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Journal Articles

Diffusion of tritiated water, $$^{137}$$Cs$$^{+}$$, and $$^{125}$$I$$^{-}$$ in compacted Ca-montmorillonite; Experimental and modeling approaches

Fukatsu, Yuta; Yotsuji, Kenji*; Okubo, Takahiro*; Tachi, Yukio

Applied Clay Science, 211, p.106176_1 - 106176_10, 2021/09

 Times Cited Count:1 Percentile:76.68(Chemistry, Physical)

Journal Articles

Evolution of the reaction and alteration of mudstone with ordinary Portland cement leachates; Sequential flow experiments and reactive-transport modelling

Bateman, K.; Murayama, Shota*; Hanamachi, Yuji*; Wilson, J.*; Seta, Takamasa*; Amano, Yuki; Kubota, Mitsuru*; Ouchi, Yuji*; Tachi, Yukio

Minerals (Internet), 11(9), p.1026_1 - 1026_23, 2021/09

 Times Cited Count:0

Journal Articles

The Impact of cement on argillaceous rocks in radioactive waste disposal systems; A Review focusing on key processes and remaining issues

Wilson, J.*; Bateman, K.; Tachi, Yukio

Applied Geochemistry, 130, p.104979_1 - 104979_19, 2021/07

 Times Cited Count:1 Percentile:0.56(Geochemistry & Geophysics)

The concept of deep geological disposal will include the multiple use of cement-based materials. In the case of argillaceous host rocks, the presence of hyperalkaline cement porefluid results in the destabilization of primary minerals in the argillite, resulting in the development of a zone of alteration at cement-rock interfaces. The process understanding gained from experimental, analogue, and modelling studies has been reviewed, and remaining areas of uncertainty identified. Although there is a reasonably good understanding of the mineral assemblages that are likely to occur due to cement-rock interactions, there are still some areas where a degree of uncertainty remains, in particular: the evolution of cement-argillite interfaces at T $$>$$ 25$$^{circ}$$C; the rates at which secondary minerals form; the extent of pore clogging due to secondary mineral precipitation; the implications of alteration for radionuclide transport.

Journal Articles

Evaluation report of Task 9B based on comparisons and analyses of modelling results for the $"A$sp$"o$ HRL LTDE-SD experiments

Soler, J. M.*; Meng, S.*; Moreno, L.*; Neretnieks, I.*; Liu, L.*; Kek$"a$l$"a$inen, P.*; Hokr, M.*; $v{R}$$'i$ha, J.*; Vete$v{s}$n$'i$k, A.*; Reimitz, D.*; et al.

SKB TR-20-17, 71 Pages, 2021/07

Task 9B of the SKB Task Force on Modelling of Groundwater Flow and Transport of Solutes in fractured rock focused on the modelling of experimental results from the LTDE-SD in situ tracer test performed at the $"A$sp$"o$ Hard Rock Laboratory in Sweden. Ten different modelling teams provided results for this exercise, using different concepts and codes. Three main types of modelling approaches were used: (1) analytical solutions to the transport-retention equations, (2) continuum-porous-medium numerical models, and (3) microstructure-based models accounting for small-scale heterogeneity (i.e. mineral grains and microfracture distributions). The modelling by the different teams allowed the comparison of many different model concepts, especially in terms of potential zonations of rock properties (porosity, diffusion, sorption), such as the presence of a disturbed zone at the rock and fracture surface, the potential effects of micro- and cm-scale fractures.

Journal Articles

Reaction and alteration of mudstone with Ordinary Portland Cement and Low Alkali Cement pore fluids

Bateman, K.; Amano, Yuki; Kubota, Mitsuru*; Ouchi, Yuji*; Tachi, Yukio

Minerals (Internet), 11(6), p.588_1 - 588_19, 2021/06

 Times Cited Count:1 Percentile:0.03(Geochemistry & Geophysics)

Journal Articles

Effect of interlayer cations on montmorillonite swelling; Comparison between molecular dynamic simulations and experiments

Yotsuji, Kenji*; Tachi, Yukio; Sakuma, Hiroshi*; Kawamura, Katsuyuki*

Applied Clay Science, 204, p.106034_1 - 106034_13, 2021/04

 Times Cited Count:4 Percentile:97.52(Chemistry, Physical)

Journal Articles

Development of evaluation method for diffusion and filtration behavior of colloid in compacted bentonites using dendrimers

