及川 健一; Su, Y.; 鬼柳 亮嗣; 川崎 卓郎; 篠原 武尚; 甲斐 哲也; 廣井 孝介; Harjo, S.; Parker, J. D.*; 松本 吉弘*; et al.
Physica B; Condensed Matter, 551, p.436 - 442, 2018/12
We are promoting for practical product observation by the energy-resolved neutron imaging method using high-intensity pulsed neutrons at J-PARC, under the Photon and Quantum Basic Research Coordinated Development Program from the Ministry of Education, Culture, Sports, Science and Technology, Japan. Bragg edge imaging, one of the energy-resolved neutron imaging methods for visualizing material properties, was applied to feasibility study of the temperature distribution of copper rod, complementary study of the texture and strain distribution of bent steel plates using neutron diffraction and EBSD, and so on. Outline of results obtained by these imaging experiments will be presented.
徐 平光; Harjo, S.; 小島 真由美*; 鈴木 裕士; 伊藤 崇芳*; Gong, W.; Vogel, S. C.*; 井上 純哉*; 友田 陽*; 相澤 一也; et al.
Journal of Applied Crystallography, 51(3), p.746 - 760, 2018/06
Neutron diffraction texture measurements provide bulk textures with excellent grain statistics even for large grained materials, together with the crystallographic parameters and microstructure information such as phase fractions, coherent crystallite size, root mean square microstrain, macroscopic/intergranular stress/strain. The procedure for high stereographic resolution texture and residual stress evaluation was established at the TAKUMI engineering materials diffractometer. The pole figure evaluation of a limestone standard sample with a trigonal crystal structure suggested that the obtained precision for texture measurement is comparable with the oversea well-established neutron beam lines utilized for texture measurements. A high strength martensite-austenite multilayered steel was employed for further verification of the reliability of simultaneous Rietveld analysis of multiphase textures and macro stress tensors. By using a geometric mean micro-mechanical model, the macro stress tensor analysis with a plane stress assumption showed a RD-TD in-plane compressive stress (about -330 MPa) in martensite layers and a RD-TD in-plane tensile stress (about 320 MPa) in austenite layers. The phase stress partitioning was ascribed to the additive effect of volume expansion during martensite transformation and the linear contraction misfit during water quenching.
佐藤 成男*; 黒田 あす美*; 佐藤 こずえ*; 熊谷 正芳*; Harjo, S.; 友田 陽*; 齋藤 洋一*; 轟 秀和*; 小貫 祐介*; 鈴木 茂*
鉄と鋼, 104(4), p.201 - 207, 2018/00
To investigate the characteristics of dislocation evolution in ferritic and austenitic stainless steels under tensile deformation, neutron diffraction line-profile analysis was carried out. The austenitic steel exhibited higher work hardening than the ferritic steel. The difference in the work hardening ability between the two steels was explained with the dislocation density estimated by the line-profile analysis. The higher dislocation density of the austenitic steel would originate from its lower stacking fault energy. Dislocation arrangement parameters indicated that the strength of interaction between dislocations in the austenitic steel was stronger than that in the ferritic steel.
友田 陽*; 関戸 信彰*; 徐 平光; 川崎 卓郎; Harjo, S.; 田中 雅彦*; 篠原 武尚; Su, Y.; 谷山 明*
鉄と鋼, 103(10), p.570 - 578, 2017/10
Various methods were employed to measure the austenite volume fraction in a 1.5Mn-1.5Si-0.2C steel. It has been confirmed that the volume fractions determined by transmission electron microscopy, scanning electron microscopy/electron back scatter diffraction, X-ray diffraction and neutron diffraction exhibit a general trend to become larger in this order, although the values obtained by X-ray and neutron diffraction are similar in the present steel because austenite is relatively stable. The austenite volume fractions determined by diffraction methods have been found to be affected by the measuring specimen direction, i.e., texture, even by applying the conventional correcting procedure. To avoid this influence, it is recommended to measure both of volume fraction and texture simultaneously using neutron diffraction. Although synchrotron X-ray shows higher angle resolution, its small incident beam size brings poor statistic reliability. The influence of texture cannot be avoided for transmission Bragg edge measurement, either, which must be overcome to realize 2D or 3D volume fraction mapping.
