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hydridosilicate at high pressures; A Bridge to BaSiH
polyhydrideBeyer, D. C.*; Spektor, K.*; Vekilova, O. Y.*; Grins, J.*; Barros Brant Carvalho, P. H.*; Leinbach, L. J.*; Sannemo-Targama, M.*; Bhat, S.*; Baran, V.*; Etter, M.*; et al.
ACS Omega (Internet), 10(15), p.15029 - 15035, 2025/04
Times Cited Count：0 Percentile：0.00(Chemistry, Multidisciplinary)Hydridosilicates featuring SiH octahedral moieties represent a rather new class of compounds with potential properties relating to hydrogen storage and hydride ion conductivity. Here, we report on the new representative BaSiH obtained from reacting the Zintl phase hydride BaSiH
with H
fluid at pressures above 4 GPa and subsequent decompression to ambient pressure. It consists of complex SiH
ions, which are octahedrally coordinated by Ba
counterions. The arrangement of Ba and Si atoms deviates only slightly from an ideal fcc NaCl structure. IR and Raman spectroscopy showed SiH bending and stretching modes in the ranges 800-1200 and 1400-1800 cm
, respectively. BaSiH is thermally stable up to 95
C above which decomposition into BaH and Si takes place. DFT calculations indicated a direct band gap of 2.5 eV. The discovery of BaSiH consolidates the compound class of hydridosilicates, accessible from hydrogenations of silicides at gigapascal pressures (
10 GPa). The structural properties of BaSiH suggest that it presents an intermediate (or precursor) for further hydrogenation at considerably higher pressures to the predicted superconducting polyhydride BaSiH.
Uchida, Kazuto*; Masuda, Tsukuru*; Hara, Shintaro*; Matsuo, Yoichi*; Liu, Y.*; Aoki, Hiroyuki; Asano, Yoshihiko*; Miyata, Kazuki*; Fukuma, Takeshi*; Ono, Toshiya*; et al.
ACS Applied Materials & Interfaces, 16(30), p.39104 - 39116, 2024/07
Times Cited Count：1 Percentile：35.94(Nanoscience & Nanotechnology)Baccou, J.*; Glantz, T.*; Ghione, A.*; Sargentini, L.*; Fillion, P.*; Damblin, G.*; Sueur, R.*; Iooss, B.*; Fang, J.*; Liu, J.*; et al.
Nuclear Engineering and Design, 421, p.113035_1 - 113035_16, 2024/05
Times Cited Count：6 Percentile：97.32(Nuclear Science & Technology)
Linh, B. D.*; Corsi, A.*; Gillibert, A.*; Obertelli, A.*; Doornenbal, P.*; Barbieri, C.*; Duguet, T.*; G
mez-Ramos, M.*; Holt, J. D.*; Hu, B. S.*; et al.
Physical Review C, 109(3), p.034312_1 - 034312_15, 2024/03
Times Cited Count：2 Percentile：58.81(Physics, Nuclear)no abstracts in English
Be ground-state molecular structure using Be(
)
He triple differential reaction cross-section measurementsLi, P. J.*; Beaumel, D.*; Lee, J.*; Assi
, M.*; Chen, S.*; Franchoo, S.*; Gibelin, J.*; Hammache, F.*; Harada, T.*; Kanada-En'yo, Yoshiko*; et al.
Physical Review Letters, 131(21), p.212501_1 - 212501_7, 2023/11
Times Cited Count：21 Percentile：93.59(Physics, Multidisciplinary)The cluster structure of the neutron-rich isotope Be has been probed via the () reaction. The triple differential cross-section was extracted and compared to distorted-wave impulse approximation reaction calculations performed in a microscopic framework using the Tohsaki-Horiuchi-Schuck-R
pke wave function and the wave function deduced from Antisymmetrized Molecular Dynamics calculations. The remarkable agreement between calculated and measured cross-sections in both shape and magnitude validates the description of the Be ground-state as a rather compact nuclear molecule.
Ca cast doubt on a doubly magic 
CaChen, S.*; Browne, F.*; Doornenbal, P.*; Lee, J.*; Obertelli, A.*; Tsunoda, Yusuke*; Otsuka, Takaharu*; Chazono, Yoshiki*; Hagen, G.*; Holt, J. D.*; et al.
