Intercalative and non-intercalative photo-recharge using all-solid-state cells for solar energy conversion and storage

Yoshimoto, Masataka*; Tamura, Kazuhisa; Watanabe, Kenta*; Shimizu, Keisuke*; Horisawa, Yuhei*; Kobayashi, Takeshi*; Tsurita, Hanae*; Suzuki, Kota*; Kanno, Ryoji*; Hirayama, Masaaki*

Sustainable Energy & Fuels (Internet), 8(6), p.1236 - 1244, 2024/03

https://doi.org/10.1039/D3SE01636F

Photo-rechargeable systems, which can efficiently convert and store solar energy into chemical energy within single devices, are essential to harness sunlight effectively. Photo-(de)intercalation plays a pivotal role in the functionality of photorechargeable systems. Nevertheless, the photo-(de)intercalation process has not been conclusively confirmed owing to potential interference from side reactions, such as the decomposition of liquid electrolytes and the elution of electrode materials. In this study, we successfully demonstrated photo-responsive Li-deintercalation using an all-solid-state thin-film battery comprised of epitaxially-grown anatase TiO doped with Nb (a-TiO:Nb) as the cathode. Under light irradiation, Li-deintercalation occurred and was subsequently reversibly intercalated into a-TiO:Nb during discharge.

Consideration of high intensity single bunch acceleration in J-PARC RCS

Tamura, Fumihiko; Okita, Hidefumi; Hotchi, Hideaki*; Saha, P. K.; Meigo, Shinichiro; Yoshii, Masahito*; Omori, Chihiro*; Yamamoto, Masanobu; Seiya, Kiyomi*; Sugiyama, Yasuyuki*; et al.

Proceedings of 20th Annual Meeting of Particle Accelerator Society of Japan (Internet), p.64 - 68, 2023/11

https://www.pasj.jp/web_publish/pasj2023/proceedings/PDF/WEOB/WEOB6.pdf

The J-PARC 3GeV synchrotron (RCS) provides high intensity proton beams to the Materials and Life Science Experimental Facility (MLF) and the Main Ring (MR). The harmonic number (h) of the RCS is 2 and the RCS normally accelerates two bunches. For some experiments at the MLF, a single bunch is preferred. In this case, one of the rf bucket is filled with protons and the other is empty. Therefore the beam intensity is halved. If the RCS can accelerate with h=1, the intensity per bunch can be doubled, enabling to provide single bunch beams to the MLF with the maximum intensity. This possibly increases the MR beam power by injecting high intensity single bunches eight times. In this presentation, we report mainly on the consideration of h=1 acceleration in the RCS by longitudinal simulations.

How to confirm the polarity of the DTQ in the J-PARC DTL

Kosaka, Satoshi*; Arai, Sora; Nemoto, Yasuo*; Kitamura, Ryo

JAEA-Technology 2023-003, 34 Pages, 2023/05

JAEA-Technology-2023-003.pdf:3.79MB

The negative hydrogen (H) ion beam is accelerated with a peak current of 50 mA in the J-PARC linac. The linac consists of the H- ion source and four kinds of accelerating cavities; a radio-frequency quadrupole linac (RFQ), a drift-tube linac (DTL), a separated-DTL (SDTL), and an annular-ring coupled structure linac (ACS). The accelerating electric field exists between the drift-tubes in the tank of the DTL. The quadrupole magnet for the beam focusing (DTQ) is installed in the drift-tube. The DTQ at J-PARC employs electromagnets to generate the magnetic field. It is important to set correctly the polarity of the magnetic field of the DTQ for tuning the beam. In this paper, we report the method of confirming the magnetic field polarity of DTQ, that is, the current wiring polarity by measuring DC current using a clamp meter on the power supply side and visually confirming the cable wiring connection on the electromagnet side.

Incommensurate helimagnetic structure of Ba(FeSc)O determined by single-crystal neutron diffraction

Tanaka, Seiya*; Kiyanagi, Ryoji; Ishikawa, Yoshihisa*; Amako, Yasushi*; Iiyama, Taku*; Futamura, Ryusuke*; Maruyama, Kenichi*; Utsumi, Shigenori*

Physical Review Materials (Internet), 7(1), p.014403_1 - 014403_11, 2023/01

https://doi.org/10.1103/PhysRevMaterials.7.014403

Longitudinal measurement of high-intensity beam with bunch-shape monitor in front-end

Kitamura, Ryo; Hayashi, Naoki; Hirano, Koichiro; Miyao, Tomoaki*; Miura, Akihiko; Morishita, Takatoshi

Proceedings of 19th Annual Meeting of Particle Accelerator Society of Japan (Internet), p.212 - 214, 2023/01

In the J-PARC linac, the bunch-shape monitor (BSM) is developed to precisely and rapidly measure the longitudinal beam profile at the front-end, towards the improvement of the beam matching. The graphite target having the good strength to the high-power beam, has been introduced in order to resist the heat loading of the high-intensity beam. The resolution and other uncertainties were evaluated for the BSM. The longitudinal Twiss parameters and emittance were measured using the BSM and the IMPACT, which was the 3D particle-in-cell simulation code. The precision of the longitudinal emittance measurement was improved, by implementing uncertainties related to the BSM into the calculation. In this presentation, we will report a series of the measurement result, the method of the beam diagnostics with the BSM at the front-end, and the comparison between the measurement and the beam simulation.

