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Ikusawa, Yoshihisa; Morimoto, Kyoichi; Kato, Masato; Saito, Kosuke; Uno, Masayoshi*
Nuclear Technology, 205(3), p.474 - 485, 2019/03
Times Cited Count：2 Percentile：21.58(Nuclear Science & Technology)This study evaluated the effects of plutonium content and self-irradiation on the thermal conductivity of mixed-oxide (MOX) fuel. Samples of UO
fuel and various MOX fuels were tested. The MOX fuels had a range of plutonium contents, and some samples were stored for 20 years. The thermal conductivity of these samples was determined from thermal diffusivity measurements taken via laser flash analysis. Although the thermal conductivity decreased with increasing plutonium content, this effect was slight. The effect of self-irradiation was investigated using the stored samples. The reduction in thermal conductivity caused by self-irradiation depended on the plutonium content, its isotopic composition, and storage time. The reduction in thermal conductivity over 20 years' storage can be predicted from the change of lattice parameter. In addition, the decrease in thermal conductivity caused by self-irradiation was recovered with heat treatment, and recovered almost completely at temperatures over 1200 K. From these evaluation results, we formulated an equation for thermal conductivity that is based on the classical phonon-transport model. This equation can predict the thermal conductivity of MOX fuel thermal conductivity by accounting for the influences of plutonium content and self-irradiation.
Zr determination with isotope dilution ICP-MSAsai, Shiho; Hanzawa, Yukiko; Konda, Miki; Suzuki, Daisuke; Magara, Masaaki; Kimura, Takaumi; Ishihara, Ryo*; Saito, Kyoichi*; Yamada, Shinsuke*; Hirota, Hideyuki*
Talanta, 185, p.98 - 105, 2018/08
Times Cited Count：8 Percentile：31.98(Chemistry, Analytical)Estimating the risks associated with radiation from long-lived fission products (LLFP) in radioactive waste is essential to ensure the long-term safety of potential disposal sites. In this study, the amount of Zr, a LLFP, was determined by ICP-MS after separating Zr from a spent nuclear fuel solution using a microvolume anion-exchange cartridge (TEDA cartridge). The TEDA cartridge achieved highly selective separation of Zr regardless of its small bed volume of 0.08 cm
. The time taken to complete the Zr separation was 1.2 min with a flow rate of 1.5 mL/min, which was 10 times faster than that for a conventional anion-exchange resin column. Almost all the other elements were removed, leading to accurate measurement of Zr. The result connects experimental value to theoretical prediction provided by ORIGEN2, which requires verification. With the measured value, we demonstrated that the theoretical value is reliable enough to estimate radiation risks.
Saito, Kyoichi*; Asai, Shiho
Bunseki Kagaku, 66(11), p.771 - 782, 2017/11
Times Cited Count：1 Percentile：3.41(Chemistry, Analytical)Recovery and purification of rare metals, which are essential ingredients for highly functional materials, generally comes with operational difficulty. In this study, we have developed polymer adsorbents specially designed for highly-efficient adsorption of rare metal ions and exhibited their practical adsorption performances. Radiation-induced graft polymerization, one of the effective modification techniques for polymers, was employed for preparing the proposed adsorbents. Among such adsorbents, a 6-nylon fiber with nucleic-acid base, adenine, on the surface of the fiber demonstrated specific adsorption of ruthenium and palladium ions. In addition, a 6-nylon fiber with an extractant HDEHP (bis (2-ethylhexyl) phophoric acid) that has high affinity for lanthanides, achieved higher separation speed than a commercially available HDEHP-impregnated resin.
Asai, Shiho; Saito, Kyoichi*
Biomedical Research on Trace Elements, 28(1), p.1 - 10, 2017/04
Radionuclides are commonly determined with radiometry and mass spectrometry. For 
-emitting nuclides, the activities can be measured without chemical separation due to the strong penetration ability. In contrast, the measurements of alpha and beta-emitting nuclides are generally associated with tedious and time-consuming chemical separation procedures to remove concomitants. Thus, an adsorbent that achieves rapid separation is desirable to reduce separation time and workload. Our research team has developed compact cartridge-type solid phase extraction materials which enable to facilitate separation procedures. In this review, basic separation performances of the developed cartridges were overviewed along with two application examples to radionuclide-containing samples.