Physics Letters B, 843, p.138025_1 - 138025_7, 2023/08
Times Cited Count：9 Percentile：85.35(Astronomy & Astrophysics)Gamma decays were observed in 
Ca and 
Ca following quasi-free one-proton knockout reactions from 
Sc. For Ca, a 
ray transition was measured to be 1456(12) keV, while for Ca an indication for a transition was observed at 1115(34) keV. Both transitions were tentatively assigned as the 
decays. A shell-model calculation in a wide model space with a marginally modified effective nucleon-nucleon interaction depicts excellent agreement with experiment for 
level energies, two-neutron separation energies, and reaction cross sections, corroborating the formation of a new nuclear shell above the N = 34 shell. Its constituents, the 
and 
orbitals, are almost degenerate. This degeneracy precludes the possibility for a doubly magic Ca and potentially drives the dripline of Ca isotopes to 
Ca or even beyond.
-edge X-ray absorption fine structure study of 
-type 
CuO
( = Rare Earth); Toward unified understanding of electronic state of -type cuprateChen, Y.*; Asano, Shun*; Wang, T.*; Xie, P.*; Kitayama, Shinnosuke*; Ishii, Kenji*; Matsumura, Daiju; Tsuji, Takuya; Taniguchi, Takanori*; Fujita, Masaki*
JPS Conference Proceedings (Internet), 38, p.011050_1 - 011050_6, 2023/05
100 MeV/nucleonPohl, T.*; Sun, Y. L.*; Obertelli, A.*; Lee, J.*; Gmez-Ramos, M.*; Ogata, Kazuyuki*; Yoshida, Kazuki; Cai, B. S.*; Yuan, C. X.*; Brown, B. A.*; et al.
Physical Review Letters, 130(17), p.172501_1 - 172501_8, 2023/04
Times Cited Count：12 Percentile：88.25(Physics, Multidisciplinary)We report on the first proton-induced single proton- and neutron-removal reactions from the neutron deficient 
O nucleus with large Fermi-surface asymmetry at 100 MeV/nucleon. Our results provide the first quantitative contributions of multiple reaction mechanisms including the quasifree knockout, inelastic scattering, and nucleon transfer processes. It is shown that the inelastic scattering and nucleon transfer, usually neglected at such energy regime, contribute about 50% and 30% to the loosely bound proton and deeply bound neutron removal, respectively.
Akuzawa, Tadashi*; Kim, S.-Y.*; Kubota, Masahiko*; Wu, H.*; Watanabe, So; Sano, Yuichi; Takeuchi, Masayuki; Arai, Tsuyoshi*
Journal of Radioanalytical and Nuclear Chemistry, 331(12), p.5851 - 5858, 2022/12
Times Cited Count：5 Percentile：61.74(Chemistry, Analytical)
island of inversion; First study of low-lying bound excited states in 
V and 
VElekes, Z.*; Juh
sz, M. M.*; Sohler, D.*; Sieja, K.*; Yoshida, Kazuki; Ogata, Kazuyuki*; Doornenbal, P.*; Obertelli, A.*; Achouri, N. L.*; Baba, Hidetada*; et al.
Physical Review C, 106(6), p.064321_1 - 064321_10, 2022/12
Times Cited Count：3 Percentile：32.42(Physics, Nuclear)The low-lying level structure of V and V was investigated for the first time. The neutron knockout reaction and inelastic proton scattering were applied for V while the neutron knock-out reaction provided the data for V. Four and five new transitions were determined for V and V, respectively. Based on the comparison to our shell-model calculations using the Lenzi-Nowacki-Poves-Sieja (LNPS) interaction, three of the observed rays for each isotope could be placed in the level scheme and assigned to the decay of the first 11/2
and 9/2 levels. The (
,
) excitation cross sections for V were analyzed by the coupled-channels formalism assuming quadrupole plus hexadecapole deformations. Due to the role of the hexadecapole deformation, V could not be unambiguously placed on the island of inversion.
neutron orbital and the 
shell closure in 
CaEnciu, M.*; Liu, H. N.*; Obertelli, A.*; Doornenbal, P.*; Nowacki, F.*; Ogata, Kazuyuki*; Poves, A.*; Yoshida, Kazuki; Achouri, N. L.*; Baba, Hidetada*; et al.
Physical Review Letters, 129(26), p.262501_1 - 262501_7, 2022/12
Times Cited Count：18 Percentile：84.65(Physics, Multidisciplinary)The one-neutron knockout from Ca was performed at 230 MeV/nucleon combined with prompt spectroscopy. The momentum distributions corresponding to the removal of 
and 
neutrons were measured. The cross sections are consistent with a shell closure at the neutron number , found as strong as at 
and 
in Ca isotopes from the same observables. The analysis of the momentum distributions leads to a difference of the root-mean-square radii of the neutron 
and orbitals of 0.61(23) fm, in agreement with the modified-shell-model prediction of 0.7 fm suggesting that the large root-mean-square radius of the orbital in neutron-rich Ca isotopes is responsible for the unexpected linear increase of the charge radius with the neutron number.
