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JAEA Reports

Structural investigation of borosilicate glasses by using XAFS measurement in soft X-ray region, 4 (Joint research)

Nagai, Takayuki; Okamoto, Yoshihiro; Shibata, Daisuke*; Kojima, Kazuo*; Hasegawa, Takehiko*; Sato, Seiichi*; Fukaya, Akane*; Hatakeyama, Kiyoshi*

JAEA-Research 2024-014, 54 Pages, 2025/02

JAEA-Research-2024-014.pdf:7.02MB

XAFS measurements in the soft X-ray region are suitable for evaluating the chemical state of the surface layer of a measurement sample because the X-ray transmittance is low. In this study, the purpose of the study was to confirm the difference between the coagulated surface layer and the inside of the simulated waste glasses by measuring the K-edge of the glass constituent elements boron, oxygen, sodium, and silicon, and the L$$_{3}$$ edge of the waste component cerium. As a result, the B K-edge XANES spectra showed that the proportion of B-O tetracoordinate sp$$^{3}$$ structures (BO$$_{4}$$) on the surface layer of the coagulated glass samples was higher than that on the cut surface inside the glass samples, which is expected to improve the water resistance of the coagulated surface. On the other hand, the O K-edge XANES spectra suggested that the O abundance in the coagulated surface layer was lower than that in the cut surface inside the glass samples, and that alkali metal elements may be concentrated in the coagulated surface layer. However, no difference was observed in the Na K-edge XANES spectra between the coagulated surface layer and the cut surface, and no difference was observed in the Si K-edge XANES spectra between the solidified surface and the inside of glass samples. In addition, the Ce L$$_{3}$$-edge XANES spectra confirmed that the Ce valence in the surface layer of coagulated glass samples were oxidized compared to the inside of glass samples.

Journal Articles

Complete genome sequence of ${it Thiomicrospira}$ sp. strain V2501 isolated from 250 m below the ground level in Horonobe, Hokkaido, Japan

Ueno, Akio*; Sato, Kiyoshi*; Tamamura, Shuji*; Murakami, Takuma*; Inomata, Hidenori*; Tamazawa, Satoshi*; Amano, Yuki; Miyakawa, Kazuya; Naganuma, Takeshi*; Igarashi, Toshifumi*

Microbiology Resource Announcements (Internet), 13(11), p.e00108-24_1 - e00108-24_4, 2024/11

Journal Articles

Missing-mass measurement of the $$^{12}$$C$$(K^-,K^+)$$ reaction at 1.8 GeV/$$c$$ with the Superconducting Kaon spectrometer

Ichikawa, Yudai; Fujita, Manami; Hasegawa, Shoichi; Imai, Kenichi*; Nanamura, Takuya; Naruki, Megumi; Sato, Susumu; Sako, Hiroyuki; Tamura, Hirokazu; Tanida, Kiyoshi; et al.

Progress of Theoretical and Experimental Physics (Internet), 2024(9), p.091D01_1 - 091D01_13, 2024/09

 Times Cited Count:0 Percentile:0.00(Physics, Multidisciplinary)

Journal Articles

Characteristics of smartphone-wirelessly-connected personal dosemeters

Mikami, Satoshi; Tokiyoshi, Masanori*; Sato, Rina*; Tanaka, Daisuke*; Yoshimura, Kazuya

Nihon Hoshasen Anzen Kanri Gakkai-Shi, 23(1), p.10 - 17, 2024/06

Taisei Corporation and Infocube LAFLA Co., Ltd. have developed the smartphone-wirelessly-connected dosemeters, aiming to apply it to real-time exposure management of multiple decontamination workers. In order to grasp the basic characteristics of the developed dosemeters, they were calibrated and tested their characteristics such as energy dependency, angle of incidence dependency, etc. at photon calibration fields in Japan Atomic Energy Agency. The results showed generally good characteristics in each test. We evaluated that the dosemeters can be effectively used for decontamination work.

JAEA Reports

Structural investigation of borosilicate glasses by using XAFS measurement in soft X-ray region, 3 (Joint research)

Nagai, Takayuki; Okamoto, Yoshihiro; Yamagishi, Hirona*; Shibata, Daisuke*; Kojima, Kazuo*; Hasegawa, Takehiko*; Sato, Seiichi*; Fukaya, Akane*; Hatakeyama, Kiyoshi*

