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Sasaki, Yuji; Yoshimitsu, Ryo*; Nishihama, Shohei*; Shimbori, Yuma*; Shiroishi, Hidenobu*
Separation Science and Technology, 52(7), p.1186 - 1192, 2017/03
Times Cited Count：2 Percentile：7.68(Chemistry, Multidisciplinary)The new extractant, biuret(C8), is synthesized and tested for the solvent extraction of hard acid metals like actinides and soft acid metals. This compound has the similar central frame to malonamide but with 2-NH introduced into the central frame, then both amidic oxygen and nitrogen atoms may bond with metals. From the present work, not only hard acid metals, but also soft acid metals can be extracted by biuret(C8) from nitric or perchloric acids to n-dodecane. The extractability for biuret(C8) is compared with other representative extractants, malonamide, TODGA and MIDOA. It is clear that the distribution ratio(D) of U and Pu by biuret(C8) is similar to those for malonamide, but with lower values than those for TODGA and MIDOA, and D for soft acid metals and oxonium anions show higher values than those for TODGA and malonamide and lower than those for MIDOA.
Suzuki, Hiroshi; Kusunoki, Koichi*; Kanematsu, Manabu*; Tasai, Akira*; Hatanaka, Yuichi*; Tsuchiya, Naoko*; Bae, S.*; Shiroishi, Sho*; Sakurai, Sonoko*; Kawasaki, Takuro; et al.
JPS Conference Proceedings (Internet), 8, p.031006_1 - 031006_6, 2015/09
The bond resistance between reinforcing bar (rebar) and concrete is one important parameter for examining integrity of the reinforced concrete structure, and is commonly evaluated by measuring the strain distribution along the rebar embedded in concrete. Here we present two types of applications of the time-of-flight neutron diffraction technique to measure the stress distribution of the rebar. It was demonstrated that bond deterioration around cracks developed in concrete can be evaluated by measuring the stress distribution along the embedded rebar using neutron diffraction. Furthermore, a change in the stress distribution along the rebar due to bond deterioration by corrosion was observed. The neutron diffraction technique is expected to become a novel method for measuring the stress (strain) of the rebar embedded in concrete, and will eventually provide insight into the actual phenomena on the reinforced concrete structures.
Sasaki, Yuji; Yoshimitsu, Ryo*; Nishihama, Shohei*; Shimbori, Yuma*; Shiroishi, Hidenobu*
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no abstracts in English