Ca; Spectroscopy of 
K, Ca, and 
CaKoiwai, Takuma*; Wimmer, K.*; Doornenbal, P.*; Obertelli, A.*; Barbieri, C.*; Duguet, T.*; Holt, J. D.*; Miyagi, Takayuki*; Navrtil, P.*; Ogata, Kazuyuki*; et al.
Physics Letters B, 827, p.136953_1 - 136953_7, 2022/04
Times Cited Count：7 Percentile：67.20(Astronomy & Astrophysics)no abstracts in English
Wang, X.*; Tang, X.*; Zhang, P.*; Wang, Y.*; Gao, D.*; Liu, J.*; Hui, K.*; Wang, Y.*; Dong, X.*; Hattori, Takanori; et al.
Journal of Physical Chemistry Letters (Internet), 12(50), p.12055 - 12061, 2021/12
Times Cited Count：14 Percentile：71.30(Chemistry, Physical)Substituted polyacetylene is expected to improve the chemical stability, physical properties, and additional functions of the polyacetylene backbones, but its diversity is very limited. Here, by applying external pressure on solid acetylenedicarboxylic acid, we report the first crystalline poly-dicarboxylacetylene with every carbon on the trans-polyacetylene backbone bonded to a carboxyl group, which is very hard to synthesize by traditional methods. This unique structure combines the extremely high content of carbonyl groups and high conductivity of a polyacetylene backbone, which exhibits a high specific capacity and excellent cycling/rate performance as a Li-ion battery (LIB) anode. We present a completely functionalized crystalline polyacetylene and provide a high-pressure solution for the synthesis of polymeric LIB materials and other polymeric materials with a high content of active groups.
Cl isotopesLinh, B. D.*; Corsi, A.*; Gillibert, A.*; Obertelli, A.*; Doornenbal, P.*; Barbieri, C.*; Chen, S.*; Chung, L. X.*; Duguet, T.*; Gmez-Ramos, M.*; et al.
Physical Review C, 104(4), p.044331_1 - 044331_16, 2021/10
Times Cited Count：10 Percentile：72.28(Physics, Nuclear)no abstracts in English
Ca from direct reactionsBrowne, F.*; Chen, S.*; Doornenbal, P.*; Obertelli, A.*; Ogata, Kazuyuki*; Utsuno, Yutaka; Yoshida, Kazuki; Achouri, N. L.*; Baba, Hidetada*; Calvet, D.*; et al.
Physical Review Letters, 126(25), p.252501_1 - 252501_7, 2021/06
Times Cited Count：12 Percentile：67.42(Physics, Multidisciplinary)Direct proton-knockout reactions of Sc were studied at the RIKEN Radioactive Isotope Beam Factory. Populated states of Ca were investigated through -ray and invariant-mass spectroscopy. Level energies were calculated from the nuclear shell model employing a phenomenological inter-nucleon interaction. Theoretical cross sections to states were calculated from distorted-wave impulse approximation estimates multiplied by the shell model spectroscopic factors. Despite the calculations showing a significant amplitude of excited neutron configurations in the ground-state of Sc, valence proton removals populated predominantly the ground-state of Ca. This counter-intuitive result is attributed to pairing effects leading to a dominance of the ground-state spectroscopic factor. Owing to the ubiquity of the pairing interaction, this argument should be generally applicable to direct knockout reactions from odd-even to even-even nuclei.
Miao, P.*; Tan, Z.*; Lee, S. H.*; Ishikawa, Yoshihisa*; Torii, Shuki*; Yonemura, Masao*; Koda, Akihiro*; Komatsu, Kazuki*; Machida, Shinichi*; Sano, Asami; et al.
Physical Review B, 103(9), p.094302_1 - 094302_18, 2021/03
Times Cited Count：4 Percentile：24.33(Materials Science, Multidisciplinary)The layered perovskite PrBaCoO
demonstrates a strong negative thermal expansion (NTE) which holds potential for being fabricated into composites with zero thermal expansion. The NTE was found to be intimately associated with the spontaneous magnetic ordering, known as magneto-volume effect (MVE). Here we report with compelling evidences that the continuous-like MVE in PrBaCoO is intrinsically of discontinuous character, originating from an magnetoelectric transition from an antiferromagnetic insulating large-volume (AFILV) phase to a ferromagnetic less-insulating small-volume (FLISV) phase. Furthermore, the magnetoelectric effect (ME) shows high sensitivity to multiple external stimuli such as temperature, carrier doping, hydrostatic pressure, magnetic field etc. In contrast to the well-known ME such as colossal magnetoresistance and multi-ferroic effect which involve symmetry breaking of crystal structure, the ME in the cobaltite is purely isostructural. Our discovery provides a new path way to realizing the ME as well as the NTE, which may find applications in new techniques.
