Structural investigation of borosilicate glasses by using XAFS measurement in soft X-ray region, 3 (Joint research)

Nagai, Takayuki; Okamoto, Yoshihiro; Yamagishi, Hirona*; Shibata, Daisuke*; Kojima, Kazuo*; Hasegawa, Takehiko*; Sato, Seiichi*; Fukaya, Akane*; Hatakeyama, Kiyoshi*

JAEA-Research 2023-004, 45 Pages, 2023/09

JAEA-Research-2023-004.pdf:6.07MB

The local structure of glass-forming elements and waste elements in borosilicate glasses varies with its chemical composition. In this study, simulated waste glass samples were prepared and the chemical state regarding boron (B), silicon (Si) and waste elements of iron (Fe), cesium (Cs) were estimated by using XAFS measurement in soft X-ray region. To understand the chemical stability of simulated waste glasses, XANES spectra of B K-edge, Fe L, L-edge, and Cs M, M-edge were measured on the glass surface exposed to the leachate. As a result, it was found that the glass surface exposed to the leachate was changed and it was difficult to obtain a clear XANES spectrum. From the B K-edge XANES spectra on glass surfaces exposed to the leachate, an increase in three-coordination of B-O (BO) and a decrease in four-coordination of B-O (BO) were observed compared to the glass surfaces before immersion. The XANES spectra of Fe L, L-edge, and Cs M, M-edge show that as the exposure time in the leachate increases, the Cs present on the glass surface dissolves into the leachate. The XANES spectra of Si K-edge were measured on simulated waste glass surfaces before immersion, and it was confirmed that the change in XANES spectra given by NaO concentration had a larger effect than the waste component concentration.

Inverse estimation scheme of radioactive source distributions inside building rooms based on monitoring air dose rates using LASSO; Theory and demonstration

Shi, W.*; Machida, Masahiko; Yamada, Susumu; Yoshida, Toru*; Hasegawa, Yukihiro*; Okamoto, Koji*

Progress in Nuclear Energy, 162, p.104792_1 - 104792_19, 2023/08

https://doi.org/10.1016/j.pnucene.2023.104792

Predicting radioactive source distributions inside reactor building rooms based on monitoring air dose rates is one of the most essential steps towards decommissioning of nuclear power plants. However, the attempt is rather a difficult task, because it can be generally mapped onto mathematically ill-posed problem. Then, in order to successfully perform the inverse estimations on radioactive source distributions even in such ill-posed conditions, we suggest that a machine learning method, least absolute shrinkage and selection operator (LASSO) minimizing the loss function, is a promising scheme. For the purpose of its feasibility demonstrations in real building rooms, we employ PHITS code to make LASSO input as the above matrix C connecting the radioactive source vector P defined on surface meshes of structural materials with the air dose rate vector Q measured at internal positions inside the rooms. We develop a mathematical criterion on the number of monitoring points to correctly predict source distributions based on the theory of Candes and Tao. Then, we confirm that LASSO actually shows extremely high possibility for source distribution reconstructions as far as the number of detection points satisfies our criterion. Moreover, we verify that radioactive hot spots can be truly reconstructed in an experiment setup. At last, we examine an influence factor like detector-source distance to enhance the predicting possibility in the inverse estimation. From the above demonstrations, we propose that LASSO scheme is a quite useful way to explore hot spots as seen in damaged nuclear power plants like Fukushima Daiichi nuclear power plants.

LASSO reconstruction scheme to predict radioactive source distributions inside reactor building rooms; Theory & demonstration

Shi, W.*; Machida, Masahiko; Yamada, Susumu; Yoshida, Toru*; Hasegawa, Yukihiro*; Okamoto, Koji*

Proceedings of Waste Management Symposia 2023 (WM2023) (Internet), 8 Pages, 2023/02

Measurement of the differential cross sections of the elastic scattering in momentum range 470 to 850 MeV/

Miwa, Koji*; Fujita, Manami; Hasegawa, Shoichi; Hosomi, Kenji; Ichikawa, Yudai; Imai, Kenichi*; Nanamura, Takuya; Naruki, Megumi; Sako, Hiroyuki; Sato, Susumu; et al.

Physical Review C, 104(4), p.045204_1 - 045204_20, 2021/10

https://doi.org/10.1103/PhysRevC.104.045204

Retreat from stress; Rattling in a planar coordination

Suekuni, Koichiro*; Lee, C. H.*; Tanaka, Hiromi*; Nishibori, Eiji*; Nakamura, Atsushi*; Kasai, Hidetaka*; Mori, Hitoshi*; Usui, Hidetomo*; Ochi, Masayuki*; Hasegawa, Takumi*; et al.

Advanced Materials, 30(13), p.1706230_1 - 1706230_6, 2018/03

https://doi.org/10.1002/adma.201706230

Thermoelectric materials for highly efficient devices must satisfy conflicting requirements of high electrical conductivity and low thermal conductivity. In this paper, we studied the crystal structure and phonon dynamics of tetrahedrites (Cu,Zn)(Sb,As)S. The results revealed that the Cu atoms in a planar coordination are rattling, which effectively scatter phonons. These findings provide a new strategy for the development of highly efficient thermoelectric materials with planar coordination.