Endo, Takashi*; Tachi, Yukio; Ishidera, Takamitsu; Terashima, Motoki

Nihon Genshiryoku Gakkai Wabun Rombunshi, 20(1), p.9 - 22, 2021/03

Evaluation method of colloid diffusion and filtration in compacted bentonites was developed using dendrimers. Diffusion and filtration behavior of PAMAM dendrimers with the size of 5.7$$sim$$7.2nm was investigated by the through-diffusion experiment in bentonite compacted to 0.8 Mg/m$$^{3}$$ and saturated with 0.005$$sim$$0.5mol/L NaCl. Effective diffusivities (De) and filtration ratios (Rf) of dendrimers were determined from the breakthrough curves and the depth profiles in compacted bentonite, respectively. The De values of negatively charged dendrimer increased when porewater salinity increased and dendrimer size decreased as influenced by anion exclusion effect in negatively charged clay surfaces. The Rf values increased when porewater salinity decreased and dendrimer size increased, demonstrating significant fractions of dendrimer were filtered by narrow pores in complex pore networks. These trends consistent with the previous studies emphasize the validity of the evaluation method using dendrimer.

Journal Articles

Surface complexation of Ca and competitive sorption of divalent cations on montmorillonite under alkaline conditions

Sugiura, Yuki; Ishidera, Takamitsu; Tachi, Yukio

Applied Clay Science, 200, p.105910_1 - 105910_10, 2021/01

 Times Cited Count:2 Percentile:0.03(Chemistry, Physical)

Journal Articles

Pore distribution of compacted Ca-montmorillonite using NMR relaxometry and cryoporometry; Comparison with Na-montmorillonite

Okubo, Takahiro*; Yamazaki, Akio*; Fukatsu, Yuta; Tachi, Yukio

Microporous and Mesoporous Materials, 313, p.110841_1 - 110841_11, 2021/01

 Times Cited Count:1 Percentile:69.4(Chemistry, Applied)

Pore distributions in water-saturated Ca-montmorillonite were investigated using $$^{1}$$H NMR measurements under various dry densities (0.8 - 1.6 g/cm$$^{3}$$) and porewater salinity conditions (deionized water, 0.1 and 1 M CaCl$$_{2}$$), at the temperature range of 233 - 303 K. The volume fractions of the interlayer pore including two and three hydrated layers and the non-interlayer pore in compacted Ca-montmorillonite were quantified by NMR relaxometry including $$T1$$ and $$T1/T2$$ distribution analysis, and were compared with NMR cryoporometry and X-ray diffractometry. These analysis provided consistent pictures on the pore distributions in compacted Ca-montmorillonite, in contrast to Na-montmorillonite. The main factor affecting the pore distribution in compacted Ca- and Na-montmorillonite is the density, whereas the effect of porewater salinity is relatively smaller. The effect of interlayer cations is also relatively smaller at higher density, although the differences in the pore structures are significant at low density.

Journal Articles

Impacts of Si on Se(IV) immobilization on ferrihydrite; An in situ ATR-IR spectroscopic study

Francisco, P. C. M.; Tachi, Yukio

ACS Earth and Space Chemistry (Internet), 4(12), p.2366 - 2377, 2020/12

 Times Cited Count:0 Percentile:0.01(Chemistry, Multidisciplinary)

Journal Articles

Using natural systems evidence to test models of transformation of montmorillonite

Savage, D.*; Wilson, J.*; Benbow, S.*; Sasamoto, Hiroshi; Oda, Chie; Walker, C.*; Kawama, Daisuke*; Tachi, Yukio

Applied Clay Science, 195, p.105741_1 - 105741_11, 2020/09

 Times Cited Count:1 Percentile:0.02(Chemistry, Physical)

Safety functions for the clay buffer in a repository for high-level radioactive waste (HLW) are fulfilled if the presence of montmorillonite with high swelling capacity and low permeability is maintained in the long-term. The transformation of montmorillonite to the non-swelling mineral likely illite is addressed in most safety assessments by using simple semi-empirical kinetic models, but this approach contrasts with more complex reactive-transport simulations. In the present study, reactive-transport simulations are compared with simple semi-empirical kinetic models. Results suggest that reactive-transport simulations err on the side of conservatism, but may produce unrealistic estimates of illitization. This comparison demonstrates that reactive-transport models may be carefully applied to simulate the long-term evolution of near field environment for HLW disposal.

