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Journal Articles

Effects of diluents on the separation of minor actinides from lanthanides with tetradodecyl-1,10-phenanthroline-2,9-diamide from nitric acid medium

Tsutsui, Nao; Ban, Yasutoshi; Suzuki, Hideya*; Nakase, Masahiko*; Ito, Sayumi*; Inaba, Yusuke*; Matsumura, Tatsuro; Takeshita, Kenji*

Analytical Sciences, 36(2), p.241 - 246, 2020/02

 Times Cited Count:1 Percentile:100(Chemistry, Analytical)

To investigate the effective separation of actinides (Ans) from lanthanides (Lns), single-stage batch extraction experiments were performed with a novel extractant, tetradodecyl-1,10-phenanthroline-2,9-diamide (TDdPTDA) with various diluents such as 3-nitrobenzotrifluoride (F-3), nitrobenzene, and ${it n}$-dodecane for Am, Cm, and Lns. The extraction kinetics with TDdPTDA was rapid enough to perform the actual extraction flow sheet. The slopes of the distribution ratio versus TDdPTDA concentration and the distribution ratio versus nitric acid concentration were similar for F-3 and nitrobenzene systems but different from ${it n}$-dodecane system. These differences were attributed to the characteristics of the diluents. This study reveals high distribution ratios of Am (${it D}$ $$_{Am}$$) and Cm (${it D}$ $$_{Cm}$$) for TDdPTDA, with the high separation factors (${it SF}$s) of Am from Lns enough for their separation.

Journal Articles

High stereographic resolution texture and residual stress evaluation using time-of-flight neutron diffraction

Xu, P. G.; Harjo, S.; Ojima, Mayumi*; Suzuki, Hiroshi; Ito, Takayoshi*; Gong, W.; Vogel, S. C.*; Inoue, Junya*; Tomota, Yo*; Aizawa, Kazuya; et al.

Journal of Applied Crystallography, 51(3), p.746 - 760, 2018/06

 Times Cited Count:10 Percentile:9.56(Chemistry, Multidisciplinary)

Journal Articles

Pair distribution function analysis of nanostructural deformation of calcium silicate hydrate under compressive stress

Bae, S.*; Jee, H.*; Kanematsu, Manabu*; Shiro, Ayumi*; Machida, Akihiko*; Watanuki, Tetsu*; Shobu, Takahisa; Suzuki, Hiroshi

Journal of the American Ceramic Society, 101(1), p.408 - 418, 2018/01

 Times Cited Count:6 Percentile:37.67(Materials Science, Ceramics)

Despite enormous interest in calcium silicate hydrate (C-S-H), its detailed atomic structure and intrinsic deformation under an external load are lacking. This study demonstrates the nanostructural deformation process of C-S-H in tricalcium silicate (C$$_{3}$$S) paste as a function of applied stress by interpreting atomic pair distribution function (PDF) based on in situ X-ray scattering. Three different strains in C$$_{3}$$S paste under compression were compared using a strain gauge and the real and reciprocal space PDFs. PDF refinement revealed that the C-S-H phase mostly contributed to PDF from 0 to 20${AA}$ whereas crystalline phases dominated that beyond 20${AA}$. The short-range atomic strains exhibited two regions for C-S-H: I) plastic deformation (0-10 MPa) and II) linear elastic deformation ($$>$$10 MPa), whereas the long-range deformation beyond 20${AA}$ was similar to that of Ca(OH)$$_{2}$$. Below 10 MPa, the short-range strain was caused by the densification of C-S-H induced by the removal of interlayer or gel-pore water. The strain is likely to be recovered when the removed water returns to C-S-H.

Journal Articles

Mesoporous alumina as an effective adsorbent for molybdenum (Mo) toward Instant production of radioisotope for medical use

Saptiama, I.*; Kaneti, Y. V.*; Suzuki, Yumi*; Suzuki, Yoshitaka; Tsuchiya, Kunihiko; Sakae, Takeji*; Takai, Kimiko*; Fukumitsu, Nobuyoshi*; Alothman, Z. A.*; Hossain, M. S. A.*; et al.