JAEA-Research 2023-004, 45 Pages, 2023/09

JAEA-Research-2023-004.pdf:6.07MB

The local structure of glass-forming elements and waste elements in borosilicate glasses varies with its chemical composition. In this study, simulated waste glass samples were prepared and the chemical state regarding boron (B), silicon (Si) and waste elements of iron (Fe), cesium (Cs) were estimated by using XAFS measurement in soft X-ray region. To understand the chemical stability of simulated waste glasses, XANES spectra of B K-edge, Fe L$$_{3}$$, L$$_{2}$$-edge, and Cs M$$_{5}$$, M$$_{4}$$-edge were measured on the glass surface exposed to the leachate. As a result, it was found that the glass surface exposed to the leachate was changed and it was difficult to obtain a clear XANES spectrum. From the B K-edge XANES spectra on glass surfaces exposed to the leachate, an increase in three-coordination of B-O (BO$$_{3}$$) and a decrease in four-coordination of B-O (BO$$_{4}$$) were observed compared to the glass surfaces before immersion. The XANES spectra of Fe L$$_{3}$$, L$$_{2}$$-edge, and Cs M$$_{5}$$, M$$_{4}$$-edge show that as the exposure time in the leachate increases, the Cs present on the glass surface dissolves into the leachate. The XANES spectra of Si K-edge were measured on simulated waste glass surfaces before immersion, and it was confirmed that the change in XANES spectra given by Na$$_{2}$$O concentration had a larger effect than the waste component concentration.

Journal Articles

Evaluation of external dose exposure of workers during house demolition and dose reduction work in a difficult-to-return zone

Sanada, Yukihisa; Tokiyoshi, Masanori*; Nishiyama, Kyohei*; Sato, Rina; Yoshimura, Kazuya; Funaki, Hironori; Abe, Tomohisa; Ishida, Mutsushi*; Nagamine, Haruo*; Fujisaka, Motoyuki*

Nihon Genshiryoku Gakkai Wabun Rombunshi (Internet), 22(2), p.87 - 96, 2023/04

Since the accident at the Fukushima Daiichi Nuclear Power Plant, many decontamination works have been carried out, but it is difficult to say that much data on workers' exposure has necessarily been analyzed in detail. In this paper, based on the GPS location information carried by the workers together with their personal dosimeters, the air dose rate in the work area and the characteristics of each type of work were analyzed. The results showed that more than 50% of the measured actual doses were more than twice the median planned dose calculated from the air dose rate and actual working hours. Furthermore, as a result of the analysis by work type, it was found that the exposure doses of demolition workers tended to be high, and that this was due to the fact that most of the work was carried out before the work was carried out to reduce the dose at the work site. In addition, when the conversion from air dose to effective dose was taken into account, there were many cases of underestimation where the planned values were lower than the measured values, and it is considered important for management to set appropriate working factor.

Journal Articles

Superconducting dipole magnet for Hyperon spectrometer

Ahn, J. K.*; Hasegawa, Shoichi; Imai, Kenichi*; Sako, Hiroyuki; Sato, Susumu; Tanida, Kiyoshi; 10 of others*

Nuclear Instruments and Methods in Physics Research A, 1047, p.167775_1 - 167775_13, 2023/02

 Times Cited Count:1 Percentile:0.00(Instruments & Instrumentation)

Journal Articles

Strangeness physics programs by S-2S at J-PARC

Gogami, Toshiyuki*; Ebata, Kengo; Fujita, Manami; Harada, Takeshi; Hasegawa, Shoichi; Hosomi, Kenji; Ichikawa, Yudai; Imai, Kenichi*; Kim, S.; Nanamura, Takuya; et al.

EPJ Web of Conferences, 271, p.11002_1 - 11002_7, 2022/11

Journal Articles

Recent progress and future prospects of hyperon nucleon scattering experiment

Miwa, Koji*; Fujita, Manami; Harada, Takeshi; Hasegawa, Shoichi; Hosomi, Kenji; Ichikawa, Masaya; Imai, Kenichi*; Sako, Hiroyuki; Sato, Susumu; Tamura, Hirokazu; et al.

EPJ Web of Conferences, 271, p.04001_1 - 04001_7, 2022/11

Journal Articles

Structural change by phosphorus addition to borosilicate glass containing simulated waste components

Okamoto, Yoshihiro; Shiwaku, Hideaki; Shimamura, Keisuke*; Kobayashi, Hidekazu; Nagai, Takayuki; Inose, Takehiko*; Sato, Seiichi*; Hatakeyama, Kiyoshi*

Journal of Nuclear Materials, 570, p.153962_1 - 153962_13, 2022/11

Simulated nuclear waste glass samples containing phosphorus, which increase the solubility of molybdenum, were prepared and analyzed using synchrotron X-ray Absorption Fine Structure (XAFS) analysis for some constituent elements and Raman spectroscopic analysis of their complex structure. Changes in local structure and chemical state due to different phosphorus additions and waste loading rates were systematically studied. Consequently, no crystalline phase due to the molybdate compound was observed even at a maximum waste content of 30 wt% (corresponding to 1.87 mol% MoO$$_3$$). Oxidation proceeded when the waste-loading rate was increased, whereas the reduction proceeded when phosphorus was added. In some cases, the effects of oxidation and reduction were offset. The local structure around specific elements can be classified as follows; Zn that is affected mainly by the waste-loading rate, Ce that is affected by both the waste-loading rate and phosphorus addition, and Zr element that is not affected by either of them. From the comparison between the analytical results of Mo and other elements, it was considered that the added phosphorus exists as a free PO$$_4$$ structural unit and may deprive the alkali metal coordinated to the molybdate ion.

