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Zhao, Y.; Yoshimura, Kimio; Shishitani, Hideyuki*; Yamaguchi, Susumu*; Tanaka, Hirohisa*; Koizumi, Satoshi*; Szekely, N.*; Radulescu, A.*; Richter, D.*; Maekawa, Yasunari
Soft Matter, 12(5), p.1567 - 1578, 2016/02
Times Cited Count:27 Percentile:80.24(Chemistry, Physical)Yoshimura, Kimio; Koshikawa, Hiroshi; Yamaki, Tetsuya; Shishitani, Hideyuki*; Yamamoto, Kazuya*; Yamaguchi, Susumu*; Tanaka, Hirohisa*; Maekawa, Yasunari
Journal of the Electrochemical Society, 161(9), p.F889 - F893, 2014/06
Times Cited Count:21 Percentile:61.31(Electrochemistry)Graft-type anion-conducting electrolyte membranes (AEMs) with imidazolium cations on graft polymers were synthesized through radiation-induced graft polymerization of -vinylimidazole (NVIm) on poly(ethylene-co-tetrafluoroethylene) (ETFE) films, followed by -propylation and ion-exchange reactions. The -propylation proceeded quantitatively, whereas the ion-exchange reactions in 1 M KOH at 60C were accompanied by partial -elimination of the imidazolium cations(AEM2), which exhibited an ion-exchange capacity (IEC) of 0.85 mmol g and ionic conductivity of 10 mS cm. AEM2 showed alkaline stability at 60C but it gradually degraded at 80C for ca. 150 h. The copolymer-type AEM (AEM3) with an IEC of 1.20 mmol g was prepared through the copolymerization of NVIm with styrene on ETFE films, followed by the same -propylation and ion-exchange reactions. AEM3 was shown higher alkaline durability in 1 M KOH at 80C. As a result, it exhibited higher conductivity (10 mS cm) for 250 h. Therefore, alkylimidazolium cations in copolymer grafts are a promising anion conducting group for alkaline-durable AEMs. A maximum power density of 75 mW cm is obtained for AEM3 in a direct hydrazine hydrate fuel cell.
Koshikawa, Hiroshi; Yoshimura, Kimio; Sinnananchi, W.; Yamaki, Tetsuya; Asano, Masaharu; Yamamoto, Kazuya*; Yamaguchi, Susumu*; Tanaka, Hirohisa*; Maekawa, Yasunari
Macromolecular Chemistry and Physics, 214(15), p.1756 - 1762, 2013/08
Times Cited Count:15 Percentile:45.37(Polymer Science)Graft-type anion-conducting polymer electrolyte membranes were prepared by the radiation-induced graft polymerization of chloromethylstyrene into poly(ethylene-co-tetrafluoroethylene) (ETFE) films and subsequent quaternization with trimethylamine to evaluate the counter anion effects on fuel cell properties. The hydroxide form was maintained in -saturated water to prevent the bicarbonate formation. The hydroxide form showed conductivity and water uptake four and two times higher than the chloride and bicarbonate forms. The hydroxide form is thermally and chemically less stable, resulting in the tendency to absorb water and to convert to the bicarbonate form.
Yoshimura, Kimio; Koshikawa, Hiroshi; Yamaki, Tetsuya; Maekawa, Yasunari; Yamamoto, Kazuya*; Shishitani, Hideyuki*; Asazawa, Koichiro*; Yamaguchi, Susumu*; Tanaka, Hirohisa*
ECS Transactions, 50(2), p.2075 - 2081, 2012/10
no abstracts in English
Ushigusa, Kenkichi; Seki, Masahiro; Ninomiya, Hiromasa; Norimatsu, Takayoshi*; Kamada, Yutaka; Mori, Masahiro; Okuno, Kiyoshi; Shibanuma, Kiyoshi; Inoue, Takashi; Sakamoto, Keishi; et al.
