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Wang, X.*; Tang, X.*; Zhang, P.*; Wang, Y.*; Gao, D.*; Liu, J.*; Hui, K.*; Wang, Y.*; Dong, X.*; Hattori, Takanori; et al.
Journal of Physical Chemistry Letters (Internet), 12(50), p.12055 - 12061, 2021/12
Times Cited Count:6 Percentile:44.89(Chemistry, Physical)Substituted polyacetylene is expected to improve the chemical stability, physical properties, and additional functions of the polyacetylene backbones, but its diversity is very limited. Here, by applying external pressure on solid acetylenedicarboxylic acid, we report the first crystalline poly-dicarboxylacetylene with every carbon on the trans-polyacetylene backbone bonded to a carboxyl group, which is very hard to synthesize by traditional methods. This unique structure combines the extremely high content of carbonyl groups and high conductivity of a polyacetylene backbone, which exhibits a high specific capacity and excellent cycling/rate performance as a Li-ion battery (LIB) anode. We present a completely functionalized crystalline polyacetylene and provide a high-pressure solution for the synthesis of polymeric LIB materials and other polymeric materials with a high content of active groups.
Yan, S. Q.*; Li, X. Y.*; Nishio, Katsuhisa; Lugaro, M.*; Li, Z. H.*; Makii, Hiroyuki; Pignatari, M.*; Wang, Y. B.*; Orlandi, R.; Hirose, Kentaro; et al.
Astrophysical Journal, 919(2), p.84_1 - 84_7, 2021/10
Times Cited Count:1 Percentile:8.87(Astronomy & Astrophysics)Zhang, P.*; Tang, X.*; Wang, Y.*; Wang, X.*; Gao, D.*; Li, Y.*; Zheng, H.*; Wang, Y.*; Wang, X.*; Fu, R.*; et al.
Journal of the American Chemical Society, 142(41), p.17662 - 17669, 2020/10
Times Cited Count:21 Percentile:74.59(Chemistry, Multidisciplinary)Solid-state topochemical polymerization (SSTP) is a promising method to construct functional crystalline polymeric materials, but in contrast to various reactions that happen in solution, only very limited types of SSTP reactions are reported. Diels-Alder (DA) and dehydro-DA (DDA) reactions are textbook reactions for preparing six-membered rings in solution but are scarcely seen in solid-state synthesis. Here, using multiple cutting-edge techniques, we demonstrate that the solid 1,4-diphenylbutadiyne (DPB) undergoes a DDA reaction under 10-20 GPa with the phenyl as the dienophile. The crystal structure at the critical pressure shows that this reaction is "distance-selected". The distance of 3.2 between the phenyl and the phenylethynyl facilitates the DDA reaction, while the distances for other DDA and 1,4-addition reactions are too large to allow the bonding. The obtained products are crystalline armchair graphitic nanoribbons, and hence our studies open a new route to construct the crystalline carbon materials with atomic-scale control.
Chen, L.-M.; Nakajima, Kazuhisa; Hong, W.*; Hua, J. F.*; Kameshima, Takashi; Kotaki, Hideyuki; Sugiyama, Kiyohiro*; Wen, X.*; Wu, Y.*; Tang, C.*; et al.
Chinese Optics Letters, 5(S1), p.S133 - S135, 2007/05
Chen, L.-M.; Kotaki, Hideyuki; Nakajima, Kazuhisa*; Koga, J. K.; Bulanov, S. V.; Tajima, Toshiki; Gu, Y. Q.*; Peng, H. S.*; Wang, X. X.*; Wen, T. S.*; et al.
Physics of Plasmas, 14(4), p.040703_1 - 040703_4, 2007/04
Times Cited Count:36 Percentile:75.52(Physics, Fluids & Plasmas)An experiment for the laser self-guiding studies has been carried out with 100 TW laser pulse interaction with the long underdense plasma. Formation of extremely long plasma channel with its length, about 10 mm, 20 times above the Rayleigh length is observed. The self-focusing channel features such as the laser pulse significant bending and the electron cavity formation are demonstrated experimentally for the first time.
