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Journal Articles

PSTEP: Project for solar-terrestrial environment prediction

Kusano, Kanya*; Ichimoto, Kiyoshi*; Ishii, Mamoru*; Miyoshi, Yoshizumi*; Yoden, Shigeo*; Akiyoshi, Hideharu*; Asai, Ayumi*; Ebihara, Yusuke*; Fujiwara, Hitoshi*; Goto, Tadanori*; et al.

Earth, Planets and Space (Internet), 73(1), p.159_1 - 159_29, 2021/12

 Times Cited Count:6 Percentile:51.19(Geosciences, Multidisciplinary)

The PSTEP is a nationwide research collaboration in Japan and was conducted from April 2015 to March 2020, supported by a Grant-in-Aid for Scientific Research on Innovative Areas from the Ministry of Education, Culture, Sports, Science and Technology of Japan. It has made a significant progress in space weather research and operational forecasts, publishing over 500 refereed journal papers and organizing four international symposiums, various workshops and seminars, and summer school for graduate students at Rikubetsu in 2017. This paper is a summary report of the PSTEP and describes the major research achievements it produced.

Journal Articles

Incorporation of U, Pb and rare earth elements in calcite through crystallisation from amorphous calcium carbonate; Simple preparation of reference materials for microanalysis

Miyajima, Yusuke*; Saito, Ayaka*; Kagi, Hiroyuki*; Yokoyama, Tatsunori; Takahashi, Yoshio*; Hirata, Takafumi*

Geostandards and Geoanalytical Research, 45(1), p.189 - 205, 2021/03

 Times Cited Count:5 Percentile:21.77(Geochemistry & Geophysics)

Uncertainty for elemental and isotopic analyses of calcite by LA-ICP-MS is largely controlled by the homogeneity of the reference materials (RMs) used for normalization and validation. In order to produce calcite RMs with homogeneous elemental and isotopic compositions, we incorporated elements including U, Pb, and rare earth elements into calcite through heat- and pressure-induced crystallization from amorphous calcium carbonate that was precipitated from element-doped reagent solution. X-ray absorption spectra showed that U was present as U(VI) in the synthesized calcite, probably with a different local structure from that of aqueous uranyl ions. The uptake rate of U by our calcite was higher in comparison to synthetic calcite of previous studies. Variations of element mass fractions in the calcite were better than 12% 2RSD, mostly within 7%. The $$^{207}$$Pb/$$^{206}$$Pb ratio in the calcite showed $$<$$1% variations, while the $$^{238}$$U/$$^{206}$$Pb ratio showed 3-24% variations depending on element mass fractions. Using the synthetic calcite as primary RMs, we could date a natural calcite RM, WC-1, with analytical uncertainty as low as $$<$$3%. The method presented can be useful to produce calcite with controlled and homogeneous element mass fractions, and is a promising alternative to natural calcite RMs for U-Pb geochronology.

Journal Articles

Quasifree neutron knockout reaction reveals a small $$s$$-Orbital component in the Borromean nucleus $$^{17}$$B

Yang, Z. H.*; Kubota, Yuki*; Corsi, A.*; Yoshida, Kazuki; Sun, X.-X.*; Li, J. G.*; Kimura, Masaaki*; Michel, N.*; Ogata, Kazuyuki*; Yuan, C. X.*; et al.

Physical Review Letters, 126(8), p.082501_1 - 082501_8, 2021/02

AA2020-0819.pdf:1.29MB

 Times Cited Count:43 Percentile:96.7(Physics, Multidisciplinary)

A quasifree ($$p$$,$$pn$$) experiment was performed to study the structure of the Borromean nucleus $$^{17}$$B, which had long been considered to have a neutron halo. By analyzing the momentum distributions and exclusive cross sections, we obtained the spectroscopic factors for $$1s_{1/2}$$ and $$0d_{5/2}$$ orbitals, and a surprisingly small percentage of 9(2)% was determined for $$1s_{1/2}$$. Our finding of such a small $$1s_{1/2}$$ component and the halo features reported in prior experiments can be explained by the deformed relativistic Hartree-Bogoliubov theory in continuum, revealing a definite but not dominant neutron halo in $$^{17}$$B. The present work gives the smallest $$s$$- or $$p$$-orbital component among known nuclei exhibiting halo features and implies that the dominant occupation of $$s$$ or $$p$$ orbitals is not a prerequisite for the occurrence of a neutron halo.

