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Journal Articles

Characterization of hydrogen embrittlement of Ti and Ti-5Ta alloys using constant load test

Yokoyama, Kenichi*; Murata, Yusuke*; Shiimori, Fusae*; Sakai, Junichi*; Yamamoto, Masahiro; Uchiyama, Gunzo; Nojima, Yasuo*; Fujine, Sachio*

Fushoku Boshoku Kyokai Dai-58-Kai Zairyo To Kankyo Toronkai Koenshu, p.11 - 12, 2011/09

Characteristics of hydrogen embrittlement of pure Ti and Ti-5Ta alloys were evaluated by stress loading and constant load tests. Mechanical properties of these materials were affected by hydride formation of surface layers. Although elongation was reduced by hydrogen absorption, embrittlement was observed only in the surface hydride area. It is also suggested that Ti-5Ta alloy was better susceptibility of hydrogen embrittlement than pure Ti.

Journal Articles

Hydrogen absorption of titanium and Ti-5Ta in nitric acid solutions under irradiation

Shiimori, Fusae*; Sakai, Junichi*; Yokoyama, Kenichi*; Motooka, Takafumi; Uchiyama, Gunzo; Nojima, Yasuo*; Fujine, Sachio*

Fushoku Boshoku Kyokai Dai-58-Kai Zairyo To Kankyo Toronkai Koenshu, p.13 - 14, 2011/09

In reprocessing plants, hydrogen gas was released by radiolysis of aqueous solution. The relationship of the amount of hydrogen gas and the amount of hydrogen absorption to titanium and Ti-5Ta were not clear. In this study, hydrogen was absorbed to titanium by the cathode charging and irradiation. Then, the amount of the hydrogen gas from solutions and the amount of the hydrogen absorbed to titanium was compared. It was found that a very small amount of the hydrogen by radiolysis was absorbed to titanium. It was suggested that the difference of the hydrogen absorption rate was caused by the difference of the hydrogen concentration on the metal surface.

Oral presentation

Study on ageing behavior of peprocessing plants, 8; Hydrogen formation by Irradiation and hydrogen adsorption of titanium in nitrate solutions

Motooka, Takafumi; Yamamoto, Masahiro; Ueno, Fumiyoshi; Ishijima, Yasuhiro; Uchiyama, Gunzo; Nojima, Yasuo*; Fujine, Sachio*; Sakai, Junichi*; Shiimori, Fusae*; Miyasaka, Yuto*

no journal, , 

As a part of studies on ageing behavior of reprocessing plants, the amount of hydrogen gas generated from nitrate solutions under $$gamma$$ irradiation and the amount of hydrogen absorbed to titanium alloy were measured after $$gamma$$ irradiation in order to evaluate the hydrogen degradation of instruments made of titanium alloy. The amount of hydrogen gas was decreased with increase of nitrate concentration. Only a little hydrogen was absorbed to titanium. It is necessary to consider the long-time prediction model for hydrogen adsorption to evaluate hydrogen degradation.

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