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Journal Articles

Development of function-graded proton exchange membrane for PEFC using heavy ion beam irradiation

Shiraki, Fumiya*; Yoshikawa, Taeko*; Oshima, Akihiro*; Oshima, Yuji*; Takasawa, Yuya*; Fukutake, Naoyuki*; Oyama, Tomoko*; Urakawa, Tatsuya*; Fujita, Hajime*; Takahashi, Tomohiro*; et al.

Nuclear Instruments and Methods in Physics Research B, 269(15), p.1777 - 1781, 2011/08

 Times Cited Count:8 Percentile:53.37(Instruments & Instrumentation)

The graded energy deposition of heavy ion beam irradiation to polymeric materials was utilized to synthesize a novel proton exchange membrane (PEM) with the graded density of sulfonic acid groups toward the thickness direction. Stacked Poly(tetrafluoroethylene-co-hexafluoropropylene) (FEP) films were irradiated by Xe$$^{54+}$$ ion beam with the energy of 6 MeV/u under a vacuum condition. Irradiated films were grafted with styrene monomer and then sulfonated. The membrane electrode assembly (MEA) fabricated by the function graded PEM showed improved fuel cell performance in terms of voltage stability. It was expected that the function-graded PEM could control the graded concentration of sulfonic acid groups in PEM.

Oral presentation

Study on direct etching of fluoropolymers by heavy ion beam irradiation

Takasawa, Yuya*; Fukutake, Naoyuki*; Takahashi, Tomohiro*; Urakawa, Tatsuya*; Oshima, Yuji*; Gowa, Tomoko*; Shiraki, Fumiya*; Fujita, Hajime*; Oka, Toshitaka; Murakami, Takeshi*; et al.

no journal, , 

Oral presentation

Development of functionally-graded materials using high energy heavy ion beam

Oshima, Akihiro*; Shiraki, Fumiya*; Takasawa, Yuya*; Fujita, Hajime*; Yoshikawa, Taeko*; Tatsumi, Takahiro*; Tsubokura, Hidehiro*; Takahashi, Tomohiro*; Gowa, Tomoko*; Sakaue, Kazuyuki*; et al.

no journal, , 

no abstracts in English

Oral presentation

Fabrication of functionally gradient PEM using heavy ion beams grafting

Washio, Masakazu*; Shiraki, Fumiya*; Oshima, Yuji*; Takasawa, Yuya*; Fujita, Hajime*; Gowa, Tomoko*; Kudo, Hisaaki*; Oka, Toshitaka; Hama, Yoshimasa*; Murakami, Takeshi*; et al.

no journal, , 

no abstracts in English

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