Saito, Kyoichi*; Kojima, Takashi*; Asai, Shiho
Bunseki Kagaku, 66(4), p.233 - 242, 2017/04
Times Cited Count：1 Percentile：3.41(Chemistry, Analytical)Insoluble cobalt ferrocyanide and sodium titanate specifically capture cesium and strontium ions, respectively, in water contaminated with radionuclides which is found in Fukushima Daiichi NPP. The inorganic compounds used in this study were formed as precipitates in the polymer chain grafted onto a commercially available 6-nylon fiber using radiation-induced graft polymerization. An impregnation structure with the precipitates entangled by the grafted polymer chain through an electrostatic interaction via multipoints was indicated. The resultant insoluble cobalt ferrocyanide- or sodium titanate-impregnated fiber exhibited a higher adsorption rate and adsorption capacity per gram of the inorganic compound for cesium or strontium ions in seawater than conventional granular adsorbents.
Sr measurementHorita, Takuma; Asai, Shiho; Konda, Miki; Hanzawa, Yukiko; Saito, Kyoichi*; Fujiwara, Kunio*; Sugo, Takanobu*; Kitatsuji, Yoshihiro
Bunseki Kagaku, 66(3), p.189 - 193, 2017/03
Times Cited Count：1 Percentile：3.41(Chemistry, Analytical)A Sr-selective adsorption fiber was prepared for rapid analysis of Sr content by using radiation-induced emulsion graft polymerization and subsequent chemical modification. A polyethylene fiber with a diameter of 13 
m was first immersed in a methanol solution of an epoxy-group-containing vinyl monomer, glycidyl methacrylate (GMA), and polyoxyethylene sorbitol ester (Tween20) as a surfactant for graft-polymerization of GMA. Octadecylamine was then bound to a polymer chain extending from the fiber surface providing hydrophobicity to the polymer chain. Dicyclohexano-18-crown-6 (DCH18C6) was finally impregnated onto the polymer chain via a hydrophobic interaction between the octadecyl moiety of the polymer chain and the cyclohexyl moiety of DCH18C6. The fiber surface structure, characterized by DCH18C6 molecules loosely entangled with polymer chains, afforded realizes the rapid and selective adsorption of Sr ions with an adsorption rate approximately 100 times higher than that of a commercially available Sr-selective resin (Sr Resin).
Sako, Hiroyuki; Harada, Hiroyuki; Sakaguchi, Takao*; Chujo, Tatsuya*; Esumi, Shinichi*; Gunji, Taku*; Hasegawa, Shoichi; Hwang, S.; Ichikawa, Yudai; Imai, Kenichi; et al.
Nuclear Physics A, 956, p.850 - 853, 2016/12
Times Cited Count：12 Percentile：65.66(Physics, Nuclear)
Np content in spent nuclear fuelAsai, Shiho; Hanzawa, Yukiko; Konda, Miki; Suzuki, Daisuke; Magara, Masaaki; Kimura, Takaumi; Ishihara, Ryo*; Saito, Kyoichi*; Yamada, Shinsuke*; Hirota, Hideyuki*
Analytical Chemistry, 88(6), p.3149 - 3155, 2016/03
Times Cited Count：8 Percentile：29.82(Chemistry, Analytical)Neptunium-237 (Np) is one of the major long-lived radionuclides found in spent nuclear fuel. To evaluate the long-term safety of a HLW repository, the Np content in spent nuclear fuel must be determined. In this study, micro-volume anion-exchange porous polymer disk-packed cartridges were prepared for Am-Np separation, which is required prior to the measurement of Np with ICP-MS. Disks with a volume of 0.08 cm were cut out from porous sheets having triethylenediamine (TEDA)-containing polymer chains densely attached on the pore surface. The resulting TEDA-introduced disk cartridge was applied to a spent nuclear fuel sample. The chemical yield of Np was 90.4%, which is sufficiently high for ICP-MS measurement of Np. Compared with the conventional separation technique using commercially available anion-exchange resin columns, the time required to adsorb, wash and elute Np using the TEDA-introduced disk cartridge was reduced by 75%.
