Fundamental study for decorporation of plutonium by chelating agents; Coordination analyses of simulated plutonium with chelating agents by X-ray absorption spectroscopy

Uehara, Akihiro*; Shuhui, X.*; Sato, Ryotaro*; Matsumura, Daiju; Tsuji, Takuya; Yakumaru, Haruko*; Shiro, Ayumi*; Saito, Hiroyuki*; Tanaka, Izumi*; Ishihara, Hiroshi*; et al.

Advances in X-Ray Chemical Analysis, Japan, 53, p.223 - 229, 2022/03

no abstracts in English

Release behavior of radionuclides from MOX fuels irradiated in a fast reactor during heating tests

Tanaka, Kosuke; Sato, Isamu*; Onishi, Takashi; Ishikawa, Takashi; Hirosawa, Takashi; Katsuyama, Kozo; Seino, Hiroshi; Ohno, Shuji; Hamada, Hirotsugu; Tokoro, Daishiro*; et al.

Journal of Nuclear Materials, 536, p.152119_1 - 152119_8, 2020/08

https://doi.org/10.1016/j.jnucmat.2020.152199

In order to obtain the release rate coefficients from fuels for fast reactors (FRs), heating tests and the subsequent analyses of the fission products (FPs) and actinides that are released were carried out using samples of uranium-plutonium mixed oxide (MOX) fuel pellets irradiated at the experimental fast reactor Joyo. Three heating tests targeting temperatures of 2773, 2973 and 3173 K were conducted using an FP release behavior test apparatus equipped with a high-frequency induction furnace and solid FP sampling systems consisting of a thermal gradient tube (TGT) and filters. Irradiated fuel pellets were placed into a tungsten crucible, then loaded into the induction furnace. The temperature was raised continuously at a heating rate of 10 K/s to the targeted temperature and maintained for 500 s in a flowing argon gas atmosphere. The FPs and actinides released from the MOX fuels and deposited in the TGT and filters were quantified by gamma-ray spectrometry and inductively coupled plasma mass spectrometry (ICP-MS) analysis. Based on the analysis, the release rates of radionuclides from MOX fuels for FR were obtained and compared with literature data for light water reactor (LWR) fuels. The release rate coefficients of FPs obtained in this study were found to be similar to or lower than the literature values for LWR fuels. It was also found that the release rate coefficient data for actinides were within the range of variation of literature values for LWR fuels.

Research and development on membrane IS process for hydrogen production using solar heat

Myagmarjav, O.; Iwatsuki, Jin; Tanaka, Nobuyuki; Noguchi, Hiroki; Kamiji, Yu; Ioka, Ikuo; Kubo, Shinji; Nomura, Mikihiro*; Yamaki, Tetsuya*; Sawada, Shinichi*; et al.

International Journal of Hydrogen Energy, 44(35), p.19141 - 19152, 2019/07

https://doi.org/10.1016/j.ijhydene.2018.03.132

Retreat from stress; Rattling in a planar coordination

Suekuni, Koichiro*; Lee, C. H.*; Tanaka, Hiromi*; Nishibori, Eiji*; Nakamura, Atsushi*; Kasai, Hidetaka*; Mori, Hitoshi*; Usui, Hidetomo*; Ochi, Masayuki*; Hasegawa, Takumi*; et al.

Advanced Materials, 30(13), p.1706230_1 - 1706230_6, 2018/03

https://doi.org/10.1002/adma.201706230

Thermoelectric materials for highly efficient devices must satisfy conflicting requirements of high electrical conductivity and low thermal conductivity. In this paper, we studied the crystal structure and phonon dynamics of tetrahedrites (Cu,Zn)(Sb,As)S. The results revealed that the Cu atoms in a planar coordination are rattling, which effectively scatter phonons. These findings provide a new strategy for the development of highly efficient thermoelectric materials with planar coordination.

Characterization of the PTW 34031 ionization chamber (PMI) at RCNP with high energy neutrons ranging from 100 - 392 MeV

Theis, C.*; Carbonez, P.*; Feldbaumer, E.*; Forkel-Wirth, D.*; Jaegerhofer, L.*; Pangallo, M.*; Perrin, D.*; Urscheler, C.*; Roesler, S.*; Vincke, H.*; et al.

EPJ Web of Conferences, 153, p.08018_1 - 08018_5, 2017/09

https://doi.org/10.1051/epjconf/201715308018

At CERN, gas-filled ionization chambers PTW-34031 (PMI) are commonly used in radiation fields including neutrons, protons and -rays. A response function for each particle is calculated by the radiation transport code FLUKA. To validate a response function to high energy neutrons, benchmark experiments with quasi mono-energetic neutrons have been carried out at RCNP, Osaka University. For neutron irradiation with energies below 200 MeV, very good agreement was found comparing the FLUKA simulations and the measurements. In addition it was found that at proton energies of 250 and 392 MeV, results calculated with neutron sources underestimate the experimental data due to a non-negligible gamma component originating from the target Li(p,n)Be reaction.

Application of neutron stress measurement to reinforced concrete structure

Suzuki, Hiroshi; Kusunoki, Koichi*; Kanematsu, Manabu*; Tasai, Akira*; Hatanaka, Yuichi*; Tsuchiya, Naoko*; Bae, S.*; Shiroishi, Sho*; Sakurai, Sonoko*; Kawasaki, Takuro; et al.

