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Journal Articles

Evaluation and mitigation of reactive ion etching-induced damage in AlGaN/GaN MOS structures fabricated by low-power inductively coupled plasma

Nozaki, Mikito*; Terashima, Daiki*; Yoshigoe, Akitaka; Hosoi, Takuji*; Shimura, Takayoshi*; Watanabe, Heiji*

Japanese Journal of Applied Physics, 59(SM), p.SMMA07_1 - SMMA07_7, 2020/07

 Times Cited Count:0 Percentile:0(Physics, Applied)

AlGaN/GaN metal-oxide-semiconductor (MOS) structures were fabricated by low-power inductively coupled plasma reactive ion etching and chemical vapor deposition of SiO$$_{2}$$ dielectrics on the etched surfaces, and they were systematically investigated by physical and electrical characterizations in an effort to develop a low-damage recessed gate process. The comprehensive research demonstrates the significant advantages of the proposed low-damage recessed gate process for fabricating next-generation AlGaN/GaN MOS-HFET devices.

Journal Articles

SiO$$_{2}$$/AlON stacked gate dielectrics for AlGaN/GaN MOS heterojunction field-effect transistors

Watanabe, Kenta*; Terashima, Daiki*; Nozaki, Mikito*; Yamada, Takahiro*; Nakazawa, Satoshi*; Ishida, Masahiro*; Anda, Yoshiharu*; Ueda, Tetsuzo*; Yoshigoe, Akitaka; Hosoi, Takuji*; et al.

Japanese Journal of Applied Physics, 57(6S3), p.06KA03_1 - 06KA03_6, 2018/06

 Times Cited Count:10 Percentile:48.92(Physics, Applied)

The advantage of SiO$$_{2}$$/AlON stacked gate dielectrics over SiO$$_{2}$$, AlON and Al$$_{2}$$O$$_{3}$$ single dielectric layers was demonstrated. Our systematic research revealed that the optimized stacked structure with 3.3-nm-thick AlON interlayer is beneficial in terms of superior interface quality, reduced gate leakage current and C-V hysteresis for next-generation high frequency and high power AlGaN/GaN MOS-HFETs.

Journal Articles

Europium binding to humic substances extracted from deep underground sedimentary groundwater studied by time-resolved laser fluorescence spectroscopy

Saito, Takumi*; Aoyagi, Noboru; Terashima, Motoki

Journal of Nuclear Science and Technology, 54(4), p.444 - 451, 2017/04

 Times Cited Count:4 Percentile:39.36(Nuclear Science & Technology)

Humic substances (HSs) are ubiquitous in various environments including deep underground and play an important role in the speciation and mobility of radionuclides. The binding of Eu$$^{3+}$$, a chemical homologue of trivalent actinide ions, to HSs isolated from sedimentary groundwater at -250 m below the surface was studied by time-resolved laser fluorescence spectroscopy combined with parallel factor analysis (PARAFAC) as a function of pH and salt concentration. PARAFAC modeling reveals the presence of multiple factors that corresponds to different Eu$$^{3+}$$ species. These factors resemble those observed for Eu$$^{3+}$$ binding to HSs from surface environments; however, detailed comparison shows that there are some particularities in Eu$$^{3+}$$ binding to the deep groundwater HSs. The distribution coefficients ($$K_{rm d}$$) of Eu$$^{3+}$$ binding to the HSs calculated from the PARAFAC modeling exhibits a rather strong salt effect. At 0.01 M NaClO$$_{4}$$ the $$K_{rm d}$$ values are relatively large and comparable to those to the surface HSs; they are decreaed at 0.1 M NaClO$$_{4}$$ by more than an order of the magnitude. The $$K_{rm d}$$ values are larger for humic acid fraction of the deep underground HSs than fulvic acid over the entire range of pH and salt concentration investigated in this study.

Journal Articles

X-ray absorption spectroscopy in the heavy Fermion compound $$alpha$$-YbAlB$$_4$$ at high magnetic fields

Terashima, Taku*; Matsuda, Yasuhiro*; Kuga, Kentaro*; Suzuki, Shintaro*; Matsumoto, Yosuke*; Nakatsuji, Satoru*; Kondo, Akihiro*; Kindo, Koichi*; Kawamura, Naomi*; Mizumaki, Masaichiro*; et al.