Ar by the (,2) reactionJuhsz, M. M.*; Elekes, Z.*; Sohler, D.*; Utsuno, Yutaka; Yoshida, Kazuki; Otsuka, Takaharu*; Ogata, Kazuyuki*; Doornenbal, P.*; Obertelli, A.*; Baba, Hidetada*; et al.
Physics Letters B, 814, p.136108_1 - 136108_8, 2021/03
Times Cited Count：7 Percentile：58.46(Astronomy & Astrophysics)The nuclear structure of Ar was studied by the (,2) reaction using -ray spectroscopy for the bound and unbound states. Comparing the results to our shell-model calculations, two bound and six unbound states were established. The low cross sections populating the two bound states of Ar could be interpreted as a clear signature for the presence of significant sub-shell closures at neutron numbers 32 and 34 in argon isotopes.
-Orbital component in the Borromean nucleus 
BYang, Z. H.*; Kubota, Yuki*; Corsi, A.*; Yoshida, Kazuki; Sun, X.-X.*; Li, J. G.*; Kimura, Masaaki*; Michel, N.*; Ogata, Kazuyuki*; Yuan, C. X.*; et al.
Physical Review Letters, 126(8), p.082501_1 - 082501_8, 2021/02
Times Cited Count：58 Percentile：95.97(Physics, Multidisciplinary)A quasifree (,
) experiment was performed to study the structure of the Borromean nucleus B, which had long been considered to have a neutron halo. By analyzing the momentum distributions and exclusive cross sections, we obtained the spectroscopic factors for 
and 
orbitals, and a surprisingly small percentage of 9(2)% was determined for . Our finding of such a small component and the halo features reported in prior experiments can be explained by the deformed relativistic Hartree-Bogoliubov theory in continuum, revealing a definite but not dominant neutron halo in B. The present work gives the smallest - or -orbital component among known nuclei exhibiting halo features and implies that the dominant occupation of or orbitals is not a prerequisite for the occurrence of a neutron halo.
= 32 shell closure below calcium; Low-lying structure of 
ArCorts, M. L.*; Rodriguez, W.*; Doornenbal, P.*; Obertelli, A.*; Holt, J. D.*; Menndez, J.*; Ogata, Kazuyuki*; Schwenk, A.*; Shimizu, Noritaka*; Simonis, J.*; et al.
Physical Review C, 102(6), p.064320_1 - 064320_9, 2020/12
Times Cited Count：13 Percentile：74.01(Physics, Nuclear)Low-lying excited states in the = 32 isotope Ar were investigated by in-beam -ray spectroscopy following proton- and neutron-knockout, multinucleon removal, and proton inelastic scattering at the RIKEN Radioactive Isotope Beam Factory. The energies of the two previously reported transitions have been confirmed, and five additional states are presented for the first time, including a candidate for a 3 state. The level scheme built using coincidences was compared to shell-model calculations in the 
model space and to 
predictions based on chiral two- and three-nucleon interactions. Theoretical proton- and neutron-knockout cross sections suggest that two of the new transitions correspond to 2
states, while the previously proposed 4
state could also correspond to a 2 state.
Zhang, P.*; Tang, X.*; Wang, Y.*; Wang, X.*; Gao, D.*; Li, Y.*; Zheng, H.*; Wang, Y.*; Wang, X.*; Fu, R.*; et al.
Journal of the American Chemical Society, 142(41), p.17662 - 17669, 2020/10
Times Cited Count：34 Percentile：79.04(Chemistry, Multidisciplinary)Solid-state topochemical polymerization (SSTP) is a promising method to construct functional crystalline polymeric materials, but in contrast to various reactions that happen in solution, only very limited types of SSTP reactions are reported. Diels-Alder (DA) and dehydro-DA (DDA) reactions are textbook reactions for preparing six-membered rings in solution but are scarcely seen in solid-state synthesis. Here, using multiple cutting-edge techniques, we demonstrate that the solid 1,4-diphenylbutadiyne (DPB) undergoes a DDA reaction under 10-20 GPa with the phenyl as the dienophile. The crystal structure at the critical pressure shows that this reaction is "distance-selected". The distance of 3.2
between the phenyl and the phenylethynyl facilitates the DDA reaction, while the distances for other DDA and 1,4-addition reactions are too large to allow the bonding. The obtained products are crystalline armchair graphitic nanoribbons, and hence our studies open a new route to construct the crystalline carbon materials with atomic-scale control.
