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Journal Articles

Intercalative and non-intercalative photo-recharge using all-solid-state cells for solar energy conversion and storage

Yoshimoto, Masataka*; Tamura, Kazuhisa; Watanabe, Kenta*; Shimizu, Keisuke*; Horisawa, Yuhei*; Kobayashi, Takeshi*; Tsurita, Hanae*; Suzuki, Kota*; Kanno, Ryoji*; Hirayama, Masaaki*

Sustainable Energy & Fuels (Internet), 8(6), p.1236 - 1244, 2024/03

 Times Cited Count:0

Photo-rechargeable systems, which can efficiently convert and store solar energy into chemical energy within single devices, are essential to harness sunlight effectively. Photo-(de)intercalation plays a pivotal role in the functionality of photorechargeable systems. Nevertheless, the photo-(de)intercalation process has not been conclusively confirmed owing to potential interference from side reactions, such as the decomposition of liquid electrolytes and the elution of electrode materials. In this study, we successfully demonstrated photo-responsive Li$$^{+}$$-deintercalation using an all-solid-state thin-film battery comprised of epitaxially-grown anatase TiO$$_{2}$$ doped with Nb (a-TiO$$_{2}$$:Nb) as the cathode. Under light irradiation, Li$$^{+}$$-deintercalation occurred and was subsequently reversibly intercalated into a-TiO$$_{2}$$:Nb during discharge.

Journal Articles

Latent ion tracks were finally observed in diamond

Amekura, Hiroshi*; Chettah, A.*; Narumi, Kazumasa*; Chiba, Atsuya*; Hirano, Yoshimi*; Yamada, Keisuke*; Yamamoto, Shunya*; Leino, A. A.*; Djurabekova, F.*; Nordlund, K.*; et al.

Nature Communications (Internet), 15, p.1786_1 - 1786_10, 2024/02

Injecting high-energy heavy ions in the electronic stopping regime into solids can create cylindrical damage zones called latent ion tracks. Although these tracks form in many materials, none have ever been observed in diamond, even when irradiated with high-energy GeV uranium ions. Here we report the first observation of ion track formation in diamond irradiated with 2-9 MeV C$$_{60}$$ fullerene ions. Depending on the ion energy, the mean track length (diameter) changed from 17 (3.2) nm to 52 (7.1) nm. High resolution scanning transmission electron microscopy (HR-STEM) indicated the amorphization in the tracks, in which $$pi$$-bonding signal from graphite was detected by the electron energy loss spectroscopy (EELS).

Journal Articles

Preliminary study of the criticality monitoring method based on the simulation for the activity ratio of short half-life noble-gas fission products from fuel debris

Riyana, E. S.; Okumura, Keisuke; Sakamoto, Masahiro; Matsumura, Taichi; Terashima, Kenichi; Kanno, Ikuo

Journal of Nuclear Science and Technology, 8 Pages, 2024/00

 Times Cited Count:0 Percentile:0.18(Nuclear Science & Technology)

Journal Articles

Corrigendum to "Visualization of the working fluid in a flat-plate pulsating heat pipe by neutron radiography" [International Journal of Heat and Mass Transfer 185 (2022) 122336]

Yasuda, Yosuke*; Matsumoto, Yoshihiro*; Shinohara, Takenao; Nabeshima, Fumika*; Horiuchi, Keisuke*; Nagai, Hiroki*

International Journal of Heat and Mass Transfer, 213, p.124291_1 - 124291_2, 2023/10

 Times Cited Count:0 Percentile:1.04(Thermodynamics)

Journal Articles

Development of coupling technology for high temperature gas-cooled reactors and hydrogen production facility; HTTR heat application test project plan

Ishii, Katsunori; Morita, Keisuke; Noguchi, Hiroki; Aoki, Takeshi; Mizuta, Naoki; Hasegawa, Takeshi; Nagatsuka, Kentaro; Nomoto, Yasunobu; Shimizu, Atsushi; Iigaki, Kazuhiko; et al.

