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Hanawa, Kazutaka; Hirata, Tomohiro; Shibata, Ryodai; Yamada, Hiroyuki; Miyaji, Noriko
Dai-46-Kai Nihon Kaku Busshitsu Kanri Gakkai Nenji Taikai Kaigi Rombunshu (Internet), 4 Pages, 2025/12
no abstracts in English
Hirata, Tomohiro; Hanawa, Kazutaka; Shibata, Ryodai; Yamada, Hiroyuki; Yamazaki, Katsuyuki
Dai-46-Kai Nihon Kaku Busshitsu Kanri Gakkai Nenji Taikai Kaigi Rombunshu (Internet), 4 Pages, 2025/12
no abstracts in English
Shibata, Motoki*; Takenaka, Mikihito*; Motokawa, Ryuhei; Kumada, Takayuki; Ueda, Yuki; Miyazaki, Tsukasa*; Nakanishi, Yohei*; Abe, Jun*; Iwase, Hiroki*; Shibayama, Mitsuhiro*; et al.
Polymer, 340, p.129203_1 - 129203_7, 2025/12
Dei, Shuntaro; Shibata, Masahito*; Negishi, Kumi*; Sugiura, Yuki; Amano, Yuki; Bateman, K.*; Wilson, J.*; Yokoyama, Tatsunori; Kagami, Saya; Takeda, Masaki; et al.
Results in Earth Sciences (Internet), 3, p.100097_1 - 100097_16, 2025/12
Interactions between cement and host rock in geological repositories for radioactive waste will result in a chemically disturbed zone, which may potentially affect the long-term safety. This paper investigates the chemical evolution at the interface between cement (Ordinary Portland Cement: OPC and Low Alkaline Cement: LAC) and mudstone after 11 years of in situ reactions at the Horonobe Underground Research Laboratory. The study combines various analytical techniques to identify the key reactions at the cement-rock interface, including cement dissolution, precipitation of secondary minerals such as calcite and C-(A-)S-H phases, cation exchange in montmorillonite and reduced porosity in mudstone. The study also highlights the effects of cement-mudstone interactions on radionuclide migration, such as reduction of diffusivity due to reduced porosity and enhancement of sorption due to incorporation into secondary minerals in the altered mudstone.
Nagai, Takayuki; Aoyama, Yusuke; Okamoto, Yoshihiro; Shibata, Daisuke*; Asakura, Kiyotaka*; Hasegawa, Takehiko*; Sato, Seiichi*; Fukaya, Akane*; Kikuchi, Tetsuya*; Hatakeyama, Kiyoshi*
JAEA-Research 2025-009, 122 Pages, 2025/11
JAEA-Research-2025-009.pdf:20.77MB
XAFS measurements in the soft X-ray region are suitable for evaluating the chemical state of the surface layer of a measurement sample because the X-ray transmittance is low. This study measured the K-edges of the glass-forming elements boron (B), oxygen (O), sodium (Na), and silicon (Si), as well as the L
-edge of the waste component cerium (Ce), to verify the differences between the coagulated layer and the inside of simulated waste glasses made from raw glass compositions with increased alumina concentration. As a result, from the B K-edge XANES spectra, the proportion of B-O tetracoordinate sp
structures (BO
) on the surface layer of the coagulated glass samples was higher than that on the cut surface inside the glass samples. On the other hand, the O K-edge XANES spectra showed differences by measuring points for each glass sample, but the trends of those differences varied between the glass samples. The reason is that the molten raw glass with increased alumina concentration has a high viscosity, making it impossible to produce waste glasses with a uniform composition. The Na and Si K-edge spectra showed no differences between the coagulated layer and the inside of glass samples. In addition, the Ce L-edge XANES spectra confirmed that the Ce valence in the coagulated layer of glass samples was more oxidized compared to that in the inside of glass samples.
-butadiene) reinforced by carbon blackWatanabe, Yuki*; Kumagawa, Daiki*; Karitani, Shu*; Inoue, Tadashi*; Iwabuki, Hitoshi*; Nakanishi, Yohei*; Shibata, Motoki*; Motokawa, Ryuhei; Sugita, Tsuyoshi; Ueda, Yuki; et al.
Macromolecules, 58(16), p.8641 - 8648, 2025/08
Times Cited Count：0 Percentile：0.00Tamura, Yukiko*; Arakawa, Masato*; Takenaka, Mikihito*; Nakanishi, Yohei*; Fujinami, So*; Shibata, Motoki*; Yamamoto, Katsuhiro*; Miyata, Noboru*; Yamada, Masako*; Seto, Hideki*; et al.
