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Journal Articles

STRAD project for systematic treatments of radioactive liquid wastes generated in nuclear facilities

Watanabe, So; Ogi, Hiromichi*; Arai, Yoichi; Aihara, Haruka; Takahatake, Yoko; Shibata, Atsuhiro; Nomura, Kazunori; Kamiya, Yuichi*; Asanuma, Noriko*; Matsuura, Haruaki*; et al.

Progress in Nuclear Energy, 117, p.103090_1 - 103090_8, 2019/11

Journal Articles

Development of a water purifier for radioactive cesium removal from contaminated natural water by radiation-induced graft polymerization

Seko, Noriaki*; Hoshina, Hiroyuki*; Kasai, Noboru*; Shibata, Takuya; Saiki, Seiichi*; Ueki, Yuji*

Radiation Physics and Chemistry, 143, p.33 - 37, 2018/02

 Times Cited Count:1 Percentile:38.14(Chemistry, Physical)

Journal Articles

Evaluation of a cesium adsorbent grafted with ammonium 12-molybdophosphate

Shibata, Takuya; Seko, Noriaki; Amada, Haruyo; Kasai, Noboru; Saiki, Seiichi; Hoshina, Hiroyuki; Ueki, Yuji

Radiation Physics and Chemistry, 119, p.247 - 252, 2016/02

 Times Cited Count:5 Percentile:23.48(Chemistry, Physical)

Journal Articles

Development of fibrous grafted adsorbents by radiation grafting technique

Seko, Noriaki

Denki Hyoron, 100(12), p.47 - 51, 2015/12

no abstracts in English

Journal Articles

Development of grafted adsorbents for Cs removal from natural water source

Seko, Noriaki; Shibata, Takuya; Kasai, Noboru; Ueki, Yuji; Saiki, Seiichi; Hoshina, Hiroyuki

Hoshasen To Sangyo, (138), p.9 - 12, 2015/06

no abstracts in English

Journal Articles

Evaluation of antibacterial effect by using a fibrous grafted material loaded Ag ligand

Shibata, Takuya; Seko, Noriaki; Kasai, Noboru; Hoshina, Hiroyuki; Ueki, Yuji

International Journal of Organic Chemistry, 5(2), p.100 - 107, 2015/06

Journal Articles

Development of an adsorbent for Cs removal synthesized by radiation-induced graft polymerization

Shibata, Takuya; Seko, Noriaki; Amada, Haruyo; Kasai, Noboru; Saiki, Seiichi; Hoshina, Hiroyuki; Ueki, Yuji

Nippon Ion Kokan Gakkai-Shi, 26(1), p.9 - 14, 2015/01

Journal Articles

The Volume reduction method of radioactively-contaminated plant waste through extraction and removal of radioactive cesium

Saiki, Seiichi; Shibata, Takuya; Hoshina, Hiroyuki; Ueki, Yuji; Kasai, Noboru; Seko, Noriaki

Nippon Ion Kokan Gakkai-Shi, 25(4), p.170 - 175, 2014/11

Journal Articles

Evaluation of the scandium affinity under the iron coexistence using radiation grafted adsorbents

Hayashi, Natsuki*; Hoshina, Hiroyuki; Amada, Haruyo; Yamanobe, Takeshi*; Seko, Noriaki

Nippon Ion Kokan Gakkai-Shi, 25(4), p.105 - 108, 2014/11

Journal Articles

Recovery of scandium from hot spring water with graft adsorbent containing phosphoric groups

Hoshina, Hiroyuki; Kasai, Noboru; Amada, Haruyo; Takahashi, Makikatsu*; Tanaka, Kazuya*; Seko, Noriaki

Nippon Ion Kokan Gakkai-Shi, 25(4), p.248 - 251, 2014/11

Journal Articles

A New eco-friendly synthesis method for arsenic adsorbent

Amada, Haruyo; Takahashi, Makikatsu*; Hoshina, Hiroyuki; Seko, Noriaki

Nippon Ion Kokan Gakkai-Shi, 25(4), p.109 - 113, 2014/11

Journal Articles

Adsorption properties of styrenesulfonate-grafted fibrous metal adsorbent

Ueki, Yuji; Saiki, Seiichi; Seko, Noriaki

Nippon Ion Kokan Gakkai-Shi, 25(4), p.99 - 104, 2014/11

Journal Articles

Synthesis of highly-selective fibrous adsorbent by introducing 2-ethylhexyl hydrogen-2-ethylhexylphosphonate for scandium adsorption

Hoshina, Hiroyuki; Ueki, Yuji; Saiki, Seiichi; Seko, Noriaki

International Journal of Organic Chemistry, 4(3), p.195 - 200, 2014/09

Journal Articles

Optimization of grafted fibrous polymer as a solid basic catalyst for biodiesel fuel production

Ueki, Yuji; Saiki, Seiichi; Shibata, Takuya; Hoshina, Hiroyuki; Kasai, Noboru; Seko, Noriaki

