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Morii, Shiori; Yomogida, Takumi; Asai, Shiho*; Ouchi, Kazuki; Oka, Toshitaka; Kitatsuji, Yoshihiro
KEK Proceedings 2023-2, p.132 - 137, 2023/11
New analytical method of a combination of laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) and isotope dilution mass spectrometry (IDMS) for quantification of Zr isotopes in a solid sample was investigated. Solid Zr-isotope reference was added to a simulated radioactive waste sample as a spike, then Zr isotope ratio was measured by LA-ICP-MS. As a result, we successfully quantify Zr isotopes in the simulated radioactive waste sample by new IDMS. There is a possibility that this new method can be applied for quantification of Zr-93 in difficult to dissolve radioactive wastes.
Morii, Shiori; Yomogida, Takumi; Asai, Shiho*; Ouchi, Kazuki; Oka, Toshitaka; Kitatsuji, Yoshihiro
Bunseki Kagaku, 72(10.11), p.441 - 448, 2023/10
Rapid analytical method for the determination of Zr-93 in radioactive wastes has been developed. Laser ablation (LA)-ICP-MS was applied to the analysis of Zr isotopes in simulated high-level radioactive waste (HLW). Sample preparation time was dramatically reduced by using a DGA resin as the adsorbent for Zr. Direct quantification of Zr isotopes in this resin sample was carried out by LA-ICP-MS. Laser settings were optimized to obtain a reliable isotope ratio of the sample by LA-ICP-MS. Quantification of Zr isotopes in the simulated HLW solution by isotope dilution mass spectrometry (IDMS) was examined. The amount of Zr-90 in the sample obtained by IDMS corresponded to a value calculated from the given concentration of Zr in the sample within uncertainty. Thus, this method can be applied for the quantification of Zr-93 in radioactive wastes.
Ouchi, Kazuki; Matsumura, Daiju; Tsuji, Takuya; Kobayashi, Toru; Otobe, Haruyoshi; Kitatsuji, Yoshihiro
RSC Advances (Internet), 13(24), p.16321 - 16326, 2023/05
Times Cited Count：0 Percentile：0(Chemistry, Multidisciplinary)We clarified the chemical state transformation of deposits following the reduction of uranyl ion (U
O
) from the results of electrochemical quartz crystal microbalance, impedance spectra and X-ray absorption fine structure measurements. We propose the following deposition mechanism: (1) U
is formed by the disproportionation of U
. (2) U forms U hydroxide deposits, and (3) finally, the hydroxide deposits transform into U oxide, generally having a larger electrical resistance than the former.
-edge to assess the U(V) electronic structure in FeUO
Yomogida, Takumi; Akiyama, Daisuke*; Ouchi, Kazuki; Kumagai, Yuta; Higashi, Kotaro*; Kitatsuji, Yoshihiro; Kirishima, Akira*; Kawamura, Naomi*; Takahashi, Yoshio*
Inorganic Chemistry, 61(50), p.20206 - 20210, 2022/12
Times Cited Count：2 Percentile：36.89(Chemistry, Inorganic & Nuclear)FeUO was studied to clarify the electronic structure of U(V) in a metal monouranate compound. We obtained the peak splitting of HERFD-XANES spectra utilizing high-energy-resolution fluorescence detection-X-ray absorption near edge structure (HERFD-XANES) spectroscopy at the U L-edge, which is a novel technique in the U(V) compounds. Theoretical calculations revealed that the peak splitting was caused by splitting the 6d orbital of U(V). Such distinctive electronic states are of major interest to researchers and engineers working in various fields, from fundamental physics to the nuclear industry and environmental sciences for actinide elements.
Cs discharge from a forested catchmentSakuma, Kazuyuki; Hayashi, Seiji*; Yoshimura, Kazuya; Kurikami, Hiroshi; Malins, A.; Funaki, Hironori; Tsuji, Hideki*; Kobayashi, Takamaru*; Kitamura, Akihiro; Iijima, Kazuki
Water Resources Research, 58(8), p.e2021WR031181_1 - e2021WR031181_16, 2022/08
Times Cited Count：2 Percentile：39.28(Environmental Sciences)Yomogida, Takumi; Ouchi, Kazuki; Oka, Toshitaka; Kitatsuji, Yoshihiro; Koma, Yoshikazu; Konno, Katsuhiro*
Scientific Reports (Internet), 12(1), p.7191_1 - 7191_10, 2022/05
Times Cited Count：4 Percentile：53.82(Multidisciplinary Sciences)Particles containing alpha (
) nuclides were identified from sediment in stagnant water at the torus room of the Fukushima Dai-ichi Nuclear Power Station (FDiNPS)'s Unit 2 reactor. Several uranium-bearing particles were identified by SEM observation. These particles contained Zr and other elements which constituted fuel cladding and structural materials. The 
U/
U isotope ratio in the solid fractions that included U particles was consistent with the nuclear fuel in the Unit 2 reactor, which indicated that the U particles had been derived from nuclear fuel. The particles with alpha-emitters detected by alpha track analysis were several tens to several hundred 
m in size. The EDX spectra showed that these particles mainly comprised iron, which indicated Pu, Am, and Cm were adsorbed on the Fe-baring particles. This study clarifