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-orbital transition metal multielemental alloy nanoparticles by atomically dispersed 4
-orbital Pd for a 100-fold extended lifetimeZhu, B.*; Huang, S.*; Seo, O.*; Cao, M.*; Matsumura, Daiju; Gu, H.*; Wu, D.*
Journal of the American Chemical Society, 147(13), p.11250 - 11256, 2025/02
Times Cited Count:81 Percentile:99.62(Chemistry, Multidisciplinary)Tang, J.*; Seo, O.*; Rivera Rocabado, D. S.*; Koitaya, Takanori*; Yamamoto, Susumu*; Namba, Yusuke*; Song, C.*; Kim, J.*; Yoshigoe, Akitaka; Koyama, Michihisa*; et al.
Applied Surface Science, 587, p.152797_1 - 152797_8, 2022/06
Times Cited Count:21 Percentile:77.13(Chemistry, Physical)The hydrogen absorption and diffusion mechanisms on cube-shaped Pd nanoparticles (NPs) which are important hydrogen-storage materials were studied using X-ray photoelectron spectroscopy and DFT calculations. In the surface region, hydrogen absorption showed almost similar behavior regardless of the NPs size. It was found that the octahedral sites are more favorable than the tetrahedral sites for hydrogen occupation. We also clarified that the hydrogen atoms absorbing on the smaller-sized Pd NPs diffuse to the subsurface more actively because of the weakened Pd-H bond by the surface disordering, which plays an important role in hydrogen adsorption at a low H
pressure.
dispersive X-ray absorption fine structure spectroscopySong, C.*; Seo, O.*; Matsumura, Daiju; Hiroi, Satoshi*; Cui, Y.-T.*; Kim, J.*; Chen, Y.*; Tayal, A.*; Kusada, Kohei*; Kobayashi, Hirokazu*; et al.
RSC Advances (Internet), 10(34), p.19751 - 19758, 2020/05
Times Cited Count:0 Percentile:0.00(Chemistry, Multidisciplinary)