Journal Articles

Key factors controlling radiocesium sorption and fixation in river sediments around the Fukushima Daiichi Nuclear Power Plant, 1; Insights from sediment properties and radiocesium distributions

Tachi, Yukio; Sato, Tomofumi*; Akagi, Yosuke*; Kawamura, Makoto*; Nakane, Hideji*; Terashima, Motoki; Fujiwara, Kenso; Iijima, Kazuki

Science of the Total Environment, 724, p.138098_1 - 138098_11, 2020/07

 Times Cited Count:5 Percentile:70.14(Environmental Sciences)

To understand and predict radiocesium transport behaviors in the environment, highly contaminated sediments from Ukedo and Odaka rivers around the Fukushima Daiichi Nuclear Power Plant were investigated systematically focusing on key factors controlling radiocesium sorption and fixation, including particle size, clay mineralogy and organic matter.

Journal Articles

Key factors controlling radiocesium sorption and fixation in river sediments around the Fukushima Daiichi Nuclear Power Plant, 2; Sorption and fixation behaviors and their relationship to sediment properties

Tachi, Yukio; Sato, Tomofumi*; Takeda, Chizuko*; Ishidera, Takamitsu; Fujiwara, Kenso; Iijima, Kazuki

Science of the Total Environment, 724, p.138097_1 - 138097_10, 2020/07

 Times Cited Count:2 Percentile:39.03(Environmental Sciences)

To understand and predict radiocesium transport behaviors in the environment, sorption and fixation behaviors of radiocesium on river sediments from Ukedo and Odaka rivers around the Fukushima Daiichi Nuclear Power Plant were investigated systematically focusing on Cs sorption and fixation mechanisms and their relationship with Cs concentrations and sediment properties including clay mineralogy and organic matter.

Journal Articles

Sorption behavior of selenide on montmorillonite

Sugiura, Yuki; Tomura, Tsutomu*; Ishidera, Takamitsu; Doi, Reisuke; Francisco, P. C. M.; Shiwaku, Hideaki; Kobayashi, Toru; Matsumura, Daiju; Takahashi, Yoshio*; Tachi, Yukio

Journal of Radioanalytical and Nuclear Chemistry, 324(2), p.615 - 622, 2020/05

 Times Cited Count:1 Percentile:0.01(Chemistry, Analytical)

JAEA Reports

Development of JAEA sorption database (JAEA-SDB); Update of sorption/QA data in FY2019

Sugiura, Yuki; Suyama, Tadahiro*; Tachi, Yukio

JAEA-Data/Code 2019-022, 40 Pages, 2020/03

JAEA-Data-Code-2019-022.pdf:2.22MB

Sorption behavior of radionuclides (RNs) in buffer materials, rocks and cementitious materials is one of the key processes in a safe geological disposal. This report focuses on updating of JAEA sorption database (JAEA-SDB) as a basis of integrated approach for the performance assessment (PA)-related distribution coefficient (K$$_{rm d}$$) setting and development of mechanistic sorption models. K$$_{rm d}$$ data and their quality assurance (QA) results were updated by focusing on the following systems as potential needs extracted from our recent activities on the K$$_{rm d}$$ setting and development of mechanistic models, i.e., clay minerals, sedimentary rocks and cementitious materials. As a result, 6,702 K$$_{rm d}$$ data from 60 references were added and the total number of K$$_{rm d}$$ values in JAEA-SDB reached 69,679. The QA/classified K$$_{rm d}$$ data reached about 72% for all K$$_{rm d}$$ data in JAEA-SDB.

JAEA Reports

Data acquisition for radionuclide sorption on barrier materials for performance assessment of geological disposal of TRU wastes

