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Journal Articles

Activity report of the Task Group on Parameters Used in Biospheric Dose Assessment Models for Radioactive Waste Disposal

Takahashi, Tomoyuki*; Fukaya, Yukiko*; Iimoto, Takeshi*; Uni, Yasuo*; Kato, Tomoko; Sun, S.*; Takeda, Seiji; Nakai, Kunihiro*; Nakabayashi, Ryo*; Uchida, Shigeo*; et al.

Hoken Butsuri (Internet), 56(4), p.288 - 305, 2021/12

We report the results of activities related to the Task Group of Parameters Used in Biospheric Dose Assessment Models for Radioactive Waste Disposal at the Japan Health Physics Society.

Journal Articles

Solid-liquid extraction of Mo and W by Aliquat 336 from HCl solutions toward extraction chromatography experiments of Sg

Komori, Yukiko*; Yokokita, Takuya*; Kasamatsu, Yoshitaka*; Haba, Hiromitsu*; Toyoshima, Atsushi; Toyomura, Keigo*; Nakamura, Kohei*; Kanaya, Jumpei*; Huang, M.*; Kudo, Yuki*; et al.

Journal of Radioanalytical and Nuclear Chemistry, 303(2), p.1385 - 1388, 2015/02

 Times Cited Count:2 Percentile:17.57(Chemistry, Analytical)

We studied solid-liquid extraction behavior of carrier-free Mo and W radiotracers onto an Aliquat 336-loaded resin from HCl solutions toward extraction chromatography experiments of element 106, seaborgium(Sg). Distribution coefficients ($${it K}$$$$_{d}$$) of Mo and W on the resin were determined as a function of HCl concentration by a batch method. On-line extraction chromatography of Mo and W was also carried out in 2-8 M HCl solutions with an automated rapid chemistry apparatus. The order of extraction probability from 2 to 8 M HCl was Mo$$>$$W, which reflected the order of the $${it K}$$$$_{d}$$ values in the batch experiment.

Journal Articles

Application of capillary electrophoresis with laser-induced fluorescence detection for the determination of trace neodymium in spent nuclear fuel using complexation with an emissive macrocyclic polyaminocarboxylate probe

Haraga, Tomoko; Saito, Shingo*; Sato, Yoshiyuki; Asai, Shiho; Hanzawa, Yukiko; Hoshino, Hitoshi*; Shibukawa, Masami*; Ishimori, Kenichiro; Takahashi, Kuniaki

Analytical Sciences, 30(7), p.773 - 776, 2014/07

 Times Cited Count:6 Percentile:21.4(Chemistry, Analytical)

A simple and rapid method with low radiation exposure risk was developed for the determination of neodymium in spent nuclear fuel by CE with LIF detection using a fluorescent ligand having a macrocyclic hexadentate polyaminocarboxylate structure. The concentration of Nd(III) in a spent nuclear fuel sample was determined with no interference from various matrix elements, including lanthanides and uranium (at a 200-fold excess), with 92 $$pm$$ 3% recovery. This is due to method's high resolution based on establishing a ternary complex equilibrium during migration in which the hydroxyl ion plays an auxiliary role.

Journal Articles

Thermal engineering of non-local resistance in lateral spin valves

Kasai, Shinya*; Hirayama, Yusuke*; Takahashi, Yukiko*; Mitani, Seiji*; Hono, Kazuhiro*; Adachi, Hiroto; Ieda, Junichi; Maekawa, Sadamichi

Applied Physics Letters, 104(16), p.162410_1 - 162410_4, 2014/04

 Times Cited Count:14 Percentile:52.23(Physics, Applied)

Journal Articles

Time-domain observation of the spinmotive force in permalloy nanowires

Hayashi, Masamitsu*; Ieda, Junichi; Yamane, Yuta; Oe, Junichiro*; Takahashi, Yukiko*; Mitani, Seiji*; Maekawa, Sadamichi

Physical Review Letters, 108(14), p.147202_1 - 147202_5, 2012/04

 Times Cited Count:37 Percentile:82.18(Physics, Multidisciplinary)

Spinmotive force associated with a moving domain wall is observed directly in permalloy nanowires using real time voltage measurements with proper subtraction of the electromotive force. Whereas the wall velocity exhibits nonlinear dependence on a magnetic field, the generated voltage increases linearly with the field. We show that the sign of the voltage reverses when the wall propagation direction is altered. Numerical simulations explain quantitatively these features of spinmotive force and indicate that the spinmotive force scales with the field even in a field range where the wall motion is no longer associated with periodic structure transformation.

Journal Articles

Surface study of organopalladium molecules on S-terminated GaAs

Konishi, Tomoya*; Nishiwaki, Nagatoshi*; Tojo, Takashi*; Ishikawa, Takuma*; Teraoka, Teruki*; Ueta, Yukiko*; Kihara, Yoshifumi*; Moritoki, Hideji*; Tono, Tatsuo*; Musashi, Mio*; et al.

