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Journal Articles

Nanocellulose hydrogels formed via crystalline transformation from cellulose I to II and subsequent freeze cross-linking reaction

Sekine, Yurina; Nankawa, Takuya; Hiroi, Kosuke; Oba, Yojiro*; Nagakawa, Yoshiyasu*; Sugita, Tsuyoshi; Shibayama, Yuki; Ikeda-Fukazawa, Tomoko*

Carbohydrate Polymers, 327, p.121538_1 - 121538_11, 2024/03

 Times Cited Count:0 Percentile:0.01(Chemistry, Applied)

We describe non-toxic, tough nanocellulose (NC) hydrogels formed from chemically unmodified NC by cellulose crystalline transformation and subsequent freeze cross-linking reaction. Using low-concentration NaOH and freezing together induced the crystalline transformation of NC from cellulose I to II via freeze concentration. After the crystalline transformation, cross-linking between the NC and CA in the freeze concentration layer (FCL) provided a strong NC network structure, forming NC hydrogels with high mechanical strength. The freeze-cross-linked NC hydrogel easily retained powder adsorbents in its inner space by mixing the NC-NaOH sol and the powder, and the hydrogel showed high removal efficiency for heavy metals. The results highlight the versatility of chemically unmodified celluloses in developing functional materials, suggest possible practical applications.

Journal Articles

Structural changes of polystyrene particles in subcritical and supercritical water revealed by in situ small-angle neutron scattering

Shibata, Motoki*; Nakanishi, Yohei*; Abe, Jun*; Arima, Hiroshi*; Iwase, Hiroki*; Shibayama, Mitsuhiro*; Motokawa, Ryuhei; Kumada, Takayuki; Takata, Shinichi; Yamamoto, Katsuhiro*; et al.

Polymer Journal, 55(11), p.1165 - 1170, 2023/11

 Times Cited Count:1 Percentile:51.7(Polymer Science)

Journal Articles

Hydrogen embrittlement of high-strength steel sheets

Hojo, Tomohiko*; Shibayama, Yuki; Ajita, Saya*; Koyama, Motomichi*; Akiyama, Eiji*

Materia, 61(7), p.413 - 418, 2022/07

no abstracts in English

Journal Articles

In situ neutron reflectometry analysis of interfacial structure formation between phenolic resin and silica during curing

Izumi, Atsushi*; Shudo, Yasuyuki*; Shibayama, Mitsuhiro*; Miyata, Noboru*; Miyazaki, Tsukasa*; Aoki, Hiroyuki

Langmuir, 37(47), p.13867 - 13872, 2021/11

 Times Cited Count:2 Percentile:14.88(Chemistry, Multidisciplinary)

Journal Articles

Effects of residual stress on hydrogen embrittlement of a stretch-formed tempered martensitic steel sheet

Nishimura, Hayato*; Hojo, Tomohiko*; Ajita, Saya*; Shibayama, Yuki*; Koyama, Motomichi*; Saito, Hiroyuki*; Shiro, Ayumi*; Yasuda, Ryo*; Shobu, Takahisa; Akiyama, Eiji*

Tetsu To Hagane, 107(9), p.760 - 768, 2021/09

 Times Cited Count:0 Percentile:0(Metallurgy & Metallurgical Engineering)

no abstracts in English

Journal Articles

Effects of stress and plastic strain on hydrogen embrittlement fracture of a U-bent martensitic steel sheet

Shibayama, Yuki; Hojo, Tomohiko*; Koyama, Motomichi*; Saito, Hiroyuki*; Shiro, Ayumi*; Yasuda, Ryo*; Shobu, Takahisa; Matsuno, Takashi*; Akiyama, Eiji*

ISIJ International, 61(4), p.1322 - 1329, 2021/04

 Times Cited Count:3 Percentile:25.78(Metallurgy & Metallurgical Engineering)

Journal Articles

Effects of residual stress on hydrogen embrittlement of a stretch-formed tempered martensitic steel sheet

Nishimura, Hayato*; Hojo, Tomohiko*; Ajita, Saya*; Shibayama, Yuki*; Koyama, Motomichi*; Saito, Hiroyuki*; Shiro, Ayumi*; Yasuda, Ryo*; Shobu, Takahisa; Akiyama, Eiji*

ISIJ International, 61(4), p.1170 - 1178, 2021/04

 Times Cited Count:3 Percentile:25.78(Metallurgy & Metallurgical Engineering)

