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Journal Articles

Interfacial distribution of Nafion ionomer thin films on nitrogen-modified carbon surfaces

Yoshimune, Wataru*; Kikkawa, Nobuaki*; Yoneyama, Hiroaki*; Takahashi, Naoko*; Minami, Saori*; Akimoto, Yusuke*; Mitsuoka, Takuya*; Kawaura, Hiroyuki*; Harada, Masashi*; Yamada, Norifumi*; et al.

ACS Applied Materials & Interfaces, 14(48), p.53744 - 53754, 2022/11

 Times Cited Count:7 Percentile:63.54(Nanoscience & Nanotechnology)

Journal Articles

Thermally altered subsurface material of asteroid (162173) Ryugu

Kitazato, Kohei*; Milliken, R. E.*; Iwata, Takahiro*; Abe, Masanao*; Otake, Makiko*; Matsuura, Shuji*; Takagi, Yasuhiko*; Nakamura, Tomoki*; Hiroi, Takahiro*; Matsuoka, Moe*; et al.

Nature Astronomy (Internet), 5(3), p.246 - 250, 2021/03

 Times Cited Count:44 Percentile:97.1(Astronomy & Astrophysics)

Here we report observations of Ryugu's subsurface material by the Near-Infrared Spectrometer (NIRS3) on the Hayabusa2 spacecraft. Reflectance spectra of excavated material exhibit a hydroxyl (OH) absorption feature that is slightly stronger and peak-shifted compared with that observed for the surface, indicating that space weathering and/or radiative heating have caused subtle spectral changes in the uppermost surface. However, the strength and shape of the OH feature still suggests that the subsurface material experienced heating above 300 $$^{circ}$$C, similar to the surface. In contrast, thermophysical modeling indicates that radiative heating does not increase the temperature above 200 $$^{circ}$$C at the estimated excavation depth of 1 m, even if the semimajor axis is reduced to 0.344 au. This supports the hypothesis that primary thermal alteration occurred due to radiogenic and/or impact heating on Ryugu's parent body.

Journal Articles

Quantum paramagnet near spin-state transition

Tomiyasu, Keisuke*; Ito, Naoko*; Okazaki, Ryuji*; Takahashi, Yuki*; Onodera, Mitsugi*; Iwasa, Kazuaki*; Nojima, Tsutomu*; Aoyama, Takuya*; Ogushi, Kenya*; Ishikawa, Yoshihisa*; et al.

Advanced Quantum Technologies (Internet), 1(3), p.1800057_1 - 1800057_7, 2018/12

Spin-state transition, also known as spin crossover, plays a key role in diverse systems. In theory, the boundary range between the low- and high-spin states is expected to enrich the transition and give rise to unusual physical states. However, no compound that realizes a nearly degenerate critical range as the ground state without requiring special external conditions has yet been experimentally identified. This study reports that the Sc substitution in LaCoO3 destabilizes its nonmagnetic low-spin state and generates an anomalous paramagnetic state accompanied by the enhancement of transport gap and magneto-lattice-expansion as well as the contraction of Co-O distance with the increase of electron site transfer. These phenomena are not well described by the mixture of conventional low- and high-spin states, but by their quantum superposition occurring on the verge of a spin-state transition.

Journal Articles

Mineralogical control of the size distribution of stable Cs and radiocesium in riverbed sediments

Tanaka, Kazuya; Watanabe, Naoko*; Yamasaki, Shinya*; Sakaguchi, Aya*; Fan, Q.*; Takahashi, Yoshio*

Geochemical Journal, 52(2), p.173 - 185, 2018/00

 Times Cited Count:9 Percentile:42.79(Geochemistry & Geophysics)