Dai-27-Kai Doryoku, Enerugi Gijutsu Shimpojiumu Koen Rombunshu (Internet), 4 Pages, 2023/09

Journal Articles

Evaluation of the remaining spent extraction solvent in vermiculite after leaching tests via PIXE analysis

Arai, Yoichi; Watanabe, So; Hasegawa, Kenta; Okamura, Nobuo; Watanabe, Masayuki; Takeda, Keisuke*; Fukumoto, Hiroki*; Ago, Tomohiro*; Hagura, Naoto*; Tsukahara, Takehiko*

Nuclear Instruments and Methods in Physics Research B, 542, p.206 - 213, 2023/09

 Times Cited Count:0 Percentile:0.02(Instruments & Instrumentation)

Journal Articles

Equipment renewal, facility improvement, and dismantling / removal in the glove-box at basic laboratory of Plutonium Conversion Development Facility

Umino, Yoshinori; Kato, Keisuke; Tanigawa, Masafumi; Kobayashi, Daisuke; Obu, Tomoyuki; Kimura, Yuichi*; Nemoto, Ryo*; Tajiri, Kazuma*

Nihon Hozen Gakkai Dai-19-Kai Gakujutsu Koenkai Yoshishu, p.33 - 36, 2023/08

In the basic laboratory of the Plutonium Conversion Development Facility in Tokai Reprocessing Plant, tests had been conducted to obtain effective data for manufacturing mixed plutonium and uranium oxide powder by irradiating a mixture of plutonium and uranium solution with microwaves. The test has already been completed, and we are currently dismantling and removing equipment. In this paper, techniques related to equipment renewal, dismantling and removal works inside the glove-box are discussed.

JAEA Reports

Differential pressure rise event for filters of HTTR primary helium gas circulators, 1; Investigation of differential pressure rise event

Nemoto, Takahiro; Arakawa, Ryoki; Kawakami, Satoru; Nagasumi, Satoru; Yokoyama, Keisuke; Watanabe, Masashi; Onishi, Takashi; Kawamoto, Taiki; Furusawa, Takayuki; Inoi, Hiroyuki; et al.

JAEA-Technology 2023-005, 33 Pages, 2023/05

JAEA-Technology-2023-005.pdf:5.25MB

During shut down of the HTTR (High Temperature engineering Test Reactor) RS-14 cycle, an increasing trend of filter differential pressure for the helium gas circulator was observed. In order to investigate this phenomenon, the blower of the primary helium purification system was disassembled and inspected. As a result, it is clear that the silicon oil mist entered into the primary coolant due to the deterioration of the charcoal filter performance. The replacement and further investigation of the filter are planning to prevent the reoccurrence of the same phenomenon in the future.

Journal Articles

Development plan for coupling technology between high temperature gas-cooled reactor HTTR and hydrogen production facility, 1; Overview of the HTTR heat application test plan to establish high safety coupling technology

Nomoto, Yasunobu; Mizuta, Naoki; Morita, Keisuke; Aoki, Takeshi; Okita, Shoichiro; Ishii, Katsunori; Kurahayashi, Kaoru; Yasuda, Takanori; Tanaka, Masato; Isaka, Kazuyoshi; et al.

Proceedings of 30th International Conference on Nuclear Engineering (ICONE30) (Internet), 7 Pages, 2023/05

Journal Articles

Development plan for coupling technology between high temperature gas-cooled reactor HTTR and Hydrogen Production Facility, 2; Development plan for coupling equipment between HTTR and Hydrogen Production Facility

Mizuta, Naoki; Morita, Keisuke; Aoki, Takeshi; Okita, Shoichiro; Ishii, Katsunori; Kurahayashi, Kaoru; Yasuda, Takanori; Tanaka, Masato; Isaka, Kazuyoshi; Noguchi, Hiroki; et al.

Proceedings of 30th International Conference on Nuclear Engineering (ICONE30) (Internet), 6 Pages, 2023/05

Journal Articles

Investigation of niobium surface roughness and hydrogen content with different polishing conditions for performance recovery of superconducting QWRs in JAEA Tokai-Tandem Accelerator

Kamiya, Junichiro; Nii, Keisuke*; Kabumoto, Hiroshi; Kondo, Yasuhiro; Tamura, Jun; Harada, Hiroyuki; Matsui, Yutaka; Matsuda, Makoto; Moriya, Katsuhiro; Ida, Yoshiaki*; et al.

e-Journal of Surface Science and Nanotechnology (Internet), 21(4), p.344 - 349, 2023/05

no abstracts in English

Journal Articles

Origin of magnetically dead layers in spinel ferrites $$M$$Fe$$_2$$O$$_4$$ grown on Al$$_2$$O$$_3$$; Effects of postdeposition annealing studied by XMCD

Nonaka, Yosuke*; Wakabayashi, Yuki*; Shibata, Goro; Sakamoto, Shoya*; Ikeda, Keisuke*; Chi, Z.*; Wan, Y.*; Suzuki, Masahiro*; Tanaka, Arata*; Tanaka, Masaaki*; et al.

