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論文

Strengthening characteristics of CoCrNi alloys with different stacking fault energies

Peng, S. Y.*; Gong, W.; Tian, Y. Z.*; Harjo, S.; 他5名*

International Journal of Plasticity, 191, p.104401_1 - 104401_15, 2025/08

 被引用回数:22 パーセンタイル:98.02(Engineering, Mechanical)

Quantifying the contributions of various strengthening mechanisms is essential for manipulating these mechanisms and designing novel alloys. Although CoCrNi alloys demonstrate exceptional mechanical properties, their strengthening characteristics remain to be investigated. In this work, we conducted in situ neutron diffraction tensile tests and characterized deformation microstructures for CoCrNi alloys with different stacking fault energies (SFEs). The dislocation strengthening characteristics and the role of planar faults were systematically investigated. A reduction in SFE restricts cross slip, thereby increasing the dislocation multiplication rate while decreasing the dislocation strengthening coefficient $$alpha$$. Additionally, a lower SFE facilitates the simultaneous activation of dislocations and planar faults, with dislocation strengthening consistently playing a dominant role. This work quantifies reasonable $$alpha$$ values for CoCrNi alloys and identifies cross slip as a critical factor potentially influencing $$alpha$$ value in face-centered cubic (FCC) alloys.

論文

Spin density wave and van Hove singularity in the kagome metal CeTi$$_3$$Bi$$_4$$

Park, P.*; Ortiz, B. R.*; Spargue, M.*; Sakuya, A. P.*; Chen, S. A.*; Frontzek, M. D.*; Tian, W.*; Sibille, R.*; Mazzone, D. G.*; 田端 千紘; et al.

Nature Communications (Internet), 16, p.4384_1 - 4384_9, 2025/05

 被引用回数:20 パーセンタイル:97.69(Multidisciplinary Sciences)

Kagome metals with van Hove singularities (VHSs) near the Fermi level can host intriguing quantum phenomena, including chiral loop currents, electronic nematicity, and unconventional superconductivity. However, unconventional magnetic states driven by VHSs, such as spin-density waves (SDWs), have yet to be observed experimentally in kagome metals. Here, we present a comprehensive investigation of the magnetic and electronic structure of the layered kagome metal CeTi$$_3$$Bi$$_4$$, where the Ti kagome electronic structure interacts with a magnetic sublattice of Ce$$^{3+}$$ $$J_{rm eff}$$ = 1/2 moments. Our findings establish the rare-earth Kagome metals LnTi3Bi4 as a model platform where characteristic electronic structure of the kagome lattice plays a pivotal role in magnetic order.

論文

Unusual low-temperature ductility increase mediated by dislocations alone

Naeem, M.*; Ma, Y.*; Tian, J.*; Kong, H.*; Romero-Resendiz, L.*; Fan, Z.*; Jiang, F.*; Gong, W.; Harjo, S.; Wu, Z.*; et al.

Materials Science & Engineering A, 924, p.147819_1 - 147819_10, 2025/02

 被引用回数:7 パーセンタイル:86.13(Nanoscience & Nanotechnology)

Face-centered cubic (fcc) medium-/high-entropy alloys (M/HEAs) typically enhance strength and ductility at cryogenic temperatures via stacking faults, twinning, or martensitic transformation. However, in-situ neutron diffraction on VCoNi MEA at 15 K reveals that strain hardening is driven solely by rapid dislocation accumulation, without these mechanisms. This results in increased yield strength, strain hardening, and fracture strain. The behavior, explained by the Orowan equation, challenges conventional views on cryogenic strengthening in fcc M/HEAs and highlights the role of dislocation-mediated plasticity at low temperatures.

論文

Uniaxial pressure effect on the magnetic ordered moment and transition temperatures in BaFe$$_{2-x}$$T$$_{x}$$As$$_{2}$$ ($$T$$ = Co,Ni)

Tam, D. M.*; Song, Y.*; Man, H.*; Cheung, S. C.*; Yin, Z.*; Lu, X.*; Wang, W.*; Frandsen, B. A.*; Liu, L.*; Gong, Z.*; et al.