Bulletin of the Chemical Society of Japan, 90(10), p.1174 - 1179, 2017/10

 Times Cited Count:33 Percentile:10.95(Chemistry, Multidisciplinary)

no abstracts in English

Journal Articles

Local deformation analysis in martensite layer of high-strength multilayered steel composite using synchrotron X-ray diffraction

Ojima, Mayumi*; Shiro, Ayumi*; Suzuki, Hiroshi; Inoue, Junya*; Shobu, Takahisa; Xu, P. G.; Akita, Koichi; Nambu, Shoichi*; Koseki, Toshihiko*

Zairyo, 66(6), p.420 - 426, 2017/06

Journal Articles

SAS4A analysis study on the initiating phase of ATWS events for generation-IV loop-type SFR

Kubota, Ryuzaburo; Koyama, Kazuya*; Moriwaki, Hiroyuki*; Yamada, Yumi*; Shimakawa, Yoshio*; Suzuki, Toru; Kawada, Kenichi; Kubo, Shigenobu; Yamano, Hidemasa

Proceedings of 2017 International Congress on Advances in Nuclear Power Plants (ICAPP 2017) (CD-ROM), 10 Pages, 2017/04

This paper describes an analysis study on the initiating phase of the ATWS events with SAS4A in order to confirm the appropriateness of the core design for the medium-scale SFR (750MWe-1765MWt). Not using a conventional lumping method that multiple fuel sub-assemblies having a similar characteristic were assigned to one channel (representing fuel assembly in SAS4A), each channel represents only the sub-assemblies of identical operating condition. In addition, the detailed power and reactivity distribution were set reflecting the change of insertion position of control rods. Applying these detailed analysis conditions, the SAS4A analyses were performed for unprotected loss-of-flow (ULOF) and unprotected transient overpower (UTOP) during both of the nominal power and the partial power operation. As a result, more proper event progression including incoherency of events especially fuel dispersion after fuel failure was successfully evaluated and then this analysis study suggested that the power excursion with prompt criticality leading to large mechanical energy release can be prevented in the initiating phase of the current design.

JAEA Reports

Preliminary tests on adsorption / desorption of alumina adsorbents

Suzuki, Yoshitaka; Ishida, Takuya*; Suzuki, Yumi*; Matsukura, Minoru*; Kurosaki, Fumio*; Nishikata, Kaori; Mimura, Hitoshi*; Tsuchiya, Kunihiko

JAEA-Technology 2016-027, 24 Pages, 2016/12


The research and development (R&D) on the production of $$^{99}$$Mo/$$^{99m}$$Tc by (n,$$gamma$$) method has been carried out in the Neutron Irradiation and Testing Reactor Center. The $$^{99}$$Mo production by (n,$$gamma$$) reaction is a simple and easy method, and it also is advantageous from viewpoints of nuclear proliferation resistance and waste management. However, it is difficult to produce the $$^{99m}$$Tc solution with high radioactive concentration because the specific radioactivity of $$^{99}$$Mo by this method is extremely low. Up to now, various Mo absorbents such as Polyzirconium Compound (PZC) and Polytitanium Compound (PTC) have been developed with high Mo adsorption efficiency. It is necessary for utilization to the generator of these absorbents to evaluate the effect of elements containing these absorbents and to assure the quality of $$^{99m}$$Tc solution. In this report, the status of R&D of the Mo adsorbents was investigated. The alumina as Mo adsorbent, which uses in medical $$^{99}$$Mo/$$^{99m}$$Tc generator, was focused and Mo adsorption/desorption properties of three kinds of alumina was evaluated by different properties such as crystal structure and specific surface.

Journal Articles

Microstructure analysis in steel using quantum beam diffraction method

Sato, Shigeo*; Onuki, Yusuke*; Shobu, Takahisa; Shiro, Ayumi*; Tashiro, Hitoshi*; Todoroki, Hidekazu*; Suzuki, Shigeru*

Kinzoku, 86(8), p.654 - 660, 2016/08

no abstracts in English

Journal Articles

Hydrostatic compression behavior and high-pressure stabilized $$beta$$-phase in $$gamma$$-based titanium aluminide intermetallics

Liss, K.-D.*; Funakoshi, Kenichi*; Dippenaar, R. J.*; Higo, Yuji*; Shiro, Ayumi*; Reid, M.*; Suzuki, Hiroshi; Shobu, Takahisa; Akita, Koichi