We analyzed riverbed sediments collected at two sites, Yamakiya and Kuroiwa, in Fukushima after the Fukushima accident. The size distributions of K, Rb, and $$^{133}$$Csreflected the mineralogy of sediments, where primary host minerals for these alkali elements would be biotite, K-feldspar, and clay minerals. Silt-size fractions contained high $$^{133}$$Cs and $$^{137}$$Cs concentrations possibly due to adsorption on clay minerals. Their concentrations decreased with particle size at the Yamakiya site. In contrast, coarse and very coarse sand fractions from the Kuroiwa site showed higher $$^{133}$$Cs and $$^{137}$$Cs concentrations in comparison to fine - medium sand fractions. The coarse sand fractions contained many weathered biotite grains. Overall, the size distributions of $$^{133}$$Cs and $$^{137}$$Cs were similar in the sediments, suggesting that the Fukushima-derived radiocesium was distributed into each particle size fraction in response to the distribution of the stable Cs that was controlled by mineralogical composition.

Journal Articles

Ligand exchange adsorption and coordination structure of Pd on $$delta$$-MnO$$_{2}$$ in NaCl solution

Tanaka, Kazuya; Tanaka, Masato*; Watanabe, Naoko*; Tokunaga, Kohei*; Takahashi, Yoshio*

Chemical Geology, 460, p.130 - 137, 2017/06

 Times Cited Count:8 Percentile:33.83(Geochemistry & Geophysics)

Pd is highly accumulated in ferromanganese nodules and crusts relative to its concentration in seawater but the mechanism by which Pd(II) is incorporated remains poorly understood. We investigated the local coordination structure of Pd(II) adsorbed on $$delta$$-MnO$$_{2}$$, using X-ray absorption fine structure spectroscopy. X-ray absorption near edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) analyses indicated that Pd was adsorbed on $$delta$$-MnO$$_{2}$$ through ligand exchange, from Cl coordination to O coordination. Furthermore, curve fitting of EXAFS spectra demonstrated the formation of two different inner-sphere complexes, bidentate-mononuclear and bidentate-binuclear complexes, and this finding was supported by density functional theory calculations. The formation of inner-sphere complexes is reasonable given the relatively large distribution coefficients obtained from adsorption experiments.

Journal Articles

Simultaneous recovery and separation of rare earth elements in ferromanganese nodules by using ${{it Shewanella putrefaciens}}$

Fujimoto, Jun*; Tanaka, Kazuya; Watanabe, Naoko*; Takahashi, Yoshio*

Hydrometallurgy, 166, p.80 - 86, 2016/12

 Times Cited Count:6 Percentile:31.22(Metallurgy & Metallurgical Engineering)

We examined recovery of REEs in Fe-Mn nodules by using ${{it Shewanella putrefaciens}}$ (Fe-reducing bacterium). In this method, Fe-Mn nodule decomposition and REE recovery were achieved simultaneously in a single solution system. Fe-Mn nodules were reductively decomposed in NaCl solution under anaerobic conditions with daily addition of sodium lactate as an electron donor. During the decomposition of Fe-Mn nodule, REEs released from the Fe-Mn nodule were adsorbed on bacterial cells. Of the conditions studied here, the best REE adsorption rates were obtained with 0.5M NaCl solution at pH7 with daily addition of 1 mmol sodium lactate.

Journal Articles

From laboratory to field; ${it OsNRAMP5}$-knockdown rice is a promising candidate for Cd phytoremediation in paddy fields

Takahashi, Ryuichi*; Ishimaru, Yasuhiro*; Shimo, H.*; Bashir, K.*; Senoura, Takeshi*; Sugimoto, Kazuhiko*; Ono, Kazuko*; Suzui, Nobuo; Kawachi, Naoki; Ishii, Satomi; et al.

PLOS ONE (Internet), 9(6), p.e98816_1 - e98816_7, 2014/06

 Times Cited Count:51 Percentile:86.5(Multidisciplinary Sciences)

Journal Articles

Deoxymugineic acid increases Zn translocation in Zn-deficient rice plants

Suzuki, Motofumi*; Tsukamoto, Takashi*; Inoue, Haruhiko*; Watanabe, Satoshi; Matsuhashi, Shimpei; Takahashi, Michiko*; Nakanishi, Hiromi*; Mori, Satoshi*; Nishizawa, Naoko*

Plant Molecular Biology, 66(6), p.609 - 617, 2008/04

 Times Cited Count:138 Percentile:95.23(Biochemistry & Molecular Biology)

Journal Articles

Mutational reconstructed ferric chelate reductase confers enhanced tolerance in rice to iron deficiency in calcareous soil

Ishimaru, Yasuhiro*; Kim, S.*; Tsukamoto, Takashi*; Oki, Hiroyuki*; Kobayashi, Takanori*; Watanabe, Satoshi; Matsuhashi, Shimpei; Takahashi, Michiko*; Nakanishi, Hiromi*; Mori, Satoshi*; et al.