Someya, Takaaki*; Asai, Shiho; Fujiwara, Kunio*; Sugo, Takanobu*; Umeno, Daisuke*; Saito, Kyoichi*
Nihon Kaisui Gakkai-Shi, 69(1), p.42 - 48, 2015/02
A large amount of seriously contaminated sea water with radioactive Cs has been reserved in semi-enclosed coastal sea area which is separated by silt fences and embankments. Insoluble cobalt ferrocyanide (Co-FC) microparticles-impregnated fiber was developed for removing Cs from the contaminated sea water. The resultant Co-FC-impregnated fiber was immersed in either nonradioactive or radioactive Cs solution. The adsorption isotherm well correlated with a Langmuir-type equation. In addition, mass-transfer capacity coefficients were determined by fitting the experimental data of the rate of Cs adsorption onto the Co-FC-impregnated fiber to theoretical adsorption curves based on the Cs concentration difference between the bulk and the interface in seawater as a driving force of the overall adsorption rate. Decontamination factors as functions of fiber weight and the contact time required for the removal of cesium ions from the contaminated seawater in a closed area were estimated.
Tanaka, Ryota*; Ishihara, Ryo*; Miyoshi, Kazuyoshi*; Umeno, Daisuke*; Saito, Kyoichi*; Asai, Shiho; Yamada, Shinsuke*; Hirota, Hideyuki*
Separation Science and Technology, 49(1), p.154 - 159, 2014/01
Times Cited Count：4 Percentile：16.82(Chemistry, Multidisciplinary)Uchiyama, Shoichiro*; Ishihara, Ryo*; Umeno, Daisuke*; Saito, Kyoichi*; Yamada, Shinsuke*; Hirota, Hideyuki*; Asai, Shiho
Journal of Chemical Engineering of Japan, 46(6), p.414 - 419, 2013/06
Times Cited Count：7 Percentile：26.06(Engineering, Chemical)Wada, Go*; Ishihara, Ryo*; Miyoshi, Kazuyoshi*; Umeno, Daisuke*; Saito, Kyoichi*; Asai, Shiho; Yamada, Shinsuke*; Hirota, Hideyuki*
Solvent Extraction and Ion Exchange, 31(2), p.210 - 220, 2013/02
Times Cited Count：2 Percentile：12.24(Chemistry, Multidisciplinary)A crosslinked chelating porous sheet was prepared by cografting ethylene glycol dimethacrylate (EGDMA) with glycidyl methacrylate onto an electron-beam-irradiated porous polyethylene sheet, followed by the introduction of an iminodiacetate group. At a molar percentage of EGDMA of 1.0 mol%, the sheet exhibited a maximum dynamic binding capacity for copper ions of 0.93 mmol/g, while the equilibrium binding capacity remained the same (1.2 mmol/g) as that of a non-crosslinked chelating porous sheet. The crosslinking of the grafted chain causes copper ions to lower their diffusion rate along the sheet thickness driven by the gradient of the amount of copper ions adsorbed.
Ishihara, Ryo*; Asai, Shiho; Otosaka, Shigeyoshi; Yamada, Shinsuke*; Hirota, Hideyuki*; Miyoshi, Kazuyoshi*; Umeno, Daisuke*; Saito, Kyoichi*
Solvent Extraction and Ion Exchange, 30(2), p.171 - 180, 2012/02
Times Cited Count：8 Percentile：31.67(Chemistry, Multidisciplinary)Ishihara, Ryo*; Fujiwara, Kunio*; Harayama, Takato*; Okamura, Yusuke*; Uchiyama, Shoichiro*; Sugiyama, Mai*; Someya, Takaaki*; Amakai, Wataru*; Umino, Satoshi*; Ono, Tsubasa*; et al.