Rewoldt, G.*; Hill, K. W.*; Nazikian, R. M.*; Tang, W. M.*; Shirai, Hiroshi; Sakamoto, Yoshiteru; Kishimoto, Yasuaki; Ide, Shunsuke; Fujita, Takaaki
Nuclear Fusion, 42(4), p.403 - 411, 2002/04
Times Cited Count:9 Percentile:30.39(Physics, Fluids & Plasmas)One class of internal transport barrier discharge in the JT-60U tokamak is characterized by two relatively flat regions of the pressure separated by a region with very large pressure gradient. Linear growth rates for toroidal drift type modes are calculated for discharges in this class, without and with sheared rotation effects. For cases with fully developed barriers, the results with rotation are consistent with a picture in which the radial electric field generated in part by the steep pressure gradient causes local stabilization, and thus reduction of the local anomalous transport, which allows the steep pressure gradient to persist. If rotation is omitted from the calculation for these cases, or if rotation is included for cases without barriers or with partially developed barriers, the unstable region spreads into the steep pressure gradient region.
Shirai, Hiroshi; Kikuchi, Mitsuru; Takizuka, Tomonori; Fujita, Takaaki; Koide, Yoshihiko; Rewoldt, G.*; Mikkelsen, D. R.*; Budny, R.*; Tang, W. M.*; Kishimoto, Yasuaki; et al.
Fusion Energy 1998, 2, p.405 - 412, 1999/00
no abstracts in English
Shirai, Hiroshi; Kikuchi, Mitsuru; Takizuka, Tomonori; Fujita, Takaaki; Koide, Yoshihiko; Rewoldt, G.*; Mikkelsen, D. R.*; Budny, R.*; Tang, W. M.*; Kishimoto, Yasuaki; et al.
Nuclear Fusion, 39(11Y), p.1713 - 1722, 1999/00
Times Cited Count:68 Percentile:87.07(Physics, Fluids & Plasmas)no abstracts in English
Dnni, A.*; Kitazawa, Hideaki*; Fischer, P.*; Tang, J.*; Kogi, M.*; Endo, Yasuo*; Morii, Yukio
Journal of Physics; Condensed Matter, 7, p.1663 - 1678, 1995/00
Times Cited Count:32 Percentile:83.46(Physics, Condensed Matter)no abstracts in English
Koga, J. K.; Chen, L.-M.; Kotaki, Hideyuki; Nakajima, Kazuhisa; Bulanov, S. V.; Tajima, Toshiki; Gu, Y. Q.*; Peng, H. S.*; Hua, J. F.*; An, W. M.*; et al.
no journal, ,
First experiments for electron acceleration with the laser-gas plasma interaction have been carried out with 30 fs, 100 TW relativistic Ti:Sapphier laser pulse into a long slit (1.2 10 mm) gas plasma. The 10 mm length plasma channel formed that was longer than 20 times the Rayleigh length. Plasma density was the key factor for this long channel stimulation under 100 TW laser pulse irradiation that was much higher than critical power for relativistic self-focusing. For the first time, channel characteristics such as laser bending, hosing and cavity formation were demonstrated experimentally. In case of long channel guiding, accelerated electron bunch was tightly collimated with low emmitance mm mrad and quasi-monoenergetic electron bunch ( 70 MeV) was obtained as well. Accelerated electron charge current with electron energy 1 MeV was 10 nC/shot which was highest value in laser accelerator, to our knowledge, and ascribed to the contribution of long plasma channel. These well controlled laser-driven acceleration is an important cornerstone of relativistic engineering.
Kameshima, Takashi; Kotaki, Hideyuki; Kando, Masaki; Daito, Izuru; Kawase, Keigo; Fukuda, Yuji; Chen, L. M.*; Homma, Takayuki; Kondo, Shuji; Esirkepov, T. Z.; et al.
no journal, ,
The acceleration method of laser plasma electron acceleration has very strong electric field, however, the acceleration length is veryshort. Hence, the energy gain of electron beams were confined to be approximately 100 MeV. Recently, this problem was solved by using discharge capillary. The feature of plasma was used that high dense plasma has low refractive index. Distributing plasma inside capillary as low dense plasma is in the center of capillary and high dense plasma is in the external side of capillary can make a laser pulse propaget inside capillary with initial focal spot size. Experiments with capillary were performed in China Academy of Engineering Physics (CAEP) and Japan Atomic Energy Agency (JAEA). We obtained the results of 4.4 J laser pulse optical guiding in 4 cm capillary and 0.56 GeV electron production in CAEP in 2006, and 1 J laser pulse optical guiding in 4 cm capillary and electron beams productions.