Metals, 6(7), p.165_1 - 165_22, 2016/07

 Times Cited Count:14 Percentile:24.19(Materials Science, Multidisciplinary)

Titanium aluminides find application in modern light-weight, high-temperature turbines, such as aircraft engines, but suffer from poor plasticity during manufacturing and processing. Huge forging presses enable materials processing in the 10 GPa range and hence, it is necessary to investigate the phase-diagrams of candidate materials under these extreme conditions. Here we report on an in-situ synchrotron X-ray diffraction study in a large-volume-press of a modern ($$alpha_{2}$$ + $$gamma$$) two-phase material, Ti-45Al-7.5Nb-0.25C, under pressures up to 9.6 GPa and temperatures up to 1686 K. At room temperature, the volume response to pressure is accommodated by the transformation $$gamma$$ $$rightarrow$$ $$alpha_{2}$$ rather than volumetric strain, expressed by apparently high bulk moduli of both constituent phases. Crystallographic aspects, specifically lattice strain and atomic order are discussed in detail. It is interesting to note that this transformation takes place despite an increase in atomic volume, which is due to the high ordering energy of $$gamma$$. Upon heating under high pressure, both the eutectoid and $$gamma$$-solvus transition temperatures are elevated, and a third, cubic $$beta$$-phase is stabilized above 1350 K. Earlier research has shown that this $$beta$$-phase is very ductile during plastic deformation, essential in near-conventional forging processes. Here, we were able to identify an ideal processing window for near-conventional forging, while the presence of the detrimental $$beta$$-phase is not present under operating conditions. Novel processing routes can be defined from these findings.

JAEA Reports

Performance tests of radiation detectors for inspection of $$^{99}$$Mo/$$^{99m}$$Tc solution, 1

Suzuki, Yumi*; Nakano, Hiroko; Suzuki, Yoshitaka; Ishida, Takuya; Shibata, Akira; Kato, Yoshiaki; Kawamata, Kazuo; Tsuchiya, Kunihiko

JAEA-Technology 2015-031, 58 Pages, 2015/11


Technetium-99m ($$^{99m}$$Tc) is one of the most commonly used radioisotopes in the field of nuclear medicine. In the Japan Atomic Energy Agency (JAEA), the research and development (R&D) have been carried out for production of molybdenum-99 ($$^{99}$$Mo) by (n, $$gamma$$) method, a parent nuclide of $$^{99m}$$Tc, with the Japan Material Testing Reactor (JMTR). On the other hand, the new project as "Domestic Production of Medical Radioisotope (Technetium preparation) in Japan" was adopted in the Tsukuba International Strategic Zone on October, 2013 and the demonstration tests will be planned for the domestic production of $$^{99}$$Mo/$$^{99m}$$Tc with the JMTR. Thus, new facilities and analysis devices were equipped in the JMTR hot laboratory in 2014 as the part of this project. As the part of the analytical device equipment, the $$gamma$$-TLC analyzer and the radiation detector connected with the High Performance Liquid Chromatography (HPLC) were installed for quality inspection of the $$^{99}$$Mo/$$^{99m}$$Tc solution and the extracted $$^{99m}$$Tc solution in the JMTR hot laboratory. The performance tests of these devices such as detection sensitivity, resolution, linearity and selectivity of energy range were carried out with $$^{137}$$Cs and $$^{152}$$Eu as alternative radionuclides of $$^{99}$$Mo and $$^{99m}$$Tc, respectively. In the results, bright prospects were obtained concerning the quality inspection of the $$^{99}$$Mo/$$^{99m}$$Tc and $$^{99m}$$Tc solutions using these devices. This report describes the results of those performance tests.

Journal Articles

Superdeformation in $$^{35}$$S

Go, Shintaro*; Ideguchi, Eiji*; Yokoyama, Rin*; Kobayashi, Motoki*; Kisamori, Keiichi*; Takaki, Motonobu*; Miya, Hioyuki*; Ota, Shinsuke*; Michimasa, Shinichiro*; Shimoura, Susumu*; et al.