Journal of Nuclear Science and Technology, 48(10), p.1281 - 1284, 2011/10
Times Cited Count：44 Percentile：94.73(Nuclear Science & Technology)
collisions at 
= 200 and 62.4 GeVAdare, A.*; Afanasiev, S.*; Aidala, C.*; Ajitanand, N. N.*; Akiba, Yasuyuki*; Al-Bataineh, H.*; Alexander, J.*; Aoki, Kazuya*; Aphecetche, L.*; Armendariz, R.*; et al.
Physical Review C, 83(6), p.064903_1 - 064903_29, 2011/06
Times Cited Count：184 Percentile：99.44(Physics, Nuclear)Transverse momentum distributions and yields for 
, and 
in collisions at = 200 and 62.4 GeV at midrapidity are measured by the PHENIX experiment at the RHIC. We present the inverse slope parameter, mean transverse momentum, and yield per unit rapidity at each energy, and compare them to other measurements at different collisions. We also present the scaling properties such as 
and 
scaling and discuss the mechanism of the particle production in collisions. The measured spectra are compared to next-to-leading order perturbative QCD calculations.
and Au+Au collisions at 
= 200 GeVAdare, A.*; Afanasiev, S.*; Aidala, C.*; Ajitanand, N. N.*; Akiba, Yasuyuki*; Al-Bataineh, H.*; Alexander, J.*; Aoki, Kazuya*; Aphecetche, L.*; Aramaki, Y.*; et al.
Physical Review C, 83(4), p.044912_1 - 044912_16, 2011/04
Times Cited Count：8 Percentile：49.7(Physics, Nuclear)Measurements of electrons from the decay of open-heavy-flavor mesons have shown that the yields are suppressed in Au+Au collisions compared to expectations from binary-scaled collisions. Here we extend these studies to two particle correlations where one particle is an electron from the decay of a heavy flavor meson and the other is a charged hadron from either the decay of the heavy meson or from jet fragmentation. These measurements provide more detailed information about the interaction between heavy quarks and the quark-gluon matter. We find the away-side-jet shape and yield to be modified in Au+Au collisions compared to collisions.
Wada, Go*; Ishihara, Ryo*; Miyoshi, Kazuyoshi*; Umeno, Daisuke*; Saito, Kyoichi*; Asai, Shiho; Yamada, Shinsuke*; Hirota, Hideyuki*
Nihon Ion Kokan Gakkai-Shi, 22(2), p.47 - 52, 2011/01
no abstracts in English
Miyazawa, Tadashi*; Asari, Yuki*; Miyoshi, Kazuyoshi*; Umeno, Daisuke*; Saito, Kyoichi*; Nagatani, Takeshi*; Yoshikawa, Naohito*; Motokawa, Ryuhei; Koizumi, Satoshi*
Nihon Kaisui Gakkai-Shi, 64(6), p.360 - 365, 2010/12
-octylphosphine oxide, and its adsorption/elution of bismuth ionsTanaka, Ryota*; Ishihara, Ryo*; Miyoshi, Kazuyoshi*; Umeno, Daisuke*; Saito, Kyoichi*; Asai, Shiho; Yamada, Shinsuke*; Hirota, Hideyuki*
Reactive and Functional Polymers, 70(12), p.986 - 990, 2010/12
Times Cited Count：7 Percentile：29.11(Chemistry, Applied)Asai, Shiho; Kimura, Takaumi; Miyoshi, Kazuyoshi*; Saito, Kyoichi*; Yamada, Shinsuke*; Hirota, Hideyuki*
Nihon Ion Kokan Gakkai-Shi, 21(3), p.334 - 339, 2010/07