Polymer, 333, p.128662_1 - 128662_8, 2025/08
Times Cited Count：0 Percentile：54.77(Polymer Science)Mochizuki, Akihito; Matsui, Hiroya; Nakayama, Masashi; Sakamoto, Ryo*; Shibata, Masahito*; Motoshima, Takayuki*; Jo, Mayumi*
Case Studies in Construction Materials, 22, p.e04648_1 - e04648_20, 2025/07
Times Cited Count：0 Percentile：0.00(Construction & Building Technology)The properties of low-pH cement used in the geological disposal of radioactive waste may change through atmospheric carbonation and degradation caused by groundwater during the long-term operation of a repository. In this study, we investigated the effects of atmospheric carbonation and groundwater contact on the chemical, microstructural, and transport properties of shotcrete made from low-pH, high-fly-ash silica-fume cement (HFSC) over a period of 16 years in an underground research laboratory. In both carbonated and degraded zones of the HFSC shotcrete, capillary porosity increased for pores of 
300 nm in diameter, and the total porosity was higher than in undegraded zones. These changes in porosity may be associated with the decalcification of calcium-silicate-hydrate and decomposition of ettringite. Such changes were minor in altered zones of OPC shotcrete, indicating that HFSC shotcrete is less resistant to atmospheric carbonation and groundwater leaching under the studied conditions. However, the hydraulic conductivity in HFSC was low enough to fulfill the specific functional requirements of low-pH cements for geological disposal.
Nagai, Takayuki; Okamoto, Yoshihiro; Shibata, Daisuke*; Kojima, Kazuo*; Hasegawa, Takehiko*; Sato, Seiichi*; Fukaya, Akane*; Hatakeyama, Kiyoshi*
JAEA-Research 2024-014, 54 Pages, 2025/02
JAEA-Research-2024-014.pdf:7.02MB
XAFS measurements in the soft X-ray region are suitable for evaluating the chemical state of the surface layer of a measurement sample because the X-ray transmittance is low. In this study, the purpose of the study was to confirm the difference between the coagulated surface layer and the inside of the simulated waste glasses by measuring the K-edge of the glass constituent elements boron, oxygen, sodium, and silicon, and the L edge of the waste component cerium. As a result, the B K-edge XANES spectra showed that the proportion of B-O tetracoordinate sp structures (BO) on the surface layer of the coagulated glass samples was higher than that on the cut surface inside the glass samples, which is expected to improve the water resistance of the coagulated surface. On the other hand, the O K-edge XANES spectra suggested that the O abundance in the coagulated surface layer was lower than that in the cut surface inside the glass samples, and that alkali metal elements may be concentrated in the coagulated surface layer. However, no difference was observed in the Na K-edge XANES spectra between the coagulated surface layer and the cut surface, and no difference was observed in the Si K-edge XANES spectra between the solidified surface and the inside of glass samples. In addition, the Ce L-edge XANES spectra confirmed that the Ce valence in the surface layer of coagulated glass samples were oxidized compared to the inside of glass samples.
Miyazaki, Tsukasa*; Miyata, Noboru*; Arima-Osonoi, Hiroshi*; Shimokita, Keisuke*; Yamamoto, Katsuhiro*; Takenaka, Mikihito*; Nakanishi, Yohei*; Shibata, Motoki*; Aoki, Hiroyuki; Yamada, Norifumi*; et al.
Colloids and Surfaces A; Physicochemical and Engineering Aspects, 701, p.134928_1 - 134928_8, 2024/11
Times Cited Count：0 Percentile：9.21(Chemistry, Physical)
insulator Sr
OsO
Wakabayashi, Yuki*; Krockenberger, Y.*; Yamagami, Kohei*; Wadachi, Hiroki*; Shibata, Goro; Fujimori, Atsushi*; Kawamura, Naomi*; Suzuki, Motohiro*; Taniyasu, Yoshitaka*; Yamamoto, Hideki*
SPring-8/SACLA Riyo Kenkyu Seikashu (Internet), 12(5), p.291 - 293, 2024/10
no abstracts in English
Ishibashi, Ryo*; Hirosaka, Kazuma*; Yamana, Takashi*; Shibata, Masatoshi*; Sasaki, Masana*; Nemoto, Yoshiyuki; Hinoki, Tatsuya*
Proceedings of TopFuel 2024 (Internet), 9 Pages, 2024/09
Shimokita, Keisuke*; Yamamoto, Katsuhiro*; Miyata, Noboru*; Shibata, Motoki*; Nakanishi, Yohei*; Arakawa, Masato*; Takenaka, Mikihito*; Kida, Takumitsu*; Tokumitsu, Katsuhisa*; Tanaka, Ryo*; et al.