Oxygen reduction activity and interfacial structures of LaSrCoO at initial electrochemical process in an alkaline solution

Matsuzaki, Akira*; Hirayama, Masaaki*; Oguchi, Shoya*; Komo, Mamoru*; Ikezawa, Atsunori*; Suzuki, Kota*; Tamura, Kazuhisa; Arai, Hajime*; Kanno, Ryoji*

Electrochemistry (Internet), 90(10), p.107001_1 - 107001_8, 2022/10

https://doi.org/10.5796/electrochemistry.22-00079

Oxygen reduction and evolution reactions (ORR and OER) of perovskite-type LaSrCoO were characterized using two-dimensional model electrodes with different reaction planes. Synthesized by pulsed laser deposition, these thin and flat electrodes can reveal the reaction plane dependence of the ORR activity. From steady-state polarization measurements in KOH (aq.), the ORR activity was the highest on the (001) film during the first ORR/OER cycle, and it decreased significantly during the second cycle. In-situ synchrotron X-ray diffraction clarified crystal structure changes in the bulk and surface regions of LaSrCoO, and these changes are associated with forming oxygen defects during the initial electrochemical process. Furthermore, the LaSrCoO surface partially decomposed upon reacting. Therefore, the interfacial structures formed in the electrochemical reaction field is important for enhancing ORR and OER activities.

Study on the evaluation method to determine the radioactivity concentration in radioactive waste on Oarai Research and Development Institute (FY2020)

Asakura, Kazuki; Shimomura, Yusuke; Donomae, Yasushi; Abe, Kazuyuki; Kitamura, Ryoichi; Miyakoshi, Hiroyuki; Takamatsu, Misao; Sakamoto, Naoki; Isozaki, Ryosuke; Onishi, Takashi; et al.

JAEA-Review 2021-020, 42 Pages, 2021/10

JAEA-Review-2021-020.pdf:2.95MB

The disposal of radioactive waste from the research facility need to calculate from the radioactivity concentration that based on variously nuclear fuels and materials. In Japan Atomic Energy Agency Oarai Research and Development Institute, the study on considering disposal is being advanced among the facilities which generate radioactive waste as well as the facilities which process radioactive waste. This report summarizes a study result in FY2020 about the evaluation method to determine the radioactivity concentration in radioactive waste on Oarai Research and Development Institute.

Development of negative muonium ion source for muon acceleration

Kitamura, Ryo; Bae, S.*; Choi, S.*; Fukao, Yoshinori*; Iinuma, Hiromi*; Ishida, Katsuhiko*; Kawamura, Naritoshi*; Kim, B.*; Kondo, Yasuhiro; Mibe, Tsutomu*; et al.

Physical Review Accelerators and Beams (Internet), 24(3), p.033403_1 - 033403_9, 2021/03

https://doi.org/10.1103/PhysRevAccelBeams.24.033403

A negative muonium ion (Mu) source using an aluminum foil target was developed as a low-energy muon source. An experiment to produce Mu ions was conducted to evaluate the performance of the Mu ion source. The measured event rate of Mu ions was Mu/s when the event rate of the incident muon beam was /s. The formation probability, defined as the ratio of the Mu ions to the incident muons on the Al target, was . This Mu ion source boosted the development of the muon accelerator, and the practicality of this low-energy muon source obtained using a relatively simple apparatus was demonstrated.

Dynamic observation and theoretical analysis of initial O molecule adsorption on polar and -plane surfaces of GaN

Sumiya, Masatomo*; Sumita, Masato*; Asai, Yuya*; Tamura, Ryo*; Uedono, Akira*; Yoshigoe, Akitaka

Journal of Physical Chemistry C, 124(46), p.25282 - 25290, 2020/11

https://doi.org/10.1021/acs.jpcc.0c07151

The initial oxidation of different GaN surfaces [the polar Ga-face (+c) and N-face (-c) and the nonpolar (100) ()plane] under O molecular beam irradiation was studied by real-time synchrotron radiation X-ray photoelectron spectroscopy and DFT molecular dynamics calculation. The results predict that triplet O either dissociates or chemisorbs at the bridge position on the +c-surface, while on N-terminated -c-surface the O2 molecule only undergoes dissociative chemisorption. On the -GaN surface, although the dissociation of O is dominant, the bond length and angle were found to fluctuate from those of O molecules adsorbed on the polar surfaces. The computational model including both the surface spin and polarity of GaN is useful for understanding the interface between GaN and oxide layers in metal-oxide electronic.

Evaluation of the bunch-shape monitor for the high-intensity proton beam

Kitamura, Ryo; Futatsukawa, Kenta*; Hayashi, Naoki; Hirano, Koichiro; Kondo, Yasuhiro; Kosaka, Satoshi*; Miyao, Tomoaki*; Nemoto, Yasuo*; Morishita, Takatoshi; Oguri, Hidetomo

Proceedings of 17th Annual Meeting of Particle Accelerator Society of Japan (Internet), p.251 - 253, 2020/09

A bunch-shape monitor (BSM) in the low-energy region is being developed in the J-PARC linac to accelerate the high-intensity proton beam with the low emittance. A highly-oriented pyrolytic graphite (HOPG) was introduced as the target of the BSM to mitigate the thermal loading. The stable measurement of the BSM was realized thanks to the HOPG target, while the tungsten target was broken by the thermal loading from the high-intensity beam. However, since the longitudinal distribution measured with the BSM using the HOPG target was wider than the expected one, the improvement of tuning parameters is necessary for the BSM. The BSM consists of an electron multiplier, a bending magnet, and a radio-frequency deflector, which should be tuned appropriately. Behavior of these components were investigated and tuned. The longitudinal distribution measured with the BSM after the tuning was consistent with the expected one.