Journal Articles

Comprehensive extraction study using $$N$$,$$N$$-dioctyldiglycolamic acid

Shimojo, Kojiro; Nakai, Ayaka*; Okamura, Hiroyuki; Saito, Takumi*; Ohashi, Akira*; Naganawa, Hirochika

Analytical Sciences, 30(4), p.513 - 517, 2014/04

 Times Cited Count:15 Percentile:48.57(Chemistry, Analytical)

Journal Articles

Growth and characterization of bismuth magnesium titanate Bi(Mg$$_{1/2}$$Ti$$_{1/2}$$)0$$_3$$

Yoneda, Yasuhiro; Saito, Hiroyuki; Yoshii, Kenji; Nishida, Takashi*; Hayakawa, Hironori*; Ikeda, Naoshi*

Key Engineering Materials, 421-422, p.30 - 33, 2010/00

Polycrystalline Bi(Mg$$_{1/2}$$Ti$$_{1/2}$$)O$$_3$$ samples were prepared under high pressure. A mixed powder of Bi$$_2$$O$$_3$$, Ti$$_2$$O$$_3$$ and MgO with a prescribed ratio was packed into platinum cell and was heated a cubic anvil-type apparatus at 6.5 GPa and 1000 $$^circ$$C. The obtained samples were characterized by powder X-ray diffraction measurements. Although some impurity peaks existed, the main peaks were perovskite peaks. The structure of Bi(Mg$$_{1/2}$$Ti$$_{1/2}$$)O$$_3$$ is rhombohedral, as well as BiFeO$$_3$$. The D-E hysteresis loop was not saturated due to the impurities, but the possibility as ferroelectric can be expected enough.

Journal Articles

The H-Invitational Database (H-InvDB); A Comprehensive annotation resource for human genes and transcripts

Yamasaki, Chisato*; Murakami, Katsuhiko*; Fujii, Yasuyuki*; Sato, Yoshiharu*; Harada, Erimi*; Takeda, Junichi*; Taniya, Takayuki*; Sakate, Ryuichi*; Kikugawa, Shingo*; Shimada, Makoto*; et al.

Nucleic Acids Research, 36(Database), p.D793 - D799, 2008/01

 Times Cited Count:51 Percentile:71.25(Biochemistry & Molecular Biology)

Here we report the new features and improvements in our latest release of the H-Invitational Database, a comprehensive annotation resource for human genes and transcripts. H-InvDB, originally developed as an integrated database of the human transcriptome based on extensive annotation of large sets of fulllength cDNA (FLcDNA) clones, now provides annotation for 120 558 human mRNAs extracted from the International Nucleotide Sequence Databases (INSD), in addition to 54 978 human FLcDNAs, in the latest release H-InvDB. We mapped those human transcripts onto the human genome sequences (NCBI build 36.1) and determined 34 699 human gene clusters, which could define 34 057 protein-coding and 642 non-protein-coding loci; 858 transcribed loci overlapped with predicted pseudogenes.

Journal Articles

Impregnation of an acidic extractant cyanex 272 to the alkylamino group and alkylthiol group introduced into the polymer chain grafted onto a porous membrane

Sawaki, Kenta*; Domon, Sayaka*; Asai, Shiho; Watanabe, Kazuo; Sugo, Takanobu*; Saito, Kyoichi*

Maku, 32(2), p.109 - 115, 2007/03

no abstracts in English

Journal Articles

Selection of the alkylamino group introduced into the polymer chain grafted onto a porous membrane for the impregnation of an acidic extractant

Domon, Sayaka*; Asai, Shiho; Saito, Kyoichi*; Watanabe, Kazuo; Sugo, Takanobu*

Journal of Membrane Science, 262(1-2), p.153 - 158, 2005/10

 Times Cited Count:16 Percentile:49.92(Engineering, Chemical)

no abstracts in English

Oral presentation

Preparation of extractant impregnated porous membrane for separation of metal ions

Sawaki, Kenta*; Asai, Shiho; Domon, Sayaka*; Saito, Kyoichi*; Sugo, Takanobu*

no journal, , 

no abstracts in English

Oral presentation

Synthesis and homogeneity evaluation of reference calcite for U-Pb dating of carbonates

Miyajima, Yusuke*; Saito, Ayaka*; Kagi, Hiroyuki*; Yokoyama, Tatsunori; Hirata, Takafumi*

no journal, , 

no abstracts in English

Oral presentation

Synthesis of calcite reference materials for in situ U-Pb dating through crystallization from amorphous calcium carbonates

