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Journal Articles

Stress and plastic strain partitioning behaviors and those contributions to martensitic transformation of retained austenite in medium manganese and transformation-induced plasticity-aided bainitic ferrite steels

Hojo, Tomohiko*; Koyama, Motomichi*; Kumai, Bakuya*; Zhou, Y.*; Shibayama, Yuki; Shiro, Ayumi*; Shobu, Takahisa; Saito, Hiroyuki*; Ajita, Saya*; Akiyama, Eiji*

ISIJ International, 65(2), p.284 - 296, 2025/02

Journal Articles

Stress-controlled hydrogen embrittlement failure in U-bend high-strength steel

Shibayama, Yuki; Hojo, Tomohiko*; Koyama, Motomichi*; Akiyama, Eiji*

International Journal of Hydrogen Energy, 88, p.1010 - 1016, 2024/10

 Times Cited Count:4 Percentile:51.25(Chemistry, Physical)

Journal Articles

Freeze-crosslinking approach for preparing carboxymethyl cellulose nanofiber/zirconium hydrogels as fluoride adsorbents

Sekine, Yurina; Nankawa, Takuya; Sugita, Tsuyoshi; Nagakawa, Yoshiyasu*; Shibayama, Yuki; Motokawa, Ryuhei; Ikeda-Fukazawa, Tomoko*

Nanoscale, 16(19), p.9400 - 9405, 2024/05

 Times Cited Count:3 Percentile:62.71(Chemistry, Multidisciplinary)

A tough carboxymethyl cellulose nanofiber (CMF)/ zirconium (Zr) hydrogel was obtained by freeze cross-linking method. The hydrogel was prepared by adding HCl solution containing Zr to frozen CMF and thawing it. The hydrogel showed high adsorptivity for fluoride. This simple gelation method provides useful insight for developing hydrogel-metal complexes.

Journal Articles

Nanocellulose hydrogels formed via crystalline transformation from cellulose I to II and subsequent freeze cross-linking reaction

Sekine, Yurina; Nankawa, Takuya; Hiroi, Kosuke; Oba, Yojiro*; Nagakawa, Yoshiyasu*; Sugita, Tsuyoshi; Shibayama, Yuki; Ikeda-Fukazawa, Tomoko*

Carbohydrate Polymers, 327, p.121538_1 - 121538_11, 2024/03

 Times Cited Count:11 Percentile:88.68(Chemistry, Applied)

We describe non-toxic, tough nanocellulose (NC) hydrogels formed from chemically unmodified NC by cellulose crystalline transformation and subsequent freeze cross-linking reaction. Using low-concentration NaOH and freezing together induced the crystalline transformation of NC from cellulose I to II via freeze concentration. After the crystalline transformation, cross-linking between the NC and CA in the freeze concentration layer (FCL) provided a strong NC network structure, forming NC hydrogels with high mechanical strength. The freeze-cross-linked NC hydrogel easily retained powder adsorbents in its inner space by mixing the NC-NaOH sol and the powder, and the hydrogel showed high removal efficiency for heavy metals. The results highlight the versatility of chemically unmodified celluloses in developing functional materials, suggest possible practical applications.

Journal Articles

Unstable stress-triaxiality development and contrasting weakening in two types of high-strength transformation-induced plasticity (TRIP) steels; Insights from a new compact tensile testing method

Matsuno, Takashi*; Fujita, Taiki*; Matsuda, Tomoko*; Shibayama, Yuki; Hojo, Tomohiko*; Watanabe, Ikumu*

Journal of Materials Processing Technology, 322, p.118174_1 - 118174_16, 2023/12

 Times Cited Count:8 Percentile:66.71(Engineering, Industrial)

The impact of high stress triaxiality on work hardening in transformation-induced plasticity (TRIP) steel has been widely acknowledged, particularly through measurements of the austenite fraction. Understanding this TRIP behavior is crucial for predicting material fracture in press-forming processes. However, the actual flow stresses under high-stress-triaxiality conditions remain largely undetermined. To address this gap, we developed a new tensile testing method using tiny notched round bars to investigate stress-triaxiality-induced work hardening in TRIP steels. The specimens were analyzed using two-dimensional micrometry to allow finite element analyses to identify the flow stress. Additionally, we conducted in situ tensile tests in which their crystal lattice stresses were monitored using synchrotron X-ray diffraction (XRD) to realize mechanism analyses of the unexpected work-hardening behavior identified by the developed tensile testing method. Our combined approach revealed a mutual, unstable increase in the flow stress and stress triaxiality in the TRIP-aided bainitic ferrite steel, which reduced the hardening exponent coefficients and thus induced a higher stress triaxiality. In contrast, the TRIP-aided martensitic steel exhibited a weakening behavior, characterized by a significant decrease in the hardening exponent coefficients in the case of the sharpest notch. XRD analyses showed that microstructural heterogeneity led to an extraordinarily high hydrostatic stress in the austenite phase, accounting for these contrasting behaviors. This finding challenges the established consensus on TRIP steels and suggests the need for a revised framework for their application in press-forming, taking into account stress-triaxiality conditions.