Physical Review Materials (Internet), 7(4), p.044413_1 - 044413_10, 2023/04

 Times Cited Count:0 Percentile:0(Materials Science, Multidisciplinary)

Journal Articles

Flow filtration/adsorption and simultaneous monitoring technologies of radiocesium $$^{137}$$Cs in river water

Enomoto, Kazuyuki*; Hoshina, Hiroyuki*; Kasai, Noboru*; Kurita, Keisuke; Ueki, Yuji*; Nagao, Yuto*; Yin, Y.-G.*; Suzui, Nobuo*; Kawachi, Naoki*; Seko, Noriaki*

Chemical Engineering Journal, 460, p.141696_1 - 141696_9, 2023/03

 Times Cited Count:1 Percentile:49.6(Engineering, Environmental)

This study develops a method that combines a radiation-grafting fibrous Cs-adsorbent filter of ammonium molybdophosphate (AMP) and a Ce:Gd$$_3$$Al$$_2$$Ga$$_3$$O$$_{12}$$ scintillator based $$gamma$$-ray detector for in situ measurements of the activity concentrations of $$^{137}$$Cs in a continuous water flow.

Journal Articles

Proposal on how to proceed with Verification and Validation of radiation shielding analyses

Okumura, Keisuke; Sakamoto, Yukio*; Tsukiyama, Toshihisa*

Shahei Kaiseki No V&V Gaidorain Sakutei Ni Mukete, p.4 - 8, 2023/03

no abstracts in English

Journal Articles

Neutron reflectivity study on the nanostructure of PMMA chains near substrate interfaces based on contrast variation accompanied with small molecule sorption

Shimokita, Keisuke*; Yamamoto, Katsuhiro*; Miyata, Noboru*; Nakanishi, Yohei*; Shibata, Motoki*; Takenaka, Mikihito*; Yamada, Norifumi*; Seto, Hideki*; Aoki, Hiroyuki; Miyazaki, Tsukasa*

Soft Matter, 19(11), p.2082 - 2089, 2023/03

 Times Cited Count:0 Percentile:0(Chemistry, Physical)

Journal Articles

Reports of electro-polishing implementation for quarter-wave resonators, 2

Nii, Keisuke*; Ida, Yoshiaki*; Ueda, Hideki*; Yamaguchi, Takanori*; Kabumoto, Hiroshi; Kamiya, Junichiro; Kondo, Yasuhiro; Tamura, Jun; Harada, Hiroyuki; Matsui, Yutaka; et al.

Proceedings of 19th Annual Meeting of Particle Accelerator Society of Japan (Internet), p.601 - 604, 2023/01

no abstracts in English

Journal Articles

Extraction properties of trivalent rare earth ions from nitric acid using a triamide-amine extractant

Uchino, Seiko*; Narita, Hirokazu*; Kita, Keisuke*; Suzuki, Hideya*; Matsumura, Tatsuro; Naganawa, Hirochika*; Sakaguchi, Koichi*; Oto, Keisuke*

Solvent Extraction Research and Development, Japan, 30(1), p.39 - 46, 2023/00

The extraction of trivalent rare earth ions (RE$$^{3+}$$) from HNO$$_{3}$$ solution using a triamide amine, tris(N,N-di-2-ethylhexyl-ethylamide)amine (DEHTAA), was conducted, and the extraction mechanism was estimated from extraction behavior of HNO$$_{3}$$ and RE$$^{3+}$$ and the relationship between atomic number and extraction percentages (E%) for RE$$^{3+}$$. A DEHTAA molecule dominantly formed a DEHTAA HNO$$_{3}$$ at 1.0 M HNO$$_{3}$$ and a DEHTAA(HNO$$_{3}$$)$$_{2}$$ at 6.0 M HNO$$_{3}$$ in the acid-equilibrated organic phase. This would provide the unique dependence of E% for the light RE$$^{3+}$$ on the HNO$$_{3}$$ concentration, in which the E% value had a minimum and maximum at $$sim$$0.5 M and $$sim$$2 M HNO$$_{3}$$, respectively. The results of the slope analyses for the distribution ratios for RE$$^{3+}$$ suggested that the dominant RE$$^{3+}$$ complex was RE(NO$$_{3}$$)$$_{3}$$DEHTAA(DEHTAA HNO$$_{3}$$) at 1.0 M HNO$$_{3}$$. The E% for RE$$^{3+}$$ decreased from La$$^{3+}$$ to Lu$$^{3+}$$ at 1.0 M HNO$$_{3}$$; on the other hand, those increased from La$$^{3+}$$ to Nd$$^{3+}$$ at 0.25 M and from La$$^{3+}$$ to Sm$$^{3+}$$ and 6.0 M HNO$$_{3}$$.