JPS Conference Proceedings (Internet), 6, p.030005_1 - 030005_4, 2015/06

Journal Articles

Studies on the extraction of soft acid metal species using MIDOA and analogous compounds

Sasaki, Yuji; Saeki, Morihisa; Sugo, Yumi; Ikeda, Yasuhisa*; Kawasaki, Takeshi*; Suzuki, Tomoya*; Ohashi, Akira*

Solvent Extraction Research and Development, Japan, 22(1), p.37 - 45, 2015/05

 Times Cited Count:8 Percentile:59.44(Chemistry, Multidisciplinary)

An extractant, methylimino-bis-${it N,N'}$-dioctylacetamide (MIDOA), was used for the extraction of soft acid metals. It was found that MIDOA can extract not only Cr(VI), Mo(VI), W(VI), Tc(VII) and Re(VII), whose metals can form the oxonium anions due to their high oxidation states, but also other metal cations, like Nb(V), Ta(V) and Pd(II). Analogous compounds, imino-bis-${it N,N'}$-dioctylacetamide (IDOA) and methylimino-bis-${it N,N'}$-di-2-ethylhexylacetamide (MIDEHA), are synthesized and compared for their extractability. It is clear that these extractants have almost same or lower $$D$$ values than those for MIDOA. In order to examine the effect on extractability with different donor atoms, TODGA (${it N,N,N',N'}$-tetraoctyl-diglycolamide) and TDGA (${it N,N,N',N'}$-tetraoctyl-tyiodiglycolamide) having oxygen and sulfur donor are employed. The comparison of their extractabilities suggests that the trend of Pd and Re extraction is N $$>$$ S $$>$$ O and N $$>$$ O $$>$$ S, respectively.

Journal Articles

Exploring of peptides with affinity to HER2 from random peptide libraries using radioisotope; Random hexapeptide libraries with fixed amino acid sequence at 1 and 2 positions

Sasaki, Ichiro; Hanaoka, Hirofumi*; Yamada, Keiichi*; Watanabe, Shigeki; Sugo, Yumi; Ohshima, Yasuhiro; Suzuki, Hiroyuki; Ishioka, Noriko

Peptide Science 2014, p.257 - 260, 2015/03

Journal Articles

Effect of the central frames and substituents attached to N atoms on extraction ability of podand-type extractants

Sasaki, Yuji; Kitatsuji, Yoshihiro; Sugo, Yumi; Tsubata, Yasuhiro; Suzuki, Tomoya; Kimura, Takaumi; Morita, Yasuji

Proceedings of 20th International Solvent Extraction Conference (ISEC 2014), p.431 - 435, 2014/09

The eight amide extractants including podand-types, which introduce oxygen, nitrogen and sulfur donor atoms in their central frame, are synthesized and their D values for actinide extraction are compared. The central frame affect greatly on their extractability and it is clear that diglycolamide (DGA) has the highest extractability among extractants used here. In addition, DGA having the different length of alkyl chain or phenyl groups attached to amidic N atoms are obtained and the effect of these substituents is studied. Due to the steric hindrance or hydrogen bond, DGA with long and branched alkyl chains, phenyl group, and proton give relatively low D values.

Journal Articles

Evaluation of welding residual stresses using diffraction spot trace method

Suzuki, Kenji*; Shobu, Takahisa; Shiro, Ayumi; Zhang, S.*

Advanced Materials Research, 996, p.76 - 81, 2014/08

 Times Cited Count:0 Percentile:100

Journal Articles

Stress evaluation in material with coarse grains using area detector

Suzuki, Kenji*; Shobu, Takahisa; Shiro, Ayumi; Zhang, S.*

Zairyo, 63(7), p.527 - 532, 2014/07

The spiral slit-system and DSTM (diffraction spot trace method) are under development in order to evaluate internal stresses of materials with coarse grains. The bending stress in the specimen with coarse grains was measured in order to confirm performance of this advanced spiral slit-system. It was proved that the combination of the advanced spiral slit-system and the DSTM is useful for the internal stress measurement of materials with coarse grains. The welded specimen of a Mg-alloy plate was prepared by melt-run with TIG welding. The residual stress map in the cross-section of the specimen was made using the DSTM. On the other hand, the residual stresses of the welded specimen were simulated by a finite element method. The measured residual stresses were similar to the simulated results, and the residual stresses due to extrusion were measured also using the DSTM. Therefore, the DSTM is suitable for the stress measurement of weld parts.