Langmuir, 40(30), p.15758 - 15766, 2024/07
Times Cited Count：2 Percentile：39.94(Chemistry, Multidisciplinary)Nakanishi, Yohei*; Shibata, Motoki*; Sawada, Satoshi*; Kondo, Hiroaki*; Motokawa, Ryuhei; Kumada, Takayuki; Yamamoto, Katsuhiro*; Mita, Kazuki*; Miyazaki, Tsukasa*; Takenaka, Mikihito*
Polymer, 306, p.127209_1 - 127209_7, 2024/06
Times Cited Count：5 Percentile：63.61(Polymer Science)
4 simulated fuel bundle for validation of thermal-hydraulics simulation codesOno, Ayako; Nagatake, Taku; Uesawa, Shinichiro; Shibata, Mitsuhiko; Yoshida, Hiroyuki
Proceedings of Specialist Workshop on Advanced Instrumentation and Measurement Techniques for Nuclear Reactor Thermal-Hydraulics and Severe Accidents (SWINTH-2024) (USB Flash Drive), 7 Pages, 2024/06
Japan Atomic Energy Agency (JAEA) is developing a neutronics/thermal-hydraulics coupling simulation code for light-water reactors. Thermal-hydraulic simulation codes applied to the coupling code are expected to calculate the void fraction distribution in a rod bundle under operational conditions, which are necessary for neutron transport simulation, and need to be validated using void fraction distribution data in a rod bundle under high-temperature and high-pressure conditions. Therefore, we have conducted the measurement of the instantaneous void distribution in the 4 4 simulated fuel bundle using a developed wire mesh sensor, which is installed in the pressurized two-phase flow experimental loop of JAEA to obtain the data for code validation.
Ueji, Rintaro*; Gong, W.; Harjo, S.; Kawasaki, Takuro; Shibata, Akinobu*; Kimura, Yuji*; Inoue, Tadanobu*; Tsuchida, Noriyuki*
ISIJ International, 64(2), p.459 - 465, 2024/01
Times Cited Count：1 Percentile：32.08(Metallurgy & Metallurgical Engineering)Shibata, Ryodai; Amano, Tsukasa; Yamada, Hiroyuki; Miyaji, Noriko; Nakamura, Hironobu
Dai-44-Kai Nihon Kaku Busshitsu Kanri Gakkai Nenji Taikai Kaigi Rombunshu (Internet), 4 Pages, 2023/11
In April 2020, JAEA has been introduced Physical Protection Corrective Action Program (PPCAP) with full-scale. It was needed to introduce unified operation for six sites with different business scales, and headquarters developed the common guideline. There was an impression that physical protection activities were carried out by a limited number of employees. Therefore, a problem was to root and activate PPCAP activities among all employees in order to make them effective. Five activities were implemented to solve this problem. As a result, more than 3,700 condition reports (CR) have been collected for 4 years. This paper reports on the activities related to the PPCAP that have been implemented at JAEA.
Koyama, Shinichi; Ikeuchi, Hirotomo; Mitsugi, Takeshi; Maeda, Koji; Sasaki, Shinji; Onishi, Takashi; Tsai, T.-H.; Takano, Masahide; Fukaya, Hiroyuki; Nakamura, Satoshi; et al.
Hairo, Osensui, Shorisui Taisaku Jigyo Jimukyoku Homu Peji (Internet), 216 Pages, 2023/11
In FY 2021 and 2022, JAEA perfomed the subsidy program for "the Project of Decommissioning and Contaminated Water Management (Development of Analysis and Estimation Technology for Characterization of Fuel Debris (Development of Technologies for Enhanced Analysis Accuracy, Thermal Behavior Estimation, and Abbreviated Analysis))" started in FY 2021. This presentation material summarized the results of the project, which will be available shortly on the website of Management Office for the Project of Decommissioning, Contaminated Water and Treated Water Management.
Shibata, Motoki*; Nakanishi, Yohei*; Abe, Jun*; Arima, Hiroshi*; Iwase, Hiroki*; Shibayama, Mitsuhiro*; Motokawa, Ryuhei; Kumada, Takayuki; Takata, Shinichi; Yamamoto, Katsuhiro*; et al.
Polymer Journal, 55(11), p.1165 - 1170, 2023/11
Times Cited Count：3 Percentile：33.50(Polymer Science)
beam at J-PARC RCSSaha, P. K.; Harada, Hiroyuki; Yoneda, Hitoki*; Michine, Yurina*; Sato, Atsushi*; Shibata, Takanori*; Kinsho, Michikazu
Proceedings of 20th Annual Meeting of Particle Accelerator Society of Japan (Internet), p.59 - 63, 2023/11