Physica Status Solidi (C), 8(2), p.405 - 407, 2011/02

 Times Cited Count:3 Percentile:74.8(Engineering, Electrical & Electronic)

JAEA Reports

Establishment of a clean chemistry laboratory at JAERI; Clean Laboratory for Environmental Analysis and Research (CLEAR)

Hanzawa, Yukiko; Magara, Masaaki; Watanabe, Kazuo; Esaka, Fumitaka; Miyamoto, Yutaka; Yasuda, Kenichiro; Gunji, Katsubumi*; Yamamoto, Yoichi; Takahashi, Tsukasa; Sakurai, Satoshi; et al.

JAERI-Tech 2002-103, 141 Pages, 2003/02

JAERI-Tech-2002-103.pdf:10.38MB

The JAERI has established a facility with a cleanroom: the Clean Laboratory for Environmental Analysis and Research (CLEAR). This report is an overview of the design, construction and performance evaluation of the CLEAR in the initial stage of the laboratory operation in June 2001. The CLEAR is a facility to be used for ultra trace analyses of nuclear materials in environmental samples for the safeguards, for the CTBT verification and for researches on environmental sciences. The CLEAR meets double requirements of a cleanroom and for handling of nuclear materials. Much attention was paid to the construction materials of the cleanroom for trace analysis of metal elements using corrosive acids. The air conditioning and purification system, experimental equipment, utilities and safety systems are also demonstrated. The potential contamination from the completed cleanroom atmosphere during the analytical procedure was evaluated. It can be concluded that the CLEAR has provided a suitable condition for reliable analysis of ultra trace amounts of nuclear materials in environmental samples.

Journal Articles

Effect of alkali metals on the accuracy of isotope ratio measurement of uranium by ICP-MS

Magara, Masaaki; Sakakibara, Takaaki; Kurosawa, Setsumi; Takahashi, Masato; Sakurai, Satoshi; Hanzawa, Yukiko; Esaka, Fumitaka; Watanabe, Kazuo; Usuda, Shigekazu

Journal of Analytical Atomic Spectrometry, 17(9), p.1157 - 1160, 2002/09

 Times Cited Count:11 Percentile:44.18(Chemistry, Analytical)

no abstracts in English

Journal Articles

Recent status of developments in analytical methods for safeguards environmental samples; Focused on particle analysis

Esaka, Fumitaka; Magara, Masaaki; Hanzawa, Yukiko; Sakurai, Satoshi; Taguchi, Takuji; Takai, Konomi; Sakakibara, Takaaki; Kurosawa, Setsumi; Takahashi, Masato; Yasuda, Kenichiro; et al.

Dai-22-Kai Kaku Busshitsu Kanri Gakkai Nihon Shibu Nenji Taikai Rombunshu, 8 Pages, 2001/11

no abstracts in English

Journal Articles

Development of trace analytical technology for nuclear materials in the clean laboratory for environmental analysis and research

Usuda, Shigekazu; Watanabe, Kazuo; Sakurai, Satoshi; Magara, Masaaki; Hanzawa, Yukiko; Esaka, Fumitaka; Miyamoto, Yutaka; Yasuda, Kenichiro; Saito, Yoko; Gunji, Katsubumi*; et al.

KEK Proceedings 2001-14, p.88 - 92, 2001/06

no abstracts in English

Journal Articles

Current status of JAERI program on development of ultra-trace-analytical technology for safeguards environmental samples

Adachi, Takeo; Usuda, Shigekazu; Watanabe, Kazuo; Sakurai, Satoshi; Magara, Masaaki; Hanzawa, Yukiko; Esaka, Fumitaka; Yasuda, Kenichiro; Saito, Yoko; Takahashi, Masato; et al.

IAEA-SM-367/10/02 (CD-ROM), 8 Pages, 2001/00

no abstracts in English

Journal Articles

Progress of environmental sampling program at Japan Atomic Energy Research Institute

Nishimura, Hideo; Magara, Masaaki; Hanzawa, Yukiko; Esaka, Fumitaka; Takahashi, Tsukasa; Gunji, Katsubumi; Miyamoto, Yutaka; Yasuda, Kenichiro; Tsuruta, Yasuhiro; Tsuda, Shinji; et al.

Heisei 11-Nendo Hosho Sochi Semina Koenroku Tekisuto, p.95 - 107, 2000/01

no abstracts in English

Journal Articles

Program to develop analytical techniques for ultra trace amounts of nuclear materials in environmental samples

Hanzawa, Yukiko; Magara, Masaaki; Esaka, Fumitaka; Watanabe, Kazuo; Usuda, Shigekazu; Gunji, Katsubumi; Yasuda, Kenichiro; Takahashi, Tsukasa; Nishimura, Hideo; Adachi, Takeo; et al.