JAEA Reports

"Development of mutual separation technology of minor actinides by the novel hydrophilic and lipophilic diamide compounds" summary of the researches for three years (Contract research)

Sasaki, Yuji; Tsubata, Yasuhiro; Kitatsuji, Yoshihiro; Sugo, Yumi; Shirasu, Noriko; Ikeda, Yasuhisa*; Kawasaki, Takeshi*; Suzuki, Tomoya*; Mimura, Hitoshi*; Usuda, Shigekazu*; et al.

JAEA-Research 2014-008, 220 Pages, 2014/06


The researches on Development of mutual separation technology of minor actinides by the novel hydrophilic and lipophilic diamide compounds, entrusted to Japan Atomic Energy Agency by the Ministry of Education, Culture, Sports, Science and Technology of Japan, from 2010 to 2012 are summarized. This project was composed of three themes, those are (1) Development of total recovery of MA+Ln: basic researches for new extractant, DOODA, (2) Development of mutual separation of Am/Cm/Ln: basic researches of Ln-complex, solvent extraction, and extraction chromatography, and (3) Evaluation of separation technique: process simulation. For topic (1), we summarized the information on characteristic of DOODA extractant. For topic (2), we summarized the information on structures of Ln-complexes, solvent extraction and chromatography. For topic (3), we summarized the information on conditions of mixer-settler and evaluation of each fraction separated.

Journal Articles

Internal stress measurement of weld part using diffraction spot trace method

Suzuki, Kenji*; Shobu, Takahisa; Shiro, Ayumi; Zhang, S.*

Materials Science Forum, 777, p.155 - 160, 2014/02

 Times Cited Count:2 Percentile:18.1

Journal Articles

Residual stresses of water-jet peened austenitic stainless steel

Suzuki, Kenji*; Shobu, Takahisa; Shiro, Ayumi

Zairyo, 62(7), p.437 - 442, 2013/07

The specimen material was austenitic stainless steel, SUS316L. The residual stress was induced by water-jet peening. The residual stress was measured using the 311 diffraction with conventional X-rays. The measured residual stress showed the equi-biaxial stress state. To investigate thermal stability of the residual stress, the specimen was aged thermally at 773 K in air to 1000 h. The residual stress kept the equi-biaxial stress state against the thermal aging. Lattice plane dependency of the residual stress induced by water-jet peening was evaluated using hard synchrotron X-rays. The residual stress measured by the soft lattice plane showed the equi-biaxial stress state, but the residual stress measured by the hard lattice plane did not. In addition, the distributions of the residual stress in the depth direction were measured using a strain scanning method with hard synchrotron X-rays and neutrons.

JAEA Reports

Study on development of evaluation technique of in-situ tracer test in Horonobe Underground Research Laboratory Project (Contract research)

Yokota, Hideharu; Amano, Kenji; Maekawa, Keisuke; Kunimaru, Takanori; Naemura, Yumi*; Ijiri, Yuji*; Motoshima, Takayuki*; Suzuki, Shunichi*; Teshima, Kazufumi*

JAEA-Research 2013-002, 281 Pages, 2013/06


To evaluate permeable heterogeneity in a fracture and scale effects which are problems to be solved based on the ${it in-situ}$ mass transportation data of fractures in hostrock, a number of tracer tests are simulated in a fictitious single plate fracture generated on computer in this study. And the transport parameters, e.g. longitudinal dispersion length, true velocity and dilution rate, are identified by fitting one- and two-dimensional models to the breakthrough curves obtained from the simulations in order to investigate the applicability of these models to the evaluation of ${it in-situ}$ tracer test. As a result, one-dimensional model yields larger longitudinal dispersion length than two-dimensional model in the both cases of homogeneous and heterogeneous hydraulic conductivity fields of the fictitious fracture. And, the longitudinal dispersion length identified from a tracer test is smaller and/or larger than the macroscopic longitudinal dispersion length identified from whole fracture. It is clarified that these are occurred by shorter or longer distance between boreholes compare to the correlation length of geostatistical heterogeneity of fictitious fracture.

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