Thermodynamic evidence for nematic superconductivity in CuBiSe

Yonezawa, Shingo*; Tajiri, Kengo*; Nakata, Suguru*; Nagai, Yuki; Wang, Z.*; Segawa, Koji*; Ando, Yoichi*; Maeno, Yoshiteru*

Nature Physics, 13(2), p.123 - 126, 2017/02

https://doi.org/10.1038/nphys3907

no abstracts in English

Simulation of phase modulation for longitudinal emittance blow-up in J-PARC MR

Yamamoto, Masanobu; Ezura, Eiji*; Hara, Keigo*; Hasegawa, Katsushi*; Nomura, Masahiro; Omori, Chihiro*; Schnase, A.*; Shimada, Taihei; Takagi, Akira*; Takata, Koji*; et al.

JPS Conference Proceedings (Internet), 8, p.012015_1 - 012015_6, 2015/09

https://doi.org/10.7566/JPSCP.8.012015

The J-PARC MR provides a coasting proton beam for nuclear physics experiments by slow extraction. The longitudinal emittance should be enlarged until the MR flat top to mitigate the microwave instability. We have investigated a Phase Modulation (PM) method by using a High Frequency Cavity (HFC) to increase the emittance. We have performed extensive simulation studies to find the appropriate parameters of the PM through the particle tracking simulation. We found that the effective HFC frequency has linear dependence with the PM frequency, where the emittance is smoothly enlarged. Furthermore, we found that the required HFC voltage is inverse proportional to the square root of the duration time of the PM. These PM properties will be used for the design of the HFC. We describe the particle tracking simulation results of controlled emittance blow-up by the PM.

Experiments of coolant accumulation in SG U tube and analytical model development

Yamaji, Tatsuya*; Koizumi, Yasuo; Yamazaki, Kohei*; Otake, Hiroyasu*; Hasegawa, Koji*; Onuki, Akira*; Kanamori, Daisuke*

Konsoryu Shimpojiumu 2015 Koen Rombunshu (USB Flash Drive), 2 Pages, 2015/08

Experiments of condensing counter-current two-phase flow in a vertical pipe were performed. This study was intended to examine water accumulation in the up-flow side of steam generator U-tubes of a PWR during the reflux cooling stage of a small break LOCA. It has been apprehended that the water accumulation may result in temporary core liquid level depression. The inner diameter and the length of a test flow channel used in the experiments were 18 mm and 4 m, respectively. The experiments were performed by using steam and water at 0.1 MPa. Two kinds of experiments were conducted; visualization experiments by using a transparent test section and quantitative water accumulation evaluation experiments by using a brass test section. Even if water on the inner surface of the test pipe could not flow downward at the lower portion of the test pipe, a part of water became to flow downward at the upper portion of the test pipe since steam velocity decreased because of condensation. Thus, two-phase mixture level was formed in the upper portion of the test pipe, which resulted in the water accumulation in the pipe. The model to predict the water accumulation was proposed. It predicted the water accumulation reasonably well.

A Beam position fiber counter with scintillation fibers and multi-pixel photon counter for high intensity beam operation

Honda, Ryotaro*; Miwa, Koji*; Matsumoto, Yuki*; Chiga, Nobuyuki*; Hasegawa, Shoichi; Imai, Kenichi

Nuclear Instruments and Methods in Physics Research A, 787, p.157 - 160, 2015/07

https://doi.org/10.1016/j.nima.2014.11.084

A beam position fiber counter consisting of the scintillation fiber and a multi-pixel photon counter was developed in order to handle a 10 MHz secondary pion beam in the J-PARC E40 experiment. This counter was installed at the entrance of the beam line spectrometer at the K1.8 experimental area in J-PARC and used for the momentum reconstruction. In order to suppress the accidental background and reconstruct the beam momentum, a good timing resolution better than 0.8 ns and a good position resolution better than 200 m were simultaneously required for the counter. These requirements were well achieved by reading the 320 fibers with a diameter of 1 mm, which were arranged in a staggered position, with MPPC fiber by fiber. The signal induced from each MPPC was handled with an Extended Analogue SiPM Integrated ReadOut Chip (EASIROC) developed by Omega/IN2P3 in France. In addition, the timing of the discriminated signals from EASIROC was measured by a FPGA-based multi-hit TDC implemented into Spartan-6. Finally, we obtained the timing resolution of 0.68 ns and the position resolution of 190 m under the 9 MHz beam condition using a pion beam.

Mizunami Underground Research Laboratory Project, Annual report for fiscal year 2013

Hama, Katsuhiro; Mikake, Shinichiro; Nishio, Kazuhisa; Kawamoto, Koji; Yamada, Nobuto; Ishibashi, Masayuki; Murakami, Hiroaki; Matsuoka, Toshiyuki; Sasao, Eiji; Sanada, Hiroyuki; et al.

JAEA-Review 2014-038, 137 Pages, 2014/12

JAEA-Review-2014-038.pdf:162.61MB

Japan Atomic Energy Agency (JAEA) at Tono Geoscience Center (TGC) is pursuing a geoscientific research and development project namely the Mizunami Underground Research Laboratory (MIU) Project in crystalline rock environment in order to construct scientific and technological basis for geological disposal of High-level Radioactive Waste (HLW). The MIU Project has three overlapping phases: Surface-based Investigation phase (Phase I), Construction phase (Phase II), and Operation phase (Phase III). The MIU Project has been ongoing the Phase II and the Phase III in fiscal year 2013. This report presents the results of the investigations, construction and collaboration studies in fiscal year 2013, as a part of the Phase II and Phase III based on the MIU Master Plan updated in 2010.