Proceedings of the Institute of Nuclear Materials Management 40th Annual Meeting (CD-ROM), 7 Pages, 1999/00

no abstracts in English

Oral presentation

Solvent extraction of heavy actinides (III) with HDEHP

Takayama, Reona*; Oe, Kazuhiro*; Komori, Yukiko*; Fujisawa, Hiroyuki*; Kuriyama, Ai*; Kikutani, Yuki*; Kikunaga, Hidetoshi*; Kasamatsu, Yoshitaka*; Yoshimura, Takashi*; Takahashi, Naruto*; et al.

no journal, , 

The extraction behavior of trivalent actinides (Am, Cm, Cf, Es, and Fm) into di(2-ethylhexyl)phosphoric acid, HDEHP, in benzene from HNO$$_{3}$$ was studied together with lanthanides. The extraction constants, $$it K$$$$_{ex}$$ values, of lanthanides, Am, Cm, Cf, and Es were determined by a batch method using stable lanthanide isotopes and radiotracers of $$^{241}$$Am, $$^{243}$$Cm, $$^{249}$$Cf, and $$^{253}$$Es, respectively, while that of Fm was measured with $$^{250}$$Fm which was produced in the $$^{238}$$U($$^{16}$$O,4n) reaction and was on-line supplied by a gas-jet method at the AVF cyclotron of RCNP, Osaka University. The $$it K$$$$_{ex}$$ values were determined by the slope analysis for the variation of the distribution ratio as a function of the concentration of HDEHP. We found that the $$it K$$$$_{ex}$$of Fm is smaller than that of Dy in spite of the similar ionic radii while those of other actinides are almost the same as those of each lanthanide with a similar ionic radius.

Oral presentation

Extraction of molybdenum and tungsten in oxidation state +5 and +6 from hydrochloric acid with Aliquat 336

Yokokita, Takuya*; Komori, Yukiko*; Kikutani, Yuki*; Kino, Aiko*; Shiohara, Naoya*; Kasamatsu, Yoshitaka*; Yoshimura, Takashi*; Takahashi, Naruto*; Oe, Kazuhiro; Shinohara, Atsushi*

no journal, , 

We are planning to study a redox behavior of element 106, seaborgium (Sg) based on the comparison of the behaviors with those of molybdenum (Mo) and tungsten (W). In this work, we studied solvent extraction behaviors of Mo(VI), Mo(V), W(VI), and W(V) with Aliquat 336 from hydrochloric acid (HCl). Mo(V) is extracted with higher distribution ratios than those of Mo(VI) in 4 to 11 M HCl. Distribution ratios of Mo(V) obtained by reducing Mo(VI) electrochemically are in good agreement with those of [MoCl$$_5$$].

Oral presentation

Extraction behavior of Mo(VI), Mo(V), W(VI), and W(V) from HCl solutions by Aliquat 336

Yokokita, Takuya*; Oe, Kazuhiro; Komori, Yukiko*; Kikutani, Yuki*; Kino, Aiko*; Nakamura, Kohei*; Kasamatsu, Yoshitaka*; Takahashi, Naruto*; Yoshimura, Takashi*; Takamiya, Koichi*; et al.

no journal, , 

We carried out solvent extraction of Mo(VI), Mo(V), W(VI) and W(V) in 0.01-0.36 M Aliquat 336 / 0.1-11 M HCl system as model experiments for element 106, seaborgium (Sg). The HCl solutions of Mo(VI), Mo(V), W(VI) and W(V) were prepared using macro amounts of Mo and W. Extraction behaviors of mononuclear Mo and W were also investigated using carrier-free radiotracers $$^{99}$$Mo and $$^{181}$$W, which were produced as $$^{235}$$U(n, f) and $$^{181}$$Ta (p, n) reaction, respectively. The distribution ratios (D) of Mo(V) and W(V) were higher than those of Mo(VI) and W(VI), respectively. These results suggest that reduction behavior of the group-6 elements can be observed by solvent extraction. The D values of carrier-free Mo(VI) and W(VI) are almost the same as those with macro amounts in 6-11 M HCl. This condition would be suitable for the Sg experiments.

Oral presentation

Development of true coincidence summing correction for cascade $$gamma$$-ray emitters including $$^{134}$$Cs, 1; Collaborative experiment by the committee on preparation of reference materials for radioactivity analysis of JSAC

Yonezawa, Chushiro*; Kakita, Kazutoshi*; Takahashi, Takanori*; Aono, Tatsuo*; Maeda, Satoshi; Abe, Takaaki*; Arakawa, Fumihiro*; Kiho, Nobuharu*; Akiyama, Masakazu*; Muramatsu, Isamu*; et al.

no journal, , 

no abstracts in English

Oral presentation

Anisotropic spin orbit torque induced by symmetry reduction for Bismuth chalcogenide

Sugimoto, Satoshi*; Araki, Yasufumi; Takahashi, Yukiko*; Ieda, Junichi; Kasai, Shinya*

no journal, , 

no abstracts in English

18 (Records 1-18 displayed on this page)
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