Harjo, S.; 川崎 卓郎; 友田 陽*; Gong, W.*; 相澤 一也; Tichy, G.*; Shi, Z.*; Ungar, T.*
Metallurgical and Materials Transactions A, 48(9), p.4080 - 4092, 2017/09
neutron diffraction during tensile deformation of lath martensite steel containing 0.22 mass% of carbon, is performed using TAKUMI of J-PARC. The diffraction peaks at plastically deformed states exhibit asymmetries as the reflection of redistributions of the stress and dislocation densities/arrangements in lath-packets where the dislocation glides are favorable (soft packet) and unfavorable (hard packet). The dislocation density is as high as 10 m at the as-quenched state, and then during tensile straining, the load and the dislocation density become different between the two lath-packets. The dislocation character and arrangement vary also in the hard packet, but hardly change in the soft packet. The hard packet plays an important role in the high work hardening in martensite, which could be understood by taking into account not only the increase of the dislocation density but also the change in dislocation arrangement.
Harjo, S.; 川崎 卓郎; 友田 陽*; Gong, W.
Materials Science Forum, 905, p.46 - 51, 2017/08
To understand the strengthening mechanism of a metallic material with high dislocation density, the plastic deformation behavior of lath martensite was studied by means of in situ neutron diffraction measurements during tensile deformations using a 22SiMn2TiB steel and a Fe-18Ni alloy. The characteristics of dislocation were analyzed and were discussed with the relation of stress-strain curves. The dislocation densities induced by martensitic transformation during heat-treatment in both materials were found to be originally as high as 10 m order, and subsequently to increase slightly by the tensile deformation. The parameter M value which displays the dislocation arrangement dropped drastically at the beginning of plastic deformation in both materials, indicating that the random arrangement became more like a dipole arrangement.
友田 陽*; 佐藤 成男*; Uchida, M.*; 徐 平光; Harjo, S.; Gong, W.; 川崎 卓郎
Materials Science Forum, 905, p.25 - 30, 2017/08
Microstructural change during hot compressive deformation at 700 C followed by isothermal annealing for a Fe-32Ni austnitic alloy was monitored using neutron diffraction. The evolution of deformation texture with 40% compression and its change to recrystallization texture during isothermal annealing were presented by inverse pole figures for the axial and radial directions. The change in dislocation density was tracked using the convolutional muli-profile whole profile fitting method. To obtain the fitting results with good statistics, at least 60 s time-slicing for the event-mode recorded data was needed. The average dislocation density in 60 s after hot compression was determined to be 2.8 10 m that decreased with increasing of annealing time.
Su, Y.; 及川 健一; 篠原 武尚; 甲斐 哲也; 廣井 孝介; Harjo, S.; 川崎 卓郎; Gong, W.; Zhang, S. Y.*; Parker, J. D.*; et al.
Physics Procedia, 88, p.42 - 49, 2017/06
The influences of bending deformation and subsequent subzero treatment on the martensite transformation behaviors in a metastable austenitic alloy Fe-25Ni-0.4C were investigated by the time-of-flight (TOF) neutron Bragg-edge transmission (BET) imaging method. Two-dimensional (2D) maps of martensite phase volume fractions and texture variations due to residual stress and lowering the temperature of the bent samples before and after subzero treatment were obtained by Bragg-edge spectral analysis. The obtained phase volume fractions were quantitatively compared with those determined by neutron diffraction.
