Formation of monolayer VSe from multilayer VSe films via V- and Se-desorption

Sumida, Kazuki; Kusaka, Shotaro*; Takeda, Yukiharu; Kobayashi, Katsuyoshi*; Hirahara, Toru*

Physical Review B, 106(19), p.195421_1 - 195421_7, 2022/11

https://doi.org/10.1103/PhysRevB.106.195421

Short-range magnetic interaction in a monolayer 1-VSe film revealed by element-specific X-ray magnetic circular dichroism

Sumida, Kazuki; Takeda, Yukiharu; Kusaka, Shotaro*; Kobayashi, Katsuyoshi*; Hirahara, Toru*

Physical Review Materials (Internet), 6(1), p.014006_1 - 014006_8, 2022/01

https://doi.org/10.1103/PhysRevMaterials.6.014006

We investigated the intrinsic magnetic properties of the two-dimensional ferromagnetic candidate monolayer 1-VSe films using X-ray magnetic circular dichroism (XMCD), an element-specific magnetic probe. By performing high-resolution measurements, we succeeded in detecting a clear XMCD signal from the atomically thin 1-VSe films under an external magnetic field. Through manipulation of the X-ray incidence angle, we were able to disentangle the in-plane and out-of-plane magnetic properties and found a strong magnetic anisotropy. Moreover, magnetic field- and temperature-dependent XMCD revealed that there is no long-range ferromagnetic ordering even at 6 K, but short-range ferromagnetic and antiferromagnetic interactions between neighboring vanadium ions exist. Such low-temperature magnetic behavior signifies that the monolayer 1-VSe is on the verge of ferromagnetism, and this fact accounts for the reported ferromagnetism in VSe-based heterostructures.

Fabrication of a novel magnetic topological heterostructure and temperature evolution of its massive Dirac cone

Hirahara, Toru*; Otrokov, M. M.*; Sasaki, Taisuke*; Sumida, Kazuki*; Tomohiro, Yuta*; Kusaka, Shotaro*; Okuyama, Yuma*; Ichinokura, Satoru*; Kobayashi, Masaki*; Takeda, Yukiharu; et al.

Nature Communications (Internet), 11, p.4821_1 - 4821_8, 2020/09

https://doi.org/10.1038/s41467-020-18645-9

Key factors controlling radiocesium sorption and fixation in river sediments around the Fukushima Daiichi Nuclear Power Plant, 2; Sorption and fixation behaviors and their relationship to sediment properties

Tachi, Yukio; Sato, Tomofumi*; Takeda, Chizuko*; Ishidera, Takamitsu; Fujiwara, Kenso; Iijima, Kazuki

Science of the Total Environment, 724, p.138097_1 - 138097_10, 2020/07

https://doi.org/10.1016/j.scitotenv.2020.138097

To understand and predict radiocesium transport behaviors in the environment, sorption and fixation behaviors of radiocesium on river sediments from Ukedo and Odaka rivers around the Fukushima Daiichi Nuclear Power Plant were investigated systematically focusing on Cs sorption and fixation mechanisms and their relationship with Cs concentrations and sediment properties including clay mineralogy and organic matter.

Element-specific density of states of CoMnGe revealed by resonant photoelectron spectroscopy

Kono, Takashi*; Kakoki, Masaaki*; Yoshikawa, Tomoki*; Wang, X.*; Sumida, Kazuki*; Miyamoto, Koji*; Muro, Takayuki*; Takeda, Yukiharu; Saito, Yuji; Goto, Kazuki*; et al.

Physical Review B, 100(16), p.165120_1 - 165120_6, 2019/10

https://doi.org/10.1103/PhysRevB.100.165120

Negative Te spin polarization responsible for ferromagnetic order in the doped topological insulator V(SbBi)Te

Ye, M.*; Xu, T.*; Li, G.*; Qiao, S.*; Takeda, Yukiharu; Saito, Yuji; Zhu, S.-Y.*; Nurmamat, M.*; Sumida, Kazuki*; Ishida, Yukiaki*; et al.

Physical Review B, 99(14), p.144413_1 - 144413_7, 2019/04

AA2018-0697.pdf:1.89MB

https://doi.org/10.1103/PhysRevB.99.144413

Carrier-mediated ferromagnetism in the magnetic topological insulator Cr-doped (Sb,Bi)Te

Ye, M.*; Li, W.*; Zhu, S.-Y.*; Takeda, Yukiharu; Saito, Yuji; Wang, J.*; Pan, H.*; Nurmamat, M.*; Sumida, Kazuki*; Ji, F.*; et al.