Tachi, Yukio; Suyama, Tadahiro*; Mihara, Morihiro

JAEA-Data/Code 2019-021, 101 Pages, 2020/03

JAEA-Data-Code-2019-021.pdf:4.05MB

Sorption of radionuclides in cement and bentonite as engineered barrier materials, and rocks as natural barrier is the one of key processes in the performance assessment of geological disposal of TRU and high-level waste. The magnitude of sorption, expressed normally by a distribution coefficient (K$$_{rm d}$$), needs to be measured and determined taking into account the properties of barrier materials and geochemical conditions and associated uncertainty in the performance assessment. The basic concept for TRU waste disposal contains cementitious materials as an engineered barrier materials, in addition to bentonite and rock. It is therefore needed to consider the effects of the cement degradation and co-existing substances such as nitrates on radionuclide sorption. This report focused on data acquisition of distribution coefficient (K$$_{rm d}$$) by batch sorption experiments for the systems coupling barrier material-chemical condition-radionuclides that are needed to consider for the performance assessment of geological disposal of TRU waste. The barrier materials considered are ordinary Portland cement (OPC), degraded OPC and tuff rock. The chemical conditions are distilled water and synthetic seawater equilibrated with OPC and those containing nitrates and ammonium salts, etc. The radionuclides considered are organic carbon, inorganic carbon, Cl, I, Cs, Ni, Se, Sr, Sn, Nb, Am and Th. Although K$$_{rm d}$$ values have been partly reported previously as RAMDA (Radionuclide Migration Datasets) for the performance assessment in the TRU-2 report, these results and addition K$$_{rm d}$$ data are reported with the details of experimental methods and conditions.

Journal Articles

Interaction of Fe$$^{II}$$ and Si under anoxic and reducing conditions; Structural characteristics of ferrous silicate co-precipitates

Francisco, P. C. M.; Mitsui, Seiichiro; Ishidera, Takamitsu; Tachi, Yukio; Doi, Reisuke; Shiwaku, Hideaki

Geochimica et Cosmochimica Acta, 270, p.1 - 20, 2020/02

 Times Cited Count:4 Percentile:74.86(Geochemistry & Geophysics)

Journal Articles

Natural systems evidence for the effects of temperature and the activity of aqueous silica upon montmorillonite stability in clay barriers for the disposal of radioactive wastes

Savage, D.*; Wilson, J.*; Benbow, S.*; Sasamoto, Hiroshi; Oda, Chie; Walker, C.*; Kawama, Daisuke*; Tachi, Yukio

Applied Clay Science, 179, p.105146_1 - 105146_10, 2019/10

 Times Cited Count:5 Percentile:57.36(Chemistry, Physical)

Natural systems evidence for the effects of temperature and the activity of aqueous silica upon montmorillonite stability was evaluated. Thermodynamic modeling using three different TDBs shows that stability fields for montmorillonite exist from 0 to 140$$^{circ}$$C, but at low values of silica activity, a stability field for illite replaces that for montmorillonite. Pore fluid chemical and mineralogical data for sediments from ODP sites from offshore Japan show a trend from montmorillonite + amorphous silica stability at temperatures up to 60$$^{circ}$$C to that for illite + quartz at higher temperatures. However, even over very long timescales ($$gg$$ 1 Ma), smectite does not transform to illite under thermodynamically-favourable conditions at temperatures less than 80$$^{circ}$$C.

Journal Articles

A Systematic radionuclide migration parameter setting approach for potential siting environments in Japan

Hamamoto, Takafumi*; Ishida, Keisuke*; Shibutani, Sanae*; Fujisaki, Kiyoshi*; Tachi, Yukio; Ishiguro, Katsuhiko*; McKinley, I. G.*

Proceedings of 2019 International High-Level Radioactive Waste Management Conference (IHLRWM 2019) (USB Flash Drive), p.77 - 82, 2019/04

Journal Articles

3D-microstructure analysis of compacted Na- and Cs-montmorillonites with nanofocus X-ray computed tomography and correlation with macroscopic transport properties

Takahashi, Hiroaki*; Tachi, Yukio

Applied Clay Science, 168, p.211 - 222, 2019/02

 Times Cited Count:8 Percentile:70.54(Chemistry, Physical)

Microstructural and mass transport properties of compacted Na- and Cs-montmorillonites with different swelling properties were investigated by combining 3D microstructure analysis using nanofocus X-ray CT and diffusion measurement of HDO. The X-ray CT observations indicated that macropores in the dry state of compacted Na-montmorillonite are filled with gel phases, and the grain sizes of clay particles shifted toward smaller values through the saturation and swelling processes. By contrast, no gel phase and no decrease in the grain and pore volumes were observed for saturated Cs-montmorillonite. The geometrical factors of the macropores including tortuosity and geometric constrictivity of saturated Cs-montmorillonite determined by the X-ray CT was consistent with the corresponding values derived in the HDO diffusion test. In the case of Na-montmorillonite, the larger differences between the geometric factors evaluated by the X-ray CT and the diffusion tests can be explained by the electrostatic constrictivity factor and the additional geometrical factors in gel phase and interlayer that are smaller than the detection limit of the X-ray CT.

216 (Records 1-20 displayed on this page)