Journal Articles

Interfacial cross-link inhomogeneity of a phenolic resin on a silica surface as revealed by X-ray and neutron reflection measurements

Izumi, Atsushi*; Shudo, Yasuyuki*; Shibayama, Mitsuhiro*; Yoshida, Tessei*; Miyata, Noboru*; Miyazaki, Tsukasa*; Aoki, Hiroyuki

Macromolecules, 53(10), p.4082 - 4089, 2020/05

 Times Cited Count:7 Percentile:32.71(Polymer Science)

Journal Articles

Diffusion behavior of methanol molecules confined in cross-linked phenolic resins studied using neutron scattering and molecular dynamics simulations

Shudo, Yasuyuki*; Izumi, Atsushi*; Hagita, Katsumi*; Yamada, Takeshi*; Shibata, Kaoru; Shibayama, Mitsuhiro*

Macromolecules, 51(16), p.6334 - 6343, 2018/08

 Times Cited Count:11 Percentile:40.86(Polymer Science)

Journal Articles

Development of the long-pulse ECRF system for JT-60SA

Kobayashi, Takayuki; Isayama, Akihiko; Fasel, D.*; Yokokura, Kenji; Shimono, Mitsugu; Hasegawa, Koichi; Sawahata, Masayuki; Suzuki, Sadaaki; Terakado, Masayuki; Hiranai, Shinichi; et al.

Journal of Plasma and Fusion Research SERIES, Vol.9, p.363 - 368, 2010/08

Improvements are required for expanding the pulse length of the JT-60 ECRF system (5s) for JT-60SA (100s). Newly developed power supplies will be fabricated and installed by EU. The conditioning operation of an improved gyrotron equipping a newly designed mode convertor has been started. The mode convertor will reduce heat flux on the internal components and therefore expected to enable long pulse operation at 1 MW. Pre-programmed and/or feedback control of the heater current and anode voltage, which was successfully demonstrated in JT-60U, will be key techniques because the beam current decreases during a shot. The evacuated transmission lines have a capability of 1 MW per line. Since maintenance of the components in the vacuum vessel is difficult, a linear motion antenna concept was proposed to reduce risks of water leakage and fault of the driving mechanism in the vacuum vessel. The detailed design and the low power test of a mock-up antenna have been started.

Journal Articles

Protonation states of buried histidine residues in human deoxyhemoglobin revealed by neutron crystallography

Chatake, Toshiyuki*; Shibayama, Naoya*; Park, S. Y.*; Kurihara, Kazuo; Tamada, Taro; Tanaka, Ichiro*; Niimura, Nobuo*; Kuroki, Ryota; Morimoto, Yukio*

Journal of the American Chemical Society, 129(48), p.14840 - 14841, 2007/12

 Times Cited Count:25 Percentile:60.26(Chemistry, Multidisciplinary)

Journal Articles

Recent results on beryllium and beryllides in Japan

Mishima, Yoshinao*; Yoshida, Naoaki*; Kawamura, Hiroshi; Ishida, Kiyohito*; Hatano, Yuji*; Shibayama, Tamaki*; Munakata, Kenzo*; Sato, Yoshiyuki*; Uchida, Munenori*; Tsuchiya, Kunihiko; et al.

Journal of Nuclear Materials, 367-370(2), p.1382 - 1386, 2007/08

 Times Cited Count:26 Percentile:84.1(Materials Science, Multidisciplinary)

no abstracts in English

Journal Articles

Development of beryllides as advanced neutron multipliers for fusion blankets

Tsuchiya, Kunihiko; Kawamura, Hiroshi; Mishima, Yoshinao*; Yoshida, Naoaki*; Tanaka, Satoru*; Uchida, Munenori*; Ishida, Kiyohito*; Shibayama, Tamaki*; Munakata, Kenzo*; Sato, Yoshiyuki*; et al.

Purazuma, Kaku Yugo Gakkai-Shi, 83(3), p.207 - 214, 2007/03

no abstracts in English

Journal Articles

Status of beryllium R&D in Japan

Kawamura, Hiroshi; Tsuchiya, Kunihiko; Mishima, Yoshinao*; Yoshida, Naoaki*; Munakata, Kenzo*; Ishida, Kiyohito*; Hatano, Yuji*; Shibayama, Tamaki*; Sato, Yoshiyuki*; Uchida, Munenori*; et al.