Journal of the Physical Society of Japan, 84(11), p.114715_1 - 114715_4, 2015/11

 Times Cited Count:4 Percentile:35.8(Physics, Multidisciplinary)

Journal Articles

Physicochemical and ion-binding properties of highly aliphatic humic substances extracted from deep sedimentary groundwater

Saito, Takumi; Terashima, Motoki; Aoyagi, Noboru; Nagao, Seiya*; Fujitake, Nobuhide*; Onuki, Toshihiko

Environmental Science; Processes & Impacts, 17(8), p.1386 - 1395, 2015/08

 Times Cited Count:8 Percentile:30.42(Chemistry, Analytical)

The deep groundwater HSs were different from surface HSs, having high aliphaticities, sulfur contents, and small molecular sizes. The amounts of their acidic functional groups were comparable to or slightly larger than those of surface HSs; however, the magnitude of Cu$$^{2+}$$ binding to the deep groundwater HSs was smaller. The NICA-Donnan model attributed this to the binding of Cu$$^{2+}$$ to chemically homogeneous carboxylic-type sites via mono-dentate coordination at relatively low pH. The binding mode tended to shift to multi-dentate coordination with carboxylic-type and probably more heterogeneous alcoholic hydroxide-type groups at higher pH. This study shows the particularity of the deep groundwater HSs in terms of their physicochemical and ion-binding properties, compared with surface HSs.

Journal Articles

Synchrotron X-ray spectroscopy study on the valence state and magnetization in $$alpha$$-YbAl$$_{1-x}$$Fe$$_x$$B$$_4$$ ($$x=0.115$$) at low temperatures and high magnetic fields

Terashima, Taku*; Matsuda, Yasuhiro*; Kuga, Kentaro*; Suzuki, Shintaro*; Matsumoto, Yosuke*; Nakatsuji, Satoru*; Kondo, Akihiro*; Kindo, Koichi*; Kawamura, Naomi*; Mizumaki, Masaichiro*; et al.

Journal of Physics; Conference Series, 592(1), p.012020_1 - 012020_6, 2015/03

 Times Cited Count:1 Percentile:43.85

Valence fluctuation phenomena in rare-earth intermetallic compounds have attracted attention because the quantum criticality of the valence transition has been proposed theoretically. Recently, it was found that $$beta$$-YbAlB$$_4$$ shows quantum criticality without tuning and has a strong mixed-valence state. In this study, we measured the magnetization curve and X-ray magnetoabsorption in $$alpha$$-YbAl$$_{1-x}$$Fe$$_x$$B$$_4$$ ($$x=0.115$$), which is a locally isostructural polymorph of $$beta$$-YbAlB$$_4$$. The magnetization and X-ray experiments were performed in fields up to 55 and 40 T, respectively. A small increase in the Yb valence was observed at fields where the magnetization curve exhibited a change in slope.

Oral presentation

Current status of the HIBMC, providing particle beam radiation therapy for more than 2,600 patients, and the prospects of laser-driven proton radiotherapy

Murakami, Masao*; Demizu, Yusuke*; Niwa, Yasue*; Nagayama, Shinichi*; Maeda, Takuya*; Baba, Masashi*; Miyawaki, Daisuke*; Terashima, Kazuki*; Arimura, Takeshi*; Mima, Masayuki*; et al.

no journal, , 

Oral presentation

Oral presentation

Effect of humic substances on the sorption and diffusion of Eu(III) in sedimentary rock

Terashima, Motoki; Tachi, Yukio; Saito, Takumi*; Iijima, Kazuki; Shimoda, Satoko*; Nakazawa, Toshiyuki*; Yoshikawa, Hideki

no journal, , 

no abstracts in English

Oral presentation

Investigation for colloids in the groundwater of Horonobe URL, 1; Characterization of colloids in the groundwater by using ultra filtration

Amano, Yuki; Amamiya, Hiroki; Murakami, Hiroaki; Iwatsuki, Teruki; Terashima, Motoki; Mizuno, Takashi; Kirishima, Akira*; Kuno, Atsushi*; Sasaki, Takayuki*; Kubota, Takumi*; et al.

no journal, , 

no abstracts in English

Oral presentation

Method for developing NICA-Donnan model parameters of groundwater humic substances

Terashima, Motoki; Saito, Takumi*; Iijima, Kazuki; Yoshikawa, Hideki

no journal, , 

no abstracts in English

Oral presentation

Assessing the effect of humic substances on migration of radionuclides in geological disposal system