徐 平光; 友田 陽*; 新垣 優; Harjo, S.; 末吉 仁*
Materials Characterization, 127, p.104 - 110, 2017/05
The volume fractions of austenite () in TRIP steels were evaluated using time-of-flight neutron diffraction through four methods. They include the analysis method with random texture assumption, the correction method of () peak intensities, the Rietveld refinement method using the summed spectrum without distinguishing the specimen orientations, and the combined Rietveld analysis method for textures and volume fractions. It was found that for a near-random spectrum obtained by the summation of all the measured neutron spectra, the Rietveld refinement provided a satisfactory precision for . Moreover, the precision was further improved through the combined Rietveld analysis method. If the texture measurement is unavailable, it is suggested to measure the neutron spectrum along the transverse direction, and to analyze the using conventional correction method of () peak intensities. It was also confirmed that the increment of evidently improved the combinations of tensile strength and uniform elongation (TSUEl).
友田 陽*; Gong, W.*; Harjo, S.; 篠崎 智也*
Scripta Materialia, 133, p.79 - 82, 2017/05
The microstructure evolution during reverse transformation of a Cr-Ni-Mo steel consisting of tempered lath martensite and Cr carbide was examined using neutron diffraction at high temperatures. The microstructural change from a reversed coarse-grained structure to a fine-grained polygonal structure by further annealing was monitored through a decrease in the diffraction intensity caused by primary extinction and the full width at half maximum. This result is different from that for a bainite steel, showing good coincidence with the observations using electron back scatter diffraction.
福田 晃二郎*; 友田 陽*; Harjo, S.; Gong, W.*; Woo, W.*; Seong, B. S.*; 桑原 義孝*; 生田 文昭*
Materials Science and Technology, 33(2), p.172 - 180, 2017/01
Residual stress distribution in a carbon steel component with collar manufactured by partial diameter-enlarging (PDE) process was evaluated using the angular dispersion and time-of-flight neutron diffraction methods in the interior and X-ray diffraction method at the surface of the collar. The residual stresses in the PDE specimen were smaller compared with those of a specimen with the similar shape and dimension made by a simple compression (SC) process. The hoop residual stress varied from -98 to 2 MPa around the circumference at the surface of the collar in the PDE specimen, whereas it was nearly constant in the SC one. The residual stresses in the central region of the both specimens were nearly in a hydrostatic compressive stress condition.
Ungr, T.*; Harjo, S.; 川崎 卓郎; 友田 陽*; Ribrik, G.*; Shi, Z.*
Metallurgical and Materials Transactions A, 48(1), p.159 - 167, 2017/01
Based on high-resolution neutron diffraction experiments we will show that in lath martensite steels the initially homogeneous dislocation structure is disrupted by plastic deformation, to produce a composite on the length scale of martensite lath packets. The diffraction patterns of plastically strained martensitic steel reveal characteristically asymmetric peak profiles in the same way as has been observed in materials with heterogeneous dislocation structures. Lath packets oriented favorably or unfavorably for dislocation glide become soft or hard. The lath packet type develops by work softening or work hardening in which the dislocation density becomes smaller or larger compared to the initial average one. The decomposition into soft and hard lath packets is accompanied by load redistribution between the two lath packet types. The composite behavior of plastically deformed lath martensite opens a new way to understand the elastic-plastic response in this class of materials.
友田 陽*; 佐藤 成男*; Harjo, S.
鉄と鋼, 103(2), p.73 - 85, 2017/01
Several methods on single-peak and multi-peaks line-profile analyses for neutron or X-ray diffraction are critically reviewed. Compared with deconvolutional methods like the classical Williamson-Hall method and the modified Warren-Averbach method combined with the modified Williamson-Hall plot, a recently developed convolutional multiple whole profile (CMWP) fitting method enables to provide the density, arrangement and character of dislocation and crystallite size reasonably. Elasto-plastic deformation behavior in austenite, ferrite, martensite and two-phase steels are studied using such profile analyses, revealing that flow stress is dependent not only on dislocation density but also its arrangement. In particular, in situ neutron diffraction with the CMWP analysis is powerful to monitor microstructural changes during deformation and/or heat treatment.