JAEA Reports

Structural investigation of borosilicate glasses by using XAFS measurement in soft X-ray region, 2 (Joint research)

Nagai, Takayuki; Okamoto, Yoshihiro; Yamagishi, Hirona*; Kojima, Kazuo*; Inose, Takehiko*; Sato, Seiichi*; Hatakeyama, Kiyoshi*

JAEA-Research 2022-008, 37 Pages, 2022/10

JAEA-Research-2022-008.pdf:5.27MB

The local structure of glass-forming elements and waste elements in borosilicate glasses varies with its chemical composition. In this study, borosilicate glass frit and simulated waste glass samples were prepared and the chemical state regarding boron (B), silicon (Si) and waste elements of iron (Fe), cesium (Cs) were estimated by using XAFS measurement in soft X-ray region. Following results were obtained by XAFS measurements of simulated waste glass surfaces after immersion test to investigate the long chemical stability. (1) As the leaching time of glass samples in immersion test passed, the Cs M$$_{5}$$, M$$_{4}$$-edge XANES spectra disappeared and the Fe L$$_{3}$$, L$$_{2}$$-edge spectra changed. (2) A new compound was formed on the sample surface after the immersion test, and these changes in the surface state were confirmed by Raman spectroscopy. However, it became difficult to obtain a clear B K-edge XANES spectrum by forming a compound on glass surfaces. The Si K-edge XANES spectra of borosilicate glass frits with different Na$$_{2}$$O content were measured, and following was confirmed. (1) As the Na$$_{2}$$O concentration increases in borosilicate glass frit, the K-edge peak of Si shifts to the low energy side. (2) The intensity of the Si K-edge peak is maximum when the Na$$_{2}$$O content in glass frits was about 7wt%.

Journal Articles

Measurement of differential cross sections for $$Sigma^+ p$$ elastic scattering in the momentum range 0.44-0.80 GeV/c

Nanamura, Takuya; Fujita, Manami; Hasegawa, Shoichi; Ichikawa, Masaya; Ichikawa, Yudai; Imai, Kenichi*; Naruki, Megumi; Sato, Susumu; Sako, Hiroyuki; Tamura, Hirokazu; et al.

Progress of Theoretical and Experimental Physics (Internet), 2022(9), p.093D01_1 - 093D01_35, 2022/09

 Times Cited Count:17 Percentile:86.03(Physics, Multidisciplinary)

Journal Articles

$$phi$$ meson production in $$p$$$$+$$Al, $$p$$$$+$$Au, $$d$$$$+$$Au, and $$^3$$He$$+$$Au collisions at $$sqrt{s_{_{NN}}}=200$$ GeV

Acharya, U. A.*; Hasegawa, Shoichi; Imai, Kenichi*; Sako, Hiroyuki; Sato, Susumu; Tanida, Kiyoshi; PHENIX Collaboration*; 365 of others*

Physical Review C, 106(1), p.014908_1 - 014908_13, 2022/07

 Times Cited Count:6 Percentile:69.74(Physics, Nuclear)

Journal Articles

Measurement of $$psi(2S)$$ nuclear modification at backward and forward rapidity in $$p$$$$+$$$$p$$, $$p$$$$+$$Al, and $$p$$$$+$$Au collisions at $$sqrt{s_{_{NN}}}=200$$ GeV

Acharya, U. A.*; Hasegawa, Shoichi; Imai, Kenichi*; Sako, Hiroyuki; Sato, Susumu; Tanida, Kiyoshi; PHENIX Collaboration*; 310 of others*

Physical Review C, 105(6), p.064912_1 - 064912_15, 2022/06

 Times Cited Count:14 Percentile:88.43(Physics, Nuclear)

Journal Articles

Systematic study of nuclear effects in $$p$$$$+$$Al, $$p$$$$+$$Au, $$d$$$$+$$Au, and $$^{3}$$He$$+$$Au collisions at $$sqrt{s_{_{NN}}}=200$$ GeV using $$pi^0$$ production