Journal Articles

Structural change by phosphorus addition to borosilicate glass containing simulated waste components

Okamoto, Yoshihiro; Shiwaku, Hideaki; Shimamura, Keisuke*; Kobayashi, Hidekazu; Nagai, Takayuki; Inose, Takehiko*; Sato, Seiichi*; Hatakeyama, Kiyoshi*

Journal of Nuclear Materials, 570, p.153962_1 - 153962_13, 2022/11

Simulated nuclear waste glass samples containing phosphorus, which increase the solubility of molybdenum, were prepared and analyzed using synchrotron X-ray Absorption Fine Structure (XAFS) analysis for some constituent elements and Raman spectroscopic analysis of their complex structure. Changes in local structure and chemical state due to different phosphorus additions and waste loading rates were systematically studied. Consequently, no crystalline phase due to the molybdate compound was observed even at a maximum waste content of 30 wt% (corresponding to 1.87 mol% MoO$$_3$$). Oxidation proceeded when the waste-loading rate was increased, whereas the reduction proceeded when phosphorus was added. In some cases, the effects of oxidation and reduction were offset. The local structure around specific elements can be classified as follows; Zn that is affected mainly by the waste-loading rate, Ce that is affected by both the waste-loading rate and phosphorus addition, and Zr element that is not affected by either of them. From the comparison between the analytical results of Mo and other elements, it was considered that the added phosphorus exists as a free PO$$_4$$ structural unit and may deprive the alkali metal coordinated to the molybdate ion.

Journal Articles

Neutron reflectivity study on the suppression of interfacial water accumulation between a polypropylene thin film and Si substrate using a silane-coupling agent

Shimokita, Keisuke*; Yamamoto, Katsuhiro*; Miyata, Noboru*; Arima-Osonoi, Hiroshi*; Nakanishi, Yohei*; Takenaka, Mikihito*; Shibata, Motoki*; Yamada, Norifumi*; Seto, Hideki*; Aoki, Hiroyuki; et al.

Langmuir, 38(41), p.12457 - 12465, 2022/10

 Times Cited Count:0 Percentile:0(Chemistry, Multidisciplinary)

Journal Articles

Materials science and fuel technologies of uranium and plutonium mixed oxide

Kato, Masato; Machida, Masahiko; Hirooka, Shun; Nakamichi, Shinya; Ikusawa, Yoshihisa; Nakamura, Hiroki; Kobayashi, Keita; Ozawa, Takayuki; Maeda, Koji; Sasaki, Shinji; et al.

Materials Science and Fuel Technologies of Uranium and Plutonium mixed Oxide, 171 Pages, 2022/10

Innovative and advanced nuclear reactors using plutonium fuel has been developed in each country. In order to develop a new nuclear fuel, irradiation tests are indispensable, and it is necessary to demonstrate the performance and safety of nuclear fuels. If we can develop a technology that accurately simulates irradiation behavior as a technology that complements the irradiation test, the cost, time, and labor involved in nuclear fuel research and development will be greatly reduced. And safety and reliability can be significantly improved through simulation of nuclear fuel irradiation behavior. In order to evaluate the performance of nuclear fuel, it is necessary to know the physical and chemical properties of the fuel at high temperatures. And it is indispensable to develop a behavior model that describes various phenomena that occur during irradiation. In previous research and development, empirical methods with fitting parameters have been used in many parts of model development. However, empirical techniques can give very different results in areas where there is no data. Therefore, the purpose of this study is to construct a scientific descriptive model that can extrapolate the basic characteristics of fuel to the composition and temperature, and to develop an irradiation behavior analysis code to which the model is applied.

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