Physical Review B, 95(6), p.060505_1 - 060505_6, 2017/02

 被引用回数:24 パーセンタイル:65.71(Materials Science, Multidisciplinary)

We use neutron diffraction and muon spin relaxation to study the effect of in-plane uniaxial pressure on the antiferromagnetic (AF) orthorhombic phase in BaFe$$_{2-x}$$T$$_{x}$$As$$_{2}$$ and its Co- and Ni-substituted members near optimal superconductivity. In the low-temperature AF ordered state, uniaxial pressure necessary to detwin the orthorhombic crystals also increases the magnetic ordered moment, reaching an 11% increase under 40 MPa for BaFe$$_{1.9}$$Co$$_{0.1}$$As$$_2$$, and a 15% increase for BaFe$$_{1.915}$$Ni$$_{0.085}$$As$$_2$$. We also observe an increase of the AF ordering temperature ($$T_N$$) of about 0.25 K/MPa in all compounds, consistent with density functional theory calculations that reveal better Fermi surface nesting for itinerant electrons under uniaxial pressure. The doping dependence of the magnetic ordered moment is captured by combining dynamical mean field theory with density functional theory, suggesting that the pressure-induced moment increase near optimal superconductivity is closely related to quantum fluctuations and the nearby electronic nematic phase.

論文

Local structure of LiNiO$$_2$$ studied by neutron diffraction

Chung, J.-H.*; Proffen, T.*; 社本 真一; Ghorayeb, A. M.*; Croguennec, L.*; Tian, W.*; Sales, B. C.*; Jin, R.*; Mandrus, D.*; 江上 毅*

Physical Review B, 71(6), p.064410_1 - 064410_11, 2005/02

 被引用回数:98 パーセンタイル:92.29(Materials Science, Multidisciplinary)

LiNiO$$_2$$は、これまでS=1/2の三角格子系としてよく研究されてきたが、そのスピン相関に関してはまだよくわかっていない。そこではヤーンテラー効果による軌道状態も問題となるが、これまで長距離の格子歪みは見つかっていない。今回これまで行われたことのない幅広い実空間での結晶PDF解析を行うことで、短距離から長距離までさまざまな格子歪みが見つかった。この結果は10nmのドメインを持つナノ構造軌道秩序モデルで説明される。この局所的な軌道秩序状態が基となって、複雑な磁気特性が現れていると思われる。

口頭

Spin density wave and van Hove singularity in the kagome metal CeTi$$_3$$Bi$$_4$$

Park, P.*; Ortiz, B. R.*; Spargue, M.*; Sakuya, A. P.*; Chen, S. A.*; Frontzek, M. D.*; Tian, W.*; Sibille, R.*; Mazzone, D. G.*; 田端 千紘; et al.

no journal, , 

The electronic band structure of kagome metals is the basis for a growing number of intriguing physical phenomena. Here we focus on the case of Ce$$^{3+}$$ pseudospin-1/2 local moments coupled by a Ti-derived Kagome electronic structure in the material CeTi$$_3$$Bi$$_4$$. Neutron scattering measurements under applied magnetic fields reveal that CeTi$$_3$$Bi$$_4$$ exhibits a rich temperature-field phase diagram where an incommensurate spin-density wave (SDW) ground state coexists with a commensurate magnetic modulation. Remarkably, ARPES and DFT investigations reveal that the van Hove singularities (VHSs) of the kagome bands near the Fermi level are nested by vectors which coincide with the observed magnetic propagation vectors. This correspondence suggests a VHS-driven mechanism for SDW formation and provides an interesting counterpart to the charge density waves observed in other kagome metals. Our results establish that CeTi$$_3$$Bi$$_4$$ offers a rare opportunity to explore intertwined kagome Fermiology and quantum-magnetic spin textures.

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