Journal Articles

Structural changes of polystyrene particles in subcritical and supercritical water revealed by in situ small-angle neutron scattering

Shibata, Motoki*; Nakanishi, Yohei*; Abe, Jun*; Arima, Hiroshi*; Iwase, Hiroki*; Shibayama, Mitsuhiro*; Motokawa, Ryuhei; Kumada, Takayuki; Takata, Shinichi; Yamamoto, Katsuhiro*; et al.

Polymer Journal, 55(11), p.1165 - 1170, 2023/11

 Times Cited Count:2 Percentile:19.24(Polymer Science)

Journal Articles

Hydrogen embrittlement of high-strength steel sheets

Hojo, Tomohiko*; Shibayama, Yuki; Ajita, Saya*; Koyama, Motomichi*; Akiyama, Eiji*

Materia, 61(7), p.413 - 418, 2022/07

no abstracts in English

Journal Articles

In situ neutron reflectometry analysis of interfacial structure formation between phenolic resin and silica during curing

Izumi, Atsushi*; Shudo, Yasuyuki*; Shibayama, Mitsuhiro*; Miyata, Noboru*; Miyazaki, Tsukasa*; Aoki, Hiroyuki

Langmuir, 37(47), p.13867 - 13872, 2021/11

 Times Cited Count:3 Percentile:14.46(Chemistry, Multidisciplinary)

Journal Articles

Effects of residual stress on hydrogen embrittlement of a stretch-formed tempered martensitic steel sheet

Nishimura, Hayato*; Hojo, Tomohiko*; Ajita, Saya*; Shibayama, Yuki*; Koyama, Motomichi*; Saito, Hiroyuki*; Shiro, Ayumi*; Yasuda, Ryo*; Shobu, Takahisa; Akiyama, Eiji*

Tetsu To Hagane, 107(9), p.760 - 768, 2021/09

 Times Cited Count:0 Percentile:0.00(Metallurgy & Metallurgical Engineering)

no abstracts in English

Journal Articles

Effects of residual stress on hydrogen embrittlement of a stretch-formed tempered martensitic steel sheet

Nishimura, Hayato*; Hojo, Tomohiko*; Ajita, Saya*; Shibayama, Yuki*; Koyama, Motomichi*; Saito, Hiroyuki*; Shiro, Ayumi*; Yasuda, Ryo*; Shobu, Takahisa; Akiyama, Eiji*

ISIJ International, 61(4), p.1170 - 1178, 2021/04

 Times Cited Count:7 Percentile:38.07(Metallurgy & Metallurgical Engineering)

Journal Articles

Effects of stress and plastic strain on hydrogen embrittlement fracture of a U-bent martensitic steel sheet

Shibayama, Yuki; Hojo, Tomohiko*; Koyama, Motomichi*; Saito, Hiroyuki*; Shiro, Ayumi*; Yasuda, Ryo*; Shobu, Takahisa; Matsuno, Takashi*; Akiyama, Eiji*

ISIJ International, 61(4), p.1322 - 1329, 2021/04

 Times Cited Count:7 Percentile:38.07(Metallurgy & Metallurgical Engineering)

Journal Articles

Interfacial cross-link inhomogeneity of a phenolic resin on a silica surface as revealed by X-ray and neutron reflection measurements

Izumi, Atsushi*; Shudo, Yasuyuki*; Shibayama, Mitsuhiro*; Yoshida, Tessei*; Miyata, Noboru*; Miyazaki, Tsukasa*; Aoki, Hiroyuki

Macromolecules, 53(10), p.4082 - 4089, 2020/05

 Times Cited Count:8 Percentile:27.68(Polymer Science)

Journal Articles

Diffusion behavior of methanol molecules confined in cross-linked phenolic resins studied using neutron scattering and molecular dynamics simulations

Shudo, Yasuyuki*; Izumi, Atsushi*; Hagita, Katsumi*; Yamada, Takeshi*; Shibata, Kaoru; Shibayama, Mitsuhiro*

Macromolecules, 51(16), p.6334 - 6343, 2018/08

 Times Cited Count:15 Percentile:43.78(Polymer Science)

Journal Articles

Development of the long-pulse ECRF system for JT-60SA

Kobayashi, Takayuki; Isayama, Akihiko; Fasel, D.*; Yokokura, Kenji; Shimono, Mitsugu; Hasegawa, Koichi; Sawahata, Masayuki; Suzuki, Sadaaki; Terakado, Masayuki; Hiranai, Shinichi; et al.