Terashima, Motoki; Saito, Takumi*; Okazaki, Mitsuhiro*; Tachi, Yukio; Iijima, Kazuki

no journal, , 

no abstracts in English

Oral presentation

Metal ion complexation to deep groundwater humic substances

Saito, Takumi; Terashima, Motoki

no journal, , 

no abstracts in English

Oral presentation

Electrochemical study on the redox properties of humic substances from deep sedimentary groundwater

Saito, Takumi; Terashima, Motoki; Onuki, Toshihiko

no journal, , 

Redox properties of humic substances extracted from deep sedimentary groundwater was investigated by cyclic voltammetry and bulk electrolysis with a mediator organic molecule. Reversible current-potential curves were observed with the mediator, although electrode reaction of humic substances are slow in general. The redox capacities of various humic substances exhibited positive correlation with their aromaticity; those of deep groundwater humic substances were appreciably smaller than those of surface humic substances.

Oral presentation

Loading effect on Eu(III) binding to groundwater humic acid; Application of NICA-Donnan model

Terashima, Motoki; Saito, Takumi; Ishii, Tomoko*; Akagi, Yosuke*; Tachi, Yukio

no journal, , 

no abstracts in English

Oral presentation

Ion-binding properties of humic substance in deep sedimentary groundwater

Saito, Takumi*; Terashima, Motoki

no journal, , 

Humic substances (HSs) are ubiquitous in various environments and play an important role for the fate of pollutants. Deep underground environment is not an exception, although physicochemical and ion-binding properties of HSs there are largely unknown due to difficulties of their extraction. Based on limited studies on deep underground HSs, it has been recognized that they are distinctive from their counterparts in surface or shallow sub-surface environments. Thus, we have been studying humic and fulvic acids extracted from sedimentary groundwater at -250 m below ground surface at the Horonobe underground research laboratory, JAEA, including their chemical compositions, size distributions, spectroscopic properties, and ion bindings. The aim of this talk is to demonstrate similarities and differences between the Horonobe HSs and surface HSs.

Oral presentation

Complexation of trace Eu with humic acid isolated from deep groundwater in the Horonobe underground research laboratory site, Japan

Terashima, Motoki; Saito, Takumi*; Ishii, Tomoko*; Ito, Miki*; Akagi, Yosuke*; Tachi, Yukio

no journal, , 

no abstracts in English

Oral presentation

Characterization and determination of thermodynamic quantities of humic acid dissolved in deep groundwater at Horonobe, Hokkaido, Japan

Kimuro, Shingo*; Kirishima, Akira*; Akiyama, Daisuke*; Sato, Nobuaki*; Nagao, Seiya*; Saito, Takumi*; Amano, Yuki; Miyakawa, Kazuya; Terashima, Motoki

no journal, , 

no abstracts in English

Oral presentation

Loading effect on Eu(III) binding ability of humic acid isolated from deep sedimentary groundwater

Terashima, Motoki; Saito, Takumi*; Ito, Miki*; Akagi, Yosuke*; Tachi, Yukio

no journal, , 

no abstracts in English

Oral presentation

Influence of deposition power and temperature on SiO$$_{2}$$/AlGaN interface property deposited by PECVD

Terashima, Daiki*; Watanabe, Kenta*; Yamada, Takahiro*; Nozaki, Mikito*; Shih, H.*; Nakazawa, Satoshi*; Anda, Yoshiharu*; Ueda, Tetsuzo*; Yoshigoe, Akitaka; Hosoi, Takuji*; et al.

no journal, , 

Impact of input power and substrate temperature of SiO$$_{2}$$ deposition by plasma-enhanced CVD on SiO$$_{2}$$/AlGaN interface was investigated by means of electrical characterization of MOS capacitors. Synchrotron radiation photoemission spectroscopy revealed that Ga oxide component on AlGaN surface increases with increasing input power of PECVD. MOS capacitors with SiO$$_{2}$$ gate insulator deposited at low input power shows relatively better SiO$$_{2}$$/AlGaN interface quality, despite degraded interface quality for the sample with SiO$$_{2}$$ deposited at high input power. These results suggest that AlGaN surface oxidation during oxide deposition should be controlled to obtain good interface property.

26 (Records 1-20 displayed on this page)