JPS Conference Proceedings (Internet), 8, p.031006_1 - 031006_6, 2015/09

https://doi.org/10.7566/JPSCP.8.031006

The bond resistance between reinforcing bar (rebar) and concrete is one important parameter for examining integrity of the reinforced concrete structure, and is commonly evaluated by measuring the strain distribution along the rebar embedded in concrete. Here we present two types of applications of the time-of-flight neutron diffraction technique to measure the stress distribution of the rebar. It was demonstrated that bond deterioration around cracks developed in concrete can be evaluated by measuring the stress distribution along the embedded rebar using neutron diffraction. Furthermore, a change in the stress distribution along the rebar due to bond deterioration by corrosion was observed. The neutron diffraction technique is expected to become a novel method for measuring the stress (strain) of the rebar embedded in concrete, and will eventually provide insight into the actual phenomena on the reinforced concrete structures.

Accurate structure analyses of polymer crystals on the basis of wide-angle X-ray and neutron diffractions

Tashiro, Koji*; Hanesaka, Makoto*; Yamamoto, Hiroko*; Wasanasuk, K.*; Jayaratri, P.*; Yoshizawa, Yoshinori*; Tanaka, Ichiro*; Niimura, Nobuo*; Kusaka, Katsuhiro*; Hosoya, Takaaki*; et al.

Kobunshi Rombunshu, 71(11), p.508 - 526, 2014/11

https://doi.org/10.1295/koron.71.508

The crystal structure analysis of various polymer substances has been reviewed on the basis of wide-angle high-energy X-ray and neutron diffraction data. The progress in structural analytical techniques of polymer crystals have been reviewed at first. The structural models proposed so far were reinvestigated and new models have been proposed for various kinds of polymer crystals including polyethylene, poly(vinyl alcohol), poly(lactic acid) and its stereocomplex etc. The hydrogen atomic positions were also clarified by the quantitative analysis of wide-angle neutron diffraction data, from which the physical properties of polymer crystals have been evaluated theoretically. The bonded electron density distribution has been estimated for a polydiacetylene single crystal on the basis of the so-called X-N method or by the combination of structural information derived from X-ray and neutron diffraction data analysis. Some comments have been added about future developments in the field of structure-property relationship determination.

Evaluation of fission product and actinide release behaviors focusing on their chemical forms; Phase relation and fission product release behavior resulting from interaction between molten zircaloy and irradiated MOX fuel

Tanaka, Kosuke; Miwa, Shuhei; Sato, Isamu; Hirosawa, Takashi; Sekine, Shinichi; Seki, Takayuki*; Tokoro, Daishiro*; Obayashi, Hiroshi; Koyama, Shinichi

JAEA-Research 2013-022, 62 Pages, 2014/01

JAEA-Research-2013-022.pdf:33.64MB

In order to establish the method for heating tests focused on the fission product release resulting from the high temperature chemical interaction between fuel and cladding material and to obtain the novel data on fission product release behaviors, the heating test was carried out with irradiate MOX fuel pellet and cladding.

Intermediate-valence icosahedral Au-Al-Yb quasicrystal

Watanuki, Tetsu; Kashimoto, Shiro*; Kawana, Daichi*; Yamazaki, Teruo*; Machida, Akihiko; Tanaka, Yukinori*; Sato, Taku*

Physical Review B, 86(9), p.094201_1 - 094201_6, 2012/09

https://doi.org/10.1103/PhysRevB.86.094201

A quasiperiodic, intermediate-valence (IV) system is realized in an icosahedral Au-Al-Yb quasicrystal. X-ray absorption spectroscopy near the Yb -edge indicates that quasiperiodically arranged Yb ions assume a mean valence of 2.61, between a divalent state (4, = 0) and a trivalent one (4, = 7/2). Magnetization measurements demonstrate that the 4 holes in this quasicrystal have a localized character. The magnetic susceptibility shows a Curie-Weiss behavior above 100 K with an effective magnetic moment of 3.81 per Yb. Moreover, a crystalline approximant to this quasicrystal is an IV compound. We propose a heterogeneous IV model for the quasicrystal, whereas the crystalline approximant is most likely a homogeneous IV system. At temperatures below 10 K, specific heat and magnetization measurements reveal non-Fermi-liquid behavior in both the quasicrystal and its crystalline approximant without either doping, pressure, or field tuning.

Consideration on the earthquake-resistant margin of equipment base-bolts receiving the shearing load during seismic movements

Sakaguchi, Shinobu; Tachibana, Ikuya; Koshino, Katsuhiko; Shirozu, Hidetomo; Shirai, Nobutoshi; Imamoto, Nobuo; Tomita, Tsuneo; Tobita, Hiroo; Yamanaka, Atsushi; Kobayashi, Daisuke; et al.

JAEA-Technology 2011-006, 24 Pages, 2011/03

JAEA-Technology-2011-006.pdf:3.07MB

In the Niigataken Chuetsu-oki Earthquake on 2007, observed earthquake motion exceeded design base at the Kashiwazaki Kariwa nuclear plant. However, there was no earthquake damage in safety important equipments to stop reactor, to cool reactor, and to contain radioactive materials. One of this reason is said that many safety margin are included in the design and the permissible value. To know more accurate safety margin, shearing force examinations for the base bolts were conducted. In examinations, delegate test-bolts were made; the test bolts were selected from heavier equipment in Tokai Reprocessing Plant. In this report, the shearing strength obtained from the examinations shows more accurate safety margin.