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Journal Articles

Regeneration of TEHDGA-impregnated adsorbents via solvent stripping and re-impregnation for application in extraction chromatography-based MA(III) separation

Ogawa, Akihiro*; Katsuki, Kenta*; Arai, Tsuyoshi*; Miyazaki, Yasunori; Watanabe, So; Sano, Yuichi; Takeuchi, Masayuki

Journal of Nuclear Science and Technology, 63(9), p.1015 - 1022, 2026/09

 Times Cited Count:1 Percentile:84.64(Nuclear Science & Technology)

This study aims to reduce waste derived from extractant-impregnated adsorbents by assessing the reusability of spent adsorbents generated during extraction chromatography for the separation of minor actinides (MA(III)) from high-level liquid waste (HLLW). Regeneration was investigated via (i) stripping of the extractant with organic solvents and (ii) re-impregnation of the support. n-dodecane and 1-octanol were examined as candidate solvents. In addition to evaluating stripping performance and the adsorption/elution performance of re-impregnated adsorbents, vacuum distillation was applied to the post-stripping solutions to separate and recover the extractant and solvent. The results demonstrate that the extractant can be stripped from the adsorbent by solvent treatment and that the adsorption and elution performance can be restored by re-impregnation. Furthermore, efficient separation of solvent and extractant from the stripping solution was achieved when n-dodecane was used.

Journal Articles

Microstructural characterization of electrodeposited nanocrystalline nickel films by X-ray diffraction

Tanaka, Keisuke*; Koike, Yuki*; Sano, Katsuki*; Tanaka, Hiroto*; Machiya, Shutaro*; Shobu, Takahisa; Kimachi, Hirohisa*

Zairyo, 64(7), p.528 - 535, 2015/07

no abstracts in English

Oral presentation

Basic research programs of vitrification technology for waste volume reduction, 122; Examination of MA separation process conditions using TEHDGA and HONTA adsorbents

Katsuki, Kenta*; Ishizawa, Kenta*; Arai, Tsuyoshi*; Watanabe, So; Sano, Yuichi; Takeuchi, Masayuki

no journal, , 

no abstracts in English

Oral presentation

Basic research programs of vitrification technology for waste volume reduction, 123; Study of removal method of adsorbed interfering elements by metastannic acid

Ichihara, Hirotsugu*; Katsuki, Kenta*; Arai, Tsuyoshi*; Watanabe, So; Sano, Yuichi; Takeuchi, Masayuki

no journal, , 

no abstracts in English

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