Nature Communications (Internet), 6, p.8913_1 - 8913_7, 2015/11

AA2015-0647.pdf:0.64MB

https://doi.org/10.1038/ncomms9913

Magnetically doped topological insulators are predicted to exhibit exotic phenomena including the quantized anomalous Hall effect and a dissipationless transport, which facilitate the development of low-power-consumption devices using electron spins. The realization of the quantized anomalous Hall effect is so far restricted to the Cr-doped (Sb,Bi)Te system at extremely low temperature; however, the microscopic origin of its ferromagnetism is poorly understood. Here we present an element-resolved study for Cr-doped (Sb,Bi)Te using X-ray magnetic circular dichroism to unambiguously show that the long-range magnetic order is mediated by the p-hole carriers of the host lattice, and the interaction between the Sb(Te) p and Cr d states is crucial.

Elucidations of the catalytic cycle of NADH-cytochrome reductase by X-ray crystallography; New insights into regulation of efficient electron transfer

Yamada, Mitsugu*; Tamada, Taro; Takeda, Kazuki*; Matsumoto, Fumiko*; Ono, Hiraku*; Kosugi, Masayuki*; Takaba, Kiyofumi*; Shoyama, Yoshinari*; Kimura, Shigenobu*; Kuroki, Ryota; et al.

Journal of Molecular Biology, 425(22), p.4295 - 4306, 2013/11

https://doi.org/10.1016/j.jmb.2013.06.010

NADH-Cytochrome reductase (b5R), a flavoprotein consisting of NADH and flavin adenine dinucleotide (FAD) binding domains, catalyzes electron transfer from the two-electron carrier NADH to the one-electron carrier cytochrome (Cb5). The crystal structures of both the fully reduced form and the oxidized form of porcine liver b5R were determined. In the reduced b5R structure determined at 1.68 resolution, the relative configuration of the two domains was slightly shifted in comparison with that of the oxidized form. This shift resulted in an increase in the solvent-accessible surface area of FAD and created a new hydrogen-bonding interaction between the N5 atom of the isoalloxazine ring of FAD and the hydroxyl oxygen atom of Thr66, which is considered to be a key residue in the release of a proton from the N5 atom. The isoalloxazine ring of FAD in the reduced form is flat as in the oxidized form and stacked together with the nicotinamide ring of NAD. Determination of the oxidized b5R structure, including the hydrogen atoms, determined at 0.78 resolution revealed the details of a hydrogen-bonding network from the N5 atom of FAD to His49 via Thr66. Both of the reduced and oxidized b5R structures explain how backflow in this catalytic cycle is prevented and the transfer of electrons to one-electron acceptors such as Cb5 is accelerated. Furthermore, crystallographic analysis by the cryo-trapping method suggests that re-oxidation follows a two-step mechanism. These results provide structural insights into the catalytic cycle of b5R.

Model experiment of cosmic ray acceleration due to an incoherent wakefield induced by an intense laser pulse

Kuramitsu, Yasuhiro*; Nakanii, Nobuhiko*; Kondo, Kiminori; Sakawa, Yoichi*; Mori, Yoshitaka*; Miura, Eisuke*; Tsuji, Kazuki*; Kimura, Kazuya*; Fukumochi, Shuji*; Kashihara, Mamoru*; et al.

Physics of Plasmas, 18(1), p.010701_1 - 010701_4, 2011/01

https://doi.org/10.1063/1.3528434

Substituting an intensive laser pulse for the large amplitude light waves, we performed a model experiment of the shock environments in a laboratory plasma. An intensive laser pulse was propagated in a plasma tube created by imploding a hollow polystyrene cylinder, as the large amplitude light waves propagated in the upstream plasma at an astrophysical shock. Nonthermal electrons were generated, and the energy distribution functions of the electrons have a power-law component with an index of 2.

Neutron structural analysis of NADH-cytochrome reductase

Hirano, Yu; Yamada, Mitsugu*; Kurihara, Kazuo; Shoyama, Yoshinari*; Kuroki, Ryota; Kusaka, Katsuhiro*; Kimura, Shigenobu*; Takeda, Kazuki*; Miki, Kunio*; Tamada, Taro

no journal, , 

NADH-cytochrome reductase (b5R), a flavoprotein consisting of NADH- and FAD- domains, catalyzes electron transfer from the two-electron carrier NADH to the one-electron carrier cytochrome . The reaction catalyzed by plays a role in fatty acid synthesis, cholesterol synthesis, and xenobiotic oxidation as a member of the electron transport chain on the endoplasmic reticulum. We have already determined the crystal structures of both the fully reduced and oxidized forms of porcine liver b5R by X-ray crystallography, but, its detail mechanism, especially hydride/proton transfers and exact states of semiquinone, still remains unknown. The hydrogen information obtained by neutron crystallography will be essential for the real understanding of catalytic cycle of the . A large crystal with the size of almost 2 mm was transferred to cryo-protectant solution by stepwise soaking method, and then were flash-frozen in a cold nitrogen gas stream. Using this crystal, we collected neutron data to 1.4 resolution at BL03 (iBIX), MLF, J-PARC, and then collected to 0.85 resolution at BL5A, PF, KEK. Crystallographic refinement using both neutron and X-ray data is in progress.