$] = 0.003 M. The result clearly demonstrates that the fluoro complex formation of Db is significantly different from that of the group-5 homologue Ta in the 6th period of the periodic table while the behavior of Db is similar to that of the lighter homologue Nb in the 5th period.

Journal Articles

Oxidation of element 102, nobelium, with flow electrolytic column chromatography on an atom-at-a-time scale

Toyoshima, Atsushi; Kasamatsu, Yoshitaka*; Tsukada, Kazuaki; Asai, Masato; Kitatsuji, Yoshihiro; Ishii, Yasuo; Tome, Hayato; Nishinaka, Ichiro; Haba, Hiromitsu*; Oe, Kazuhiro*; et al.

Journal of the American Chemical Society, 131(26), p.9180 - 9181, 2009/07

 Times Cited Count:15 Percentile:45.51(Chemistry, Multidisciplinary)

We report here on the successful oxidation of element 102, nobelium (No), on an atom-at-a-time scale in 0.1 M $$alpha$$-hydroxyisobutyric acid ($$alpha$$-HIB) solution using newly developed flow electrolytic column chromatography. It is found that the most stable No$$^{2+}$$ is oxidized to No$$^{3+}$$ within 3 min and that the oxidized No complex with $$alpha$$-HIB holds the trivalent state in the column above the applied potential of 1.0 V.

Journal Articles

Adsorption of Db and its homologues Nb and Ta, and the pseudo-homologue Pa on anion-exchange resin in HF solution

Tsukada, Kazuaki; Haba, Hiromitsu*; Asai, Masato; Toyoshima, Atsushi; Akiyama, Kazuhiko*; Kasamatsu, Yoshitaka; Nishinaka, Ichiro; Ichikawa, Shinichi; Yasuda, Kenichiro; Miyamoto, Yutaka; et al.

Radiochimica Acta, 97(2), p.83 - 89, 2009/02

 Times Cited Count:21 Percentile:77.63(Chemistry, Inorganic & Nuclear)

Anion-exchange chromatography of element 105, dubnium (Db), produced in the $$^{248}$$Cm($$^{19}$$F, 5n)$$^{262}$$Db reaction is investigated together with the homologues Nb and Ta, and the pseudo-homologue Pa in 13.9 M hydrofluoric acid (HF) solution. The distribution coefficient (K$$_{d}$$) of Db on an anion-exchange resin is successfully determined by running cycles of the 1702 chromatographic column separations. The result clearly indicates that the adsorption of Db on the resin is significantly different from that of the homologues and that the adsorption of anionic fluoro complexes of these elements decreases in the sequence of Ta $$approx$$ Nb $$>$$ Db $$geq$$ Pa.

Journal Articles

Hexafluoro complex of rutherfordium in mixed HF/HNO$$_{3}$$ solutions

Toyoshima, Atsushi; Haba, Hiromitsu*; Tsukada, Kazuaki; Asai, Masato; Akiyama, Kazuhiko*; Goto, Shinichi*; Ishii, Yasuo; Nishinaka, Ichiro; Sato, Tetsuya; Nagame, Yuichiro; et al.

Radiochimica Acta, 96(3), p.125 - 134, 2008/03

 Times Cited Count:29 Percentile:84.99(Chemistry, Inorganic & Nuclear)

Formation of an anionic fluoride-complex of element 104, rutherfordium (Rf) produced in the $$^{248}$$Cm($$^{18}$$O,5n)$$^{261}$$Rf reaction was studied by an anion-exchange method based on an atom-at-a-time scale. It was found that the hexafluoro complex of Rf, [RfF$$_{6}$$]$$^{2-}$$, was formed in the studied fluoride ion concentrations of 0.0005 - 0.013 M. Formation of [RfF$$_{6}$$]$$^{2-}$$ was significantly different from that of the homologues Zr and Hf, [ZrF$$_{6}$$]$$^{2-}$$ and [HfF$$_{6}$$]$$^{2-}$$; the evaluated formation constant of [RfF$$_{6}$$]$$^{2-}$$ is at least one-order of magnitude smaller than those of [ZrF$$_{6}$$]$$^{2-}$$ and [HfF$$_{6}$$]$$^{2-}$$.