Miyajima, Yusuke*; Saito, Ayaka*; Kagi, Hiroyuki*; Yokoyama, Tatsunori; Hirata, Takafumi*

no journal, , 

Calcium carbonates are ubiquitously present throughout the Earth history as animal shells, speleothems, fault-related vein fillings, and hydrothermal or cold-seep precipitates. Direct dating of carbonates provides valuable information on paleoenvironmental change, tectonics, and fluid and material cycling. U-Pb dating using high spatial-resolution LA-ICP-MS is a key technique to date natural carbonates. In situ U-Pb dating by LA-ICP-MS needs matrix-matched reference materials to correct matrix-dependent elemental fractionation in LA-ICP-MS. Roberts et al. (2017) demonstrated that a natural calcite cement WC-1 is suitable as a calcite reference material. However, the WC-1 calcite has an inhomogeneous distribution of U and Pb and lacks concordance in the U-Pb system. In this study, we synthesized novel calcite reference materials with homogeneous U and Pb concentrations and isotope ratios. We incorporated U and Pb into calcite through heat-induced crystallization from U, Pb-doped amorphous calcium carbonate (ACC). The homogeneity of the U/Ca and Pb/Ca ratios in the synthetic calcite was generally better than 8% and 13%, respectively, in relative standard deviation. The $$^{207}$$Pb/$$^{206}$$Pb ratio of the synthetic calcite was homogeneous within ~1% errors, whereas the $$^{238}$$U/$$^{206}$$Pb ratio was less homogeneous (3%-11% errors). To test the usability of the synthetic calcite, we dated WC-1 using the synthetic calcite for correction of elemental fractionation. We calculated the nominal $$^{238}$$U/$$^{206}$$Pb ratio in the synthetic calcite from its U and Pb concentrations. We then obtained the fractionation factor to correct bias between the isotope ratios and the nominal value. We could accurately date WC-1 with an ~3% precision. If the isotopic compositions of the synthetic calcite are certified by isotope-dilution technique, we could date natural carbonates with $$<$$10% precisions using the synthetic reference calcite.

Oral presentation

Synthesis of U and Pb-doped calcite; A Novel reference material for in situ U-Pb dating of carbonate

Miyajima, Yusuke*; Saito, Ayaka*; Kagi, Hiroyuki*; Yokoyama, Tatsunori; Hirata, Takafumi*; Roberts, N. M. W.*; Horstwood, M.*

no journal, , 

Direct age determination of carbonate minerals provides valuable insight to paleoenvironmental change, tectonics, and sub-surface fluid-flow. The U-Pb method using laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) is a key technique to date natural carbonates such as fault-hosted calcite that cannot be dated by biostratigraphy or Sr isotope stratigraphy. A natural calcite cement WC-1 (254.4 $$pm$$ 6.4 Ma) is suitable as a reference material to correct elemental fractionation with LA-ICP-MS. However, the resulting uncertainty on a sample date is limited by the heterogeneity of U and Pb distribution in the reference material. Our objective is to synthesize calcite with homogeneous U and Pb concentrations and isotope ratios to be used as novel reference materials. To achieve this, we incorporate incompatible U and Pb into calcite through heat-induced crystallization from amorphous calcium carbonate precipitated from U, Pb-doped reagent solution. LA-ICP-MS analyses of results so far revealed that the U/Ca and Pb/Ca ratios in the synthetic calcites were generally homogeneous with relative standard deviation (2SD, n = 10) better than 4% and 7%, respectively. The Pb/Ca homogeneity of calcites doped with $$<$$1 $$mu$$g/g Pb was up to ~25%. The $$^{207}$$Pb/$$^{206}$$Pb ratio of the synthetic calcites was very homogeneous with $$<$$ 1% variation, whereas the $$^{238}$$U/$$^{206}$$Pb ratio was less homogeneous (2%$$sim$$7% variation). To evaluate the suitability of the synthetic calcite as a reference material, we measured the age of WC-1 using the synthetic calcite for elemental fractionation correction; we could date WC-1 with a precision and accuracy of ~3% (246.6 $$pm$$ 7.3 Ma). This method is a promising alternative in addition to characterising natural carbonate materials for elemental and isotopic composition.

Oral presentation

Physical properties test for flowability of K-based alkali-activated materials

Hiraki, Yoshihisa; Saito, Toshimitsu*; Kakuda, Ayaka; Osugi, Takeshi; Sone, Tomoyuki; Kuroki, Ryoichiro; Kudo, Isamu*; Elakneswaran, Y.*; Sato, Tsutomu*

no journal, , 

no abstracts in English

Oral presentation

Physical properties of K-based alkali-activated materials containing iron coprecipitation slurry

Hiraki, Yoshihisa; Kakuda, Ayaka; Saito, Toshimitsu*; Osugi, Takeshi; Sone, Tomoyuki; Kuroki, Ryoichiro; Elakneswaran, Y.*; Sato, Tsutomu*

no journal, , 

no abstracts in English

Oral presentation

Factors derived from metakaolin that cause changes in physical properties of alkali-activated materials

Hiraki, Yoshihisa; Kakuda, Ayaka; Saito, Toshimitsu*; Sone, Tomoyuki; Elakneswaran, Y.*; Sato, Tsutomu*; Osugi, Takeshi; Kuroki, Ryoichiro

no journal, , 

no abstracts in English

15 (Records 1-15 displayed on this page)
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