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Journal Articles

Hexafluoro complex of rutherfordium in mixed HF/HNO$$_{3}$$ solutions

Toyoshima, Atsushi; Haba, Hiromitsu*; Tsukada, Kazuaki; Asai, Masato; Akiyama, Kazuhiko*; Goto, Shinichi*; Ishii, Yasuo; Nishinaka, Ichiro; Sato, Tetsuya; Nagame, Yuichiro; et al.

Radiochimica Acta, 96(3), p.125 - 134, 2008/03

https://doi.org/10.1524/ract.2008.1474
 Times Cited Count：28 Percentile：85.1(Chemistry, Inorganic & Nuclear)

Formation of an anionic fluoride-complex of element 104, rutherfordium (Rf) produced in the $$^{248}$$Cm($$^{18}$$O,5n)$$^{261}$$Rf reaction was studied by an anion-exchange method based on an atom-at-a-time scale. It was found that the hexafluoro complex of Rf, [RfF$$_{6}$$]$$^{2-}$$, was formed in the studied fluoride ion concentrations of 0.0005 - 0.013 M. Formation of [RfF$$_{6}$$]$$^{2-}$$ was significantly different from that of the homologues Zr and Hf, [ZrF$$_{6}$$]$$^{2-}$$ and [HfF$$_{6}$$]$$^{2-}$$; the evaluated formation constant of [RfF$$_{6}$$]$$^{2-}$$ is at least one-order of magnitude smaller than those of [ZrF$$_{6}$$]$$^{2-}$$ and [HfF$$_{6}$$]$$^{2-}$$.

Journal Articles

Chemical studies on rutherfordium (Rf) at JAERI

Nagame, Yuichiro; Tsukada, Kazuaki; Asai, Masato; Toyoshima, Atsushi; Akiyama, Kazuhiko; Ishii, Yasuo; Sato, Tetsuya; Hirata, Masaru; Nishinaka, Ichiro; Ichikawa, Shinichi; et al.

Radiochimica Acta, 93(9-10), p.519 - 526, 2005/00

https://doi.org/10.1524/ract.2005.93.9-10.519
 Times Cited Count：30 Percentile：87.1(Chemistry, Inorganic & Nuclear)

no abstracts in English

Journal Articles

Elution curve of Rutherfordium (Rf) in anion-exchange chromatography with hydrofluoric acid solution

Toyoshima, Atsushi; Haba, Hiromitsu*; Tsukada, Kazuaki; Asai, Masato; Akiyama, Kazuhiko; Nishinaka, Ichiro; Nagame, Yuichiro; Saika, Daisuke*; Matsuo, Keishi*; Sato, Wataru*; et al.

Journal of Nuclear and Radiochemical Sciences, 5(2), p.45 - 48, 2004/12

https://doi.org/10.14494/jnrs2000.5.45

no abstracts in English

3 (Records 1-3 displayed on this page)
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