INL/EXT-06-01222, p.1 - 7, 2006/02

no abstracts in English

Journal Articles

Effects of He/Electron irradiation on microstructure evolution in Be$$_{12}$$Ti

Shibayama, Tamaki*; Nakamichi, Masaru*; Uchida, Munenori*; Kawamura, Hiroshi; Kinoshita, Hiroshi*; Kiyanagi, Yoshiaki*; Takahashi, Heishichiro*; Nomura, Naoyuki*

JAERI-Conf 2004-006, p.216 - 219, 2004/03

no abstracts in English

Oral presentation

Effect of minor alloying element on dispersing nano-particles in ODS steel

Uchida, Yosuke*; Nagai, Yoshiyasu*; Suda, Takanori*; Hashimoto, Naoyuki*; Onuki, Somei*; Shibayama, Tamaki*; Yamashita, Shinichiro; Akasaka, Naoaki

no journal, , 

no abstracts in English

Oral presentation

Fundamental study for development of austenitic ODS steel; Effect of nano-particle dispersion on radiation-induced defect formation

Yamashita, Shinichiro; Otsuka, Satoshi; Watanabe, Masashi*; Uchida, Yosuke*; Suda, Takanori*; Hashimoto, Naoyuki*; Onuki, Somei*; Shibayama, Tamaki*

no journal, , 

no abstracts in English

Oral presentation

Development of power modulation on JT-60U ECRF system

Kobayashi, Takayuki; Isayama, Akihiko; Terakado, Masayuki; Sato, Fumiaki; Sawahata, Masayuki; Suzuki, Sadaaki; Hiranai, Shinichi; Igarashi, Koichi; Wada, Kenji; Shimono, Mitsugu; et al.

no journal, , 

It is recognized that stabilization of neoclassical tearing mode (NTM) instabilities using power modulated electron cyclotron current drive (ECCD) is effective. Although a modulation frequency of around 5 kHz was required to NTM suppression experiments in JT-60U, the achieved frequency had been limited to 3 kHz due to the slow response time of the high voltage circuit and over-current during charging/discharging. In this study, the anode voltage divider of the system was improved and the capacitance and resistance in the high voltage circuit was optimized resulting in the modulation frequency of over 5 kHz. The robust modulated operation region was also studied with suppressing undesired mode. Moreover, the real-time synchronizing system was developed to control the phase and duty ratio of the modulated ECCD synchronizing with the NTM frequency which varies during ECCD with plasma rotation, and modulated ECCD experiments with NTM suppression was carried out in JT-60U.

Oral presentation

Development of 100-second ECRF system for JT-60SA

Moriyama, Shinichi; Kobayashi, Takayuki; Isayama, Akihiko; Yokokura, Kenji; Shimono, Mitsugu; Hasegawa, Koichi; Sawahata, Masayuki; Suzuki, Sadaaki; Terakado, Masayuki; Hiranai, Shinichi; et al.

no journal, , 

The electron cyclotron range of frequency (ECRF) system (3 MW $$times$$ 5s at 110 GHz with 4 gyrotrons) of JT-60U will be upgrade to the system having 9 gyrotrons (7 MW $$times$$ 100s) for JT-60SA (super advanced). As heat removal from the mirrors is essential for a long pulse antenna, a new concept with a mirror driven in the linear motion which eliminates the flexible tube for coolant supply is under development. The design study featuring beam profile calculation showed feasibility of the antenna in the 0.48 m $$times$$ 0.48 m port. The low power rf test with simple mockup antenna has just been begun. Aging of the gyrotron with improved mode converter was started in the end of 2008, aiming at 1 MW, 100s oscillation. Because the current capacity of the present high voltage power supply is not enough to realize 100s oscillation, LHRF power supply having twice larger current capacity is connected to the gyrotron in March 2009. The gyrotron aging will be started soon again.

Oral presentation

Development of ECRF system toward steady-state operation in JT 60SA

Isayama, Akihiko; Kobayashi, Takayuki; Moriyama, Shinichi; Sawahata, Masayuki; Suzuki, Sadaaki; Yokokura, Kenji; Shimono, Mitsugu; Hasegawa, Koichi; Terakado, Masayuki; Hiranai, Shinichi; et al.

no journal, , 

no abstracts in English

55 (Records 1-20 displayed on this page)