Genshiryoku Handobukku, p.906 - 1029, 2007/11
no abstracts in English
Tsuchiya, Kunihiko; Hoshino, Tsuyoshi; Kawamura, Hiroshi; Mishima, Yoshinao*; Yoshida, Naoaki*; Terai, Takayuki*; Tanaka, Satoru*; Munakata, Kenzo*; Kato, Shigeru*; Uchida, Munenori*; et al.
Nuclear Fusion, 47(9), p.1300 - 1306, 2007/09
Times Cited Count:23 Percentile:61.91(Physics, Fluids & Plasmas)no abstracts in English
Tsuchiya, Kunihiko; Hoshino, Tsuyoshi; Kawamura, Hiroshi; Mishima, Yoshinao*; Yoshida, Naoaki*; Terai, Takayuki*; Tanaka, Satoru*; Munakata, Kenzo*; Kato, Shigeru*; Uchida, Munenori*; et al.
Proceedings of 21st IAEA Fusion Energy Conference (FEC 2006) (CD-ROM), 8 Pages, 2007/03
no abstracts in English
Hoshino, Tsuyoshi; Tsuchiya, Kunihiko; Hayashi, Kimio; Terai, Takayuki*; Tanaka, Satoru*; Takahashi, Yoichi*
Fusion Engineering and Design, 75-79, p.939 - 943, 2005/11
Times Cited Count:13 Percentile:65.32(Nuclear Science & Technology)no abstracts in English
Hayashi, Kimio; Ishihara, Masahiro; Shibata, Taiju; Ishino, Shiori*; Terai, Takayuki*; Ito, Hisayoshi; Tagawa, Seiichi*; Katsumura, Yosuke*; Yamawaki, Michio*; Shikama, Tatsuo*; et al.
Proceedings of 1st Information Exchange Meeting on Basic Studies on High-Temperature Engineering, p.41 - 58,268, 1999/09
no abstracts in English
Saito, Shinzo; Tanaka, Toshiyuki; Sudo, Yukio; Baba, Osamu; Shindo, Masami; Shiozawa, Shusaku; Mogi, Haruyoshi; Okubo, Minoru; Ito, Noboru; Shindo, Ryuichi; et al.
JAERI 1332, 247 Pages, 1994/09
no abstracts in English
Saito, Mikio*; Sugihara, Takashi*; Tanaka, Kimio*; Ogiso, Yoichi*; Funayama, Tomoo; Wada, Seiichi; Sakashita, Tetsuya; Kobayashi, Yasuhiko
no journal, ,
no abstracts in English
Sugimoto, Masaki; Yoshimura, Kimio; Idesaki, Akira; Yoshikawa, Masahito; Asano, Atsushi*; Seki, Shu*; Tsukuda, Satoshi*; Tanaka, Shunichiro*
no journal, ,
no abstracts in English
Koshikawa, Hiroshi; Yamaki, Tetsuya; Asano, Masaharu; Yoshimura, Kimio; Maekawa, Yasunari; Yamamoto, Kazuya*; Shishitani, Hideyuki*; Asazawa, Koichiro*; Yamaguchi, Susumu*; Tanaka, Hirohisa*
no journal, ,
We investigated the effect of the length of the linear chain on the structure of quaternary ammonium ions on the membrane properties such as durability of ion conductivity. Graft polymerization was performed by immersing the pre-irradiated ETFE film in the CMS solution. The ETFE-g-CMS film was then quaternized in four different tertiary amines, that is, trimethylamine (n = 1), dimethylethylamine (n = 2), n-butyldimethylamine (n = 4) and n-hexyldimethylamine (n = 6) solutions. The n dependence of the OH conductivity and chemical durability, which was represented by a residual percentage of the conductivity after treatment with a Fenton solution. When n increased from 1 to 6, the OH conductivity decreased slightly, but it still stayed 20 mS/cm for n = 6. The chemical durability seemed to increase eight-fold at the same time. The chemical attack by hydroxyl radicals on the quaternary ammonium ions would be controlled by hydrophobicity and steric hindrance of the alkyl group.