及川 健一; Su, Y.; 友田 陽*; 川崎 卓郎; 篠原 武尚; 甲斐 哲也; 廣井 孝介; Zhang, S.*; Parker, J. D.*; 佐藤 博隆*; et al.
Physics Procedia, 88, p.34 - 41, 2017/00
Su, Y.; 及川 健一; Harjo, S.; 篠原 武尚; 甲斐 哲也; 原田 正英; 廣井 孝介; Zhang, S.*; Parker, J. D.*; 佐藤 博隆*; et al.
Materials Science and Engineering A, 675, p.19 - 31, 2016/10
Neutron Bragg-edge transmission imaging makes it possible to quantitatively visualize the two-dimensional distribution of microstructure within a sample. In order to examine its application to engineering products, time-of-flight Bragg-edge transmission imaging experiments using a pulsed neutron source were performed for plastically bent plates composed of a ferritic steel and a duplex stainless steel. The non-homogeneous microstructure distributions, such as texture, crystalline size, phase volume fraction and residual elastic strain, were evaluated for the cross sections of the bent plates. The obtained results were compared with those by neutron diffraction and electron back scatter diffraction, showing that the Bragg-edge transmission imaging is powerful for engineering use.
Su, Y.; 及川 健一; 川崎 卓郎; 甲斐 哲也; 塩田 佳徳*; 佐藤 博隆*; 篠原 武尚; 友田 陽*; 原田 正英; 鬼柳 亮嗣; et al.
JPS Conference Proceedings (Internet), 8, p.031015_1 - 031015_5, 2015/09
川崎 卓郎; Harjo, S.; Gong, W.; 相澤 一也; 岩橋 孝明; Shi, Z.*; Li, J.*; 友田 陽*; Ungr, T.*
JPS Conference Proceedings (Internet), 8, p.031009_1 - 031009_5, 2015/09
徐 平光; Harjo, S.; 伊藤 崇芳*; 森井 幸生*; Gong, W.; 鈴木 裕士; 秋田 貢一; 鈴木 徹也*; 友田 陽; Lutterotti, L.*
JPS Conference Proceedings (Internet), 8, p.031022_1 - 031022_6, 2015/09
The current status of bulk texture measurements both using angle dispersive neutron diffraction and time-of-flight neutron diffraction at JAEA was briefly reviewed, then the effect of sample orientation coverage in the time-of-flight neutron diffraction on the reliability of reconstructed pole figure on the reliability of reconstructed pole figure was simply compared after the simultaneous Rietveld texture analysis. The similar texture results obtained at different orientation coverage levels suggests that it is possible to reduce the sample rotation times reasonably during the bulk texture measurement.
Gong, W.; 友田 陽*; Harjo, S.; Su, Y.; 相澤 一也
Acta Materialia, 85, p.243 - 249, 2015/02
石橋 寿啓*; 友田 陽*; 菅谷 聡*; 豊川 弘之*; 平出 哲也; 堀田 善治*; 鈴木 裕士
Materials Transactions, 54(9), p.1562 - 1569, 2013/09
Equal Channel Angular Pressing(ECAP)法による99.99%銅の空孔密度,組織,粒界応力などのバルク平均された微視的構造パラメータを加速器利用の線誘起陽電子消滅分光(AIPAS)と中性子回折により調べた。AIPASで得られた消滅線ピークのドップラー広がりを示すSパラメータは最初のECAP処理で大きく増大し、その後の処理でわずかな減少が確認された。また、熱処理によって回復が見られたが、8サイクルのECAP処理試料の方が1サイクルのものよりも低温での回復が見られた。ECAP処理による組織や粒界の応力を中性子回折分析で求めた。熱処理を行いながら観測した中性子回折の半値幅と強度の変化から、8サイクルのECAP処理試料において再結晶化がより早く起こっていることがわかった。これらのバルク平均されたデータは結晶方位解析(SEM-EBSD)や機械的特性評価の結果と定性的に良い一致を示した。