International Journal of Organic Chemistry, 4(2), p.91 - 105, 2014/06

Grafted fibrous polymer with quaternary amine groups could function as a highly-efficient catalyst for biodiesel fuel (BDF) production. In this study, the optimization of grafted fibrous polymer (catalyst) and transesterification conditions for the effective BDF production was attempted through a batch-wise transesterification of triglyceride (TG) with ethanol (EtOH) in the presence of a cosolvent. Trimethylamine was the optimal quaternary amine group for the grafted fibrous catalyst. The optimal degree of grafting of the grafted fibrous catalyst was 170%. The optimal transesterification conditions were as follows: The molar quantity of quaternary amine groups, transesterification temperature, molar ratio of TG and EtOH, and primary alkyl alcohol were 0.8 mmol, 80$$^{circ}$$C, 1:200, and 1-pentanol, respectively. The grafted fibrous catalyst could be applied to BDF production using natural oils. Furthermore, the grafted fibrous catalyst could be used repeatedly after regeneration involving three sequential processes, i.e., organic acid, alkali, and alcohol treatments, without any significant loss of catalytic activity.

Journal Articles

Effect of initial radical concentration on radiation-induced graft polymerization on polyethylene nonwoven fabric

Saiki, Seiichi; Okaya, Keiko*; Seko, Noriaki

JAEA-Review 2013-059, JAEA Takasaki Annual Report 2012, P. 54, 2014/03

no abstracts in English

Journal Articles

Homogeneous transesterification kinetics of triglyceride to biodiesel using grafted fibrous catalyst

Ueki, Yuji; Seko, Noriaki

JAEA-Review 2013-059, JAEA Takasaki Annual Report 2012, P. 53, 2014/03

no abstracts in English

Journal Articles

The Influence on the vulcanized rubber physical properties by radiation grafting

Saito, Hiroaki*; Mizote, Norihito*; Ueki, Yuji; Seko, Noriaki

JAEA-Review 2013-059, JAEA Takasaki Annual Report 2012, P. 57, 2014/03

no abstracts in English

JAEA Reports

Pilot-scale synthesis for radioactive cesium adsorbents by radiation graft polymerization and their field tests

Kasai, Noboru; Iwanade, Akio; Ueki, Yuji; Saiki, Seiichi; Hoshina, Hiroyuki; Seko, Noriaki

JAEA-Technology 2013-046, 25 Pages, 2014/02

JAEA-Technology-2013-046.pdf:9.63MB

To remove their radioactive species which have long radioactive half-life from the circumstances as rapidly as possible, we developed novel radioactive cesium adsorbents containing ammonium 12-molybdophosphate, which had adsorption selectivity for cesium ion, by radiation grafting method. The bench-scale equipment 150 times as large volume as laboratory scale was established for graft polymerization. The radioactive cesium adsorbents 1,000 times as large as laboratory scale were successfully synthesized with the bench-scale equipment. Moreover, the adsorption performance with radioactive cesium in environmental water was evaluated at field tests in Fukushima Prefecture. As a result, the adsorbents could successfully remove radioactive cesium dissolved in environmental water below the detection limit of radioactivity concentration.

Journal Articles

A Novel avenue to gold nanostructured microtubes using functionalized fiber as the ligand, the reductant, and the template

Ma, H.*; Chi, H.*; Wu, J.*; Wang, M.*; Li, J.*; Hoshina, Hiroyuki; Saiki, Seiichi; Seko, Noriaki

Applied Materials & Interfaces, 5(17), p.8761 - 8765, 2013/09

Journal Articles

Abaca/polyester nonwoven fabric functionalization for metal ion adsorbent synthesis via electron beam-induced emulsion grafting

Madrid, J. F.*; Ueki, Yuji; Seko, Noriaki

Radiation Physics and Chemistry, 90, p.104 - 110, 2013/09

 Times Cited Count:10 Percentile:22.62(Chemistry, Physical)

A metal ion adsorbent was developed from a nonwoven fabric trunk material composed of both natural and synthetic polymers. A pre-irradiation technique was used for emulsion grafting of glycidyl methacrylate (GMA) onto an electron beam irradiated abaca/polyester nonwoven fabric (APNWF). The dependence of degree of grafting (Dg), calculated from the weight of APNWF before and after grafting, on absorbed dose, reaction time and monomer concentration were evaluated. After 50 kGy irradiation with 2 MeV electron beam and subsequent 3 h reaction with an emulsion consisting of 5% GMA and 0.5% polyoxyethylene sorbitan monolaurate (Tween 20) surfactant in deionized water at 40 $$^{circ}$$C, a grafted APNWF with a Dg greater than 150% was obtained. The GMA-grafted APNWF was further modified by reaction with ethylenediamine (EDA) in isopropyl alcohol at 60 $$^{circ}$$C to introduce amine functional groups. After a 3 h reaction with 50% EDA, an amine group density of 2.7 mmole/gram adsorbent was achieved based from elemental analysis. Batch adsorption experiments were performed using Cu$$^{2+}$$ and Ni$$^{2+}$$ ions in aqueous solutions with initial pH of 5 at 30 $$^{circ}$$C. Results show that the adsorption capacity of the grafted adsorbent for Cu$$^{2+}$$ is four times higher than Ni$$^{2+}$$ ions.

284 (Records 1-20 displayed on this page)