Tanaka, Yasuharu*; Goto, Kazuyuki*; Miyagawa, Kimio*; Tsukuda, Kazuhiro*; Goshima, Keiichiro*; Kunimaru, Takanori; Tsuruta, Tadahiko; Morikawa, Keita; Yuguchi, Takashi
no journal, ,
no abstracts in English
Yoshimura, Kimio; Sinnananchi, W.; Koshikawa, Hiroshi; Yamaki, Tetsuya; Maekawa, Yasunari; Yamamoto, Kazuya*; Shishitani, Hideyuki*; Asazawa, Koichiro*; Yamaguchi, Susumu*; Tanaka, Hirohisa*
no journal, ,
no abstracts in English
Asano, Masaharu; Koshikawa, Hiroshi; Yamaki, Tetsuya; Yoshimura, Kimio; Maekawa, Yasunari; Yamamoto, Kazuya*; Sampei, Fumihiro*; Shishitani, Hideyuki*; Asazawa, Koichiro*; Yamaguchi, Susumu*; et al.
no journal, ,
no abstracts in English
Yoshimura, Kimio; Koshikawa, Hiroshi; Yamaki, Tetsuya; Sampei, Fumihiro*; Shishitani, Hideyuki*; Asazawa, Koichiro*; Yamaguchi, Susumu*; Tanaka, Hirohisa*; Maekawa, Yasunari
no journal, ,
no abstracts in English
Yoshimura, Kimio; Sinananwanich, W.*; Koshikawa, Hiroshi; Asano, Masaharu; Yamaki, Tetsuya; Maekawa, Yasunari; Yamamoto, Kazuya*; Shishitani, Hideyuki*; Asazawa, Koichiro*; Yamaguchi, Susumu*; et al.
no journal, ,
no abstracts in English
Maekawa, Yasunari; Yoshimura, Kimio; Koshikawa, Hiroshi; Yamaki, Tetsuya; Yamamoto, Kazuya*; Shishitani, Hideyuki*; Asazawa, Koichiro*; Yamaguchi, Susumu*; Tanaka, Hirohisa*
no journal, ,
Anion-exchange membranes (AEM) for hydrazine fuel cells, in which non precious metals are used as an electrode catalyst, have been developing by radiation techniques. AEMs having polyvinylimidazolium grafts were synthesized by radiation-induced graft polymerization of N-vinylimidazole or the copolymerizaiton with styrene onto ETFE film, followed by N-alkylation and ion exchange reactions. The alkaline durability of the membranes was evaluated in 1M KOH at 80 C. The AEM consisting of the homopolymer grafts showed alkaline stability at 80 C for ca. 150 hours. In contrast, the copolymer (1:1 molar ratio) grafts type AEM kept its ion conductivity above 10 mS/cm in 1M KOH at 80 C for 250 h. The alkylimidazolium group in the copolymer grafts is a promising anion exchange group in AEMs for highly alkaline durable fuel cells.
Koshikawa, Hiroshi; Yamaki, Tetsuya; Asano, Masaharu; Yoshimura, Kimio; Maekawa, Yasunari; Yamamoto, Kazuya*; Shishitani, Hideyuki*; Asazawa, Koichiro*; Yamaguchi, Susumu*; Tanaka, Hirohisa*
no journal, ,
We prepared anion-exchange membranes based on an ethylene-tetrafluoroethylene copolymer by -ray-induced graft polymerization of chloromethylstyrene (CMS) and the subsequent quaternization reaction. The crosslinker effect was investigated in terms of membrane preparation and performance of a hydrazine fuel cell. The quaternization ratio appeared to decrease as the concentration of divinylbenzene (DVB) in the CMS grafting solution increased. Importantly, the crosslinker lowered the water uptake of the resulting membranes in the Cl and OH forms, possibly thereby restricting excessive swelling during the fuel-cell operation.