Proceedings of the National Academy of Sciences of the United States of America, 104(18), p.7373 - 7378, 2007/05

 Times Cited Count:131 Percentile:93.39(Multidisciplinary Sciences)

Journal Articles

Biosynthesis and secretion of mugineic acid family phytosiderophores in zinc-deficient barley

Suzuki, Motofumi*; Takahashi, Michiko*; Tsukamoto, Takashi*; Watanabe, Satoshi; Matsuhashi, Shimpei; Yazaki, Junshi*; Kishimoto, Naoki*; Kikuchi, Shoshi*; Nakanishi, Hiromi*; Mori, Satoshi*; et al.

Plant Journal, 48(1), p.85 - 97, 2006/10

 Times Cited Count:172 Percentile:95.74(Plant Sciences)

Journal Articles

Rice plants take up iron as an Fe$$^{3+}$$-phytosiderophore and as Fe$$^{2+}$$

Ishimaru, Yasuhiro*; Suzuki, Motofumi*; Tsukamoto, Takashi*; Suzuki, Kazumasa*; Nakazono, Mikio*; Kobayashi, Takanori*; Wada, Yasuaki*; Watanabe, Satoshi; Matsuhashi, Shimpei; Takahashi, Michiko*; et al.

Plant Journal, 45(3), p.335 - 346, 2006/02

 Times Cited Count:549 Percentile:99.64(Plant Sciences)

Oral presentation

Characterization of ${it OsNRAMP5}$ knockdown rice plants using high cadmium accumulating cultivar

Takahashi, Ryuichi*; Bashir, K.*; Ishimaru, Yasuhiro*; Senoura, Takeshi*; Sugimoto, Kazuhiko*; Ono, Kazuko*; Yano, Masahiro*; Suzui, Nobuo; Fujimaki, Shu; Nishizawa, Naoko*; et al.

no journal, , 

no abstracts in English

Oral presentation

Transport and accumulation of particulate $$^{137}$$Cs on the continental shelf off Fukushima

Otosaka, Shigeyoshi*; Misono, Toshiharu; Dohi, Terumi; Tsuruta, Tadahiko; Takahashi, Yoshio*; Sugihara, Naoko*; Obata, Hajime*; Ikenoue, Takahito*; Jimi, Naoto*; Hookabe, Natsumi*

no journal, , 

no abstracts in English

Oral presentation

Status and future of radiocesium in the seafloor off Fukushima

Otosaka, Shigeyoshi*; Aono, Tatsuo*; Fukuda, Miho*; Kambayashi, Shota*; Misono, Toshiharu; Dohi, Terumi; Tsuruta, Tadahiko; Suzuki, Takashi; Takahashi, Yoshio*; Sugihara, Naoko*; et al.

no journal, , 

While the amount of cesium-137 ($$^{137}$$Cs: half-life 30.1 years) accumulated on the seabed due to the accident of the Fukushima Daiichi Nuclear Power Plant (0.1-0.2 PBq) is only about 1 to 2% of the total amount of $$^{137}$$Cs transported to the ocean, it has been reported that it will remain for a long time in the coastal areas. On the other hand, long-term migration process of the sedimentary radiocesium and the impact on the ecosystem near the seafloor remain unknown. In this presentation, we will give an overview of the distribution and behavior of $$^{137}$$Cs, especially on the seafloor along the coast of Fukushima, and report the latest results on the processes I the seafloor that should be considered on decadal timescale.

14 (Records 1-14 displayed on this page)
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