Acharya, U. A.*; Hasegawa, Shoichi; Imai, Kenichi*; Sako, Hiroyuki; Sato, Susumu; Tanida, Kiyoshi; PHENIX Collaboration*; 547 of others*

Physical Review C, 105(6), p.064902_1 - 064902_19, 2022/06

 Times Cited Count:17 Percentile:92.17(Physics, Nuclear)

Journal Articles

Kinematic dependence of azimuthal anisotropies in $$p$$$$+$$Au, $$d$$$$+$$Au, and $$^3$$He+Au at $$sqrt{s_{_{NN}}}$$ = 200 GeV

Acharya, U. A.*; Hasegawa, Shoichi; Imai, Kenichi*; Sako, Hiroyuki; Sato, Susumu; Tanida, Kiyoshi; PHENIX Collaboration*; 378 of others*

Physical Review C, 105(2), p.024901_1 - 024901_13, 2022/02

 Times Cited Count:12 Percentile:88.43(Physics, Nuclear)

Journal Articles

Transverse-single-spin asymmetries of charged pions at midrapidity in transversely polarized $$p{+}p$$ collisions at $$sqrt{s}=200$$ GeV

Acharya, U. A.*; Hasegawa, Shoichi; Imai, Kenichi*; Sako, Hiroyuki; Sato, Susumu; Tanida, Kiyoshi; PHENIX Collaboration*; 306 of others*

Physical Review D, 105(3), p.032003_1 - 032003_8, 2022/02

 Times Cited Count:2 Percentile:21.84(Astronomy & Astrophysics)

Journal Articles

Transverse single spin asymmetries of forward neutrons in $$p$$$$+$$$$p$$, $$p$$$$+$$Al, and $$p$$$$+$$Au collisions at $$sqrt{s_{_{NN}}}$$ = 200 GeV as a function of transverse and longitudinal momenta

Acharya, U. A.*; Hasegawa, Shoichi; Imai, Kenichi*; Sako, Hiroyuki; Sato, Susumu; Tanida, Kiyoshi; PHENIX Collaboration*; 305 of others*

Physical Review D, 105(3), p.032004_1 - 032004_13, 2022/02

 Times Cited Count:4 Percentile:31.14(Astronomy & Astrophysics)

Journal Articles

Precise measurement of differential cross sections of the $${Sigma}^- p to {Lambda} n$$ reaction in momentum range 470-650 MeV/$$c$$

Miwa, Koji*; Fujita, Manami; Hasegawa, Shoichi; Hosomi, Kenji; Ichikawa, Yudai*; Imai, Kenichi*; Nanamura, Takuya; Sako, Hiroyuki; Sato, Susumu; Tamura, Hirokazu; et al.

Physical Review Letters, 128(7), p.072501_1 - 072501_6, 2022/02

 Times Cited Count:18 Percentile:88.17(Physics, Multidisciplinary)

JAEA Reports

Structural investigation of borosilicate glasses by using XAFS measurement in Soft X-ray region (Joint research)

Nagai, Takayuki; Okamoto, Yoshihiro; Yamagishi, Hirona*; Ota, Toshiaki*; Kojima, Kazuo*; Inose, Takehiko*; Sato, Seiichi*; Hatakeyama, Kiyoshi*

JAEA-Research 2021-010, 62 Pages, 2022/01

JAEA-Research-2021-010.pdf:6.05MB

The local structure of glass-forming elements and waste elements in borosilicate glasses varies with its chemical composition. In this study, borosilicate glass frit and simulated waste glass samples were prepared and the local structure and chemical state regarding boron(B), oxygen(O), silicon(Si) and waste elements of iron(Fe), cesium(Cs) were estimated by using XAFS measurement in soft X-ray region. Following results were obtained by XAFS measurements of prepared glass frit and simulated waste glass samples: (1) The effect of Na$$_{2}$$O concentration on B-O coordination structure is greater than that of the waste elements concentration. (2) The height of pre-edge by O K-edge spectrum depends on the concentration of first transition elements such as Fe in glass samples. Following results were obtained by XAFS measurements of simulated waste glass samples after immersion test to investigate the long chemical stability. (1) A new compound was formed on the sample surface after the immersion test, and changes in the surface state were confirmed by Raman spectroscopy. (2) Cs on the sample surface after immersion test dissolves into the leaching solution. The Si K-edge XANES spectra of borosilicate glass frits and simulated waste glass samples included lanthanides oxide were measured, and following was confirmed. (1) As the Na$$_{2}$$O concentration increases in borosilicate glass frit, the K-edge peak of Si shifts to the low energy side. (2) The peak height of the K-edge of Si differs depending on the kind of lanthanide.

306 (Records 1-20 displayed on this page)