Journal of Plasma and Fusion Research SERIES, Vol.9, p.363 - 368, 2010/08

Improvements are required for expanding the pulse length of the JT-60 ECRF system (5s) for JT-60SA (100s). Newly developed power supplies will be fabricated and installed by EU. The conditioning operation of an improved gyrotron equipping a newly designed mode convertor has been started. The mode convertor will reduce heat flux on the internal components and therefore expected to enable long pulse operation at 1 MW. Pre-programmed and/or feedback control of the heater current and anode voltage, which was successfully demonstrated in JT-60U, will be key techniques because the beam current decreases during a shot. The evacuated transmission lines have a capability of 1 MW per line. Since maintenance of the components in the vacuum vessel is difficult, a linear motion antenna concept was proposed to reduce risks of water leakage and fault of the driving mechanism in the vacuum vessel. The detailed design and the low power test of a mock-up antenna have been started.

Journal Articles

Protonation states of buried histidine residues in human deoxyhemoglobin revealed by neutron crystallography

Chatake, Toshiyuki*; Shibayama, Naoya*; Park, S. Y.*; Kurihara, Kazuo; Tamada, Taro; Tanaka, Ichiro*; Niimura, Nobuo*; Kuroki, Ryota; Morimoto, Yukio*

Journal of the American Chemical Society, 129(48), p.14840 - 14841, 2007/12

 Times Cited Count:26 Percentile:60.48(Chemistry, Multidisciplinary)

Journal Articles

Recent results on beryllium and beryllides in Japan

Mishima, Yoshinao*; Yoshida, Naoaki*; Kawamura, Hiroshi; Ishida, Kiyohito*; Hatano, Yuji*; Shibayama, Tamaki*; Munakata, Kenzo*; Sato, Yoshiyuki*; Uchida, Munenori*; Tsuchiya, Kunihiko; et al.

Journal of Nuclear Materials, 367-370(2), p.1382 - 1386, 2007/08

 Times Cited Count:29 Percentile:85.50(Materials Science, Multidisciplinary)

no abstracts in English

Journal Articles

Development of beryllides as advanced neutron multipliers for fusion blankets

Tsuchiya, Kunihiko; Kawamura, Hiroshi; Mishima, Yoshinao*; Yoshida, Naoaki*; Tanaka, Satoru*; Uchida, Munenori*; Ishida, Kiyohito*; Shibayama, Tamaki*; Munakata, Kenzo*; Sato, Yoshiyuki*; et al.

Purazuma, Kaku Yugo Gakkai-Shi, 83(3), p.207 - 214, 2007/03

no abstracts in English

Journal Articles

Status of beryllium R&D in Japan

Kawamura, Hiroshi; Tsuchiya, Kunihiko; Mishima, Yoshinao*; Yoshida, Naoaki*; Munakata, Kenzo*; Ishida, Kiyohito*; Hatano, Yuji*; Shibayama, Tamaki*; Sato, Yoshiyuki*; Uchida, Munenori*; et al.

INL/EXT-06-01222, p.1 - 7, 2006/02

no abstracts in English

Journal Articles

Effects of He/Electron irradiation on microstructure evolution in Be$$_{12}$$Ti

Shibayama, Tamaki*; Nakamichi, Masaru*; Uchida, Munenori*; Kawamura, Hiroshi; Kinoshita, Hiroshi*; Kiyanagi, Yoshiaki*; Takahashi, Heishichiro*; Nomura, Naoyuki*

JAERI-Conf 2004-006, p.216 - 219, 2004/03

no abstracts in English

Oral presentation

Fundamental study on electrolyte recycle process by phosphate conversion technique, 9; Study on sorption mechanism of iron phosphate-glass as sorbent

Amamoto, Ippei; Kofuji, Hirohide; Tsuzuki, Tatsuya*; Mitamura, Naoki*; Takasaki, Yasushi*; Shibayama, Atsushi*; Yano, Tetsuji*; Terai, Takayuki*

no journal, , 

no abstracts in English

62 (Records 1-20 displayed on this page)