Journal Articles

Extraction behavior of rutherfordium into tributylphosphate from hydrochloric acid

Haba, Hiromitsu*; Tsukada, Kazuaki; Asai, Masato; Toyoshima, Atsushi; Ishii, Yasuo; Tome, Hayato; Sato, Tetsuya; Nishinaka, Ichiro; Ichikawa, Takatoshi; Ichikawa, Shinichi; et al.

Radiochimica Acta, 95(1), p.1 - 6, 2007/01

 Times Cited Count:16 Percentile:70.17(Chemistry, Inorganic & Nuclear)

no abstracts in English

Journal Articles

Chemical studies on rutherfordium (Rf) at JAERI

Nagame, Yuichiro; Tsukada, Kazuaki; Asai, Masato; Toyoshima, Atsushi; Akiyama, Kazuhiko; Ishii, Yasuo; Sato, Tetsuya; Hirata, Masaru; Nishinaka, Ichiro; Ichikawa, Shinichi; et al.

Radiochimica Acta, 93(9-10), p.519 - 526, 2005/00

 Times Cited Count:31 Percentile:87.03(Chemistry, Inorganic & Nuclear)

no abstracts in English

Journal Articles

Elution curve of Rutherfordium (Rf) in anion-exchange chromatography with hydrofluoric acid solution

Toyoshima, Atsushi; Haba, Hiromitsu*; Tsukada, Kazuaki; Asai, Masato; Akiyama, Kazuhiko; Nishinaka, Ichiro; Nagame, Yuichiro; Saika, Daisuke*; Matsuo, Keishi*; Sato, Wataru*; et al.

Journal of Nuclear and Radiochemical Sciences, 5(2), p.45 - 48, 2004/12

no abstracts in English

Oral presentation

Formation of anionic chloride complex of Rutherfordium (Rf)

Tsukada, Kazuaki; Toyoshima, Atsushi; Haba, Hiromitsu*; Asai, Masato; Akiyama, Kazuhiko*; Ishii, Yasuo; Tome, Hayato*; Nishinaka, Ichiro; Sato, Tetsuya; Ichikawa, Takatoshi; et al.

no journal, , 

no abstracts in English

Oral presentation

TBP reversed-phase extraction chromatography of Rutherfordium in the HCl solution

Toyoshima, Atsushi; Haba, Hiromitsu*; Tsukada, Kazuaki; Asai, Masato; Akiyama, Kazuhiko*; Ishii, Yasuo; Tome, Hayato*; Nishinaka, Ichiro; Sato, Tetsuya; Ichikawa, Takatoshi; et al.

no journal, , 

no abstracts in English

Oral presentation

Chloride complex formation of Rf in HCl and CH$$_{3}$$OH mixed solution

Tsukada, Kazuaki; Toyoshima, Atsushi; Haba, Hiromitsu*; Asai, Masato; Akiyama, Kazuhiko*; Ishii, Yasuo; Tome, Hayato; Nishinaka, Ichiro; Sato, Tetsuya; Ichikawa, Shinichi; et al.

no journal, , 

no abstracts in English

Oral presentation

Changes in water distribution and formation of defensive tissue in wounded trees

Yamada, Toshihiro*; Nagaishi, Norimichi*; Yamashita, Tokuo*; Koyama, Tsuneo*; Kaniwa, Masanori*; Oshima, Wataru*; Iikura, Hiroshi

no journal, , 

no abstracts in English

Oral presentation

Oxidation of nobelium

Toyoshima, Atsushi; Kasamatsu, Yoshitaka; Kitatsuji, Yoshihiro; Tsukada, Kazuaki; Ishii, Yasuo; Tome, Hayato; Asai, Masato; Haba, Hiromitsu*; Akiyama, Kazuhiko*; Oe, Kazuhiro*; et al.

no journal, , 

no abstracts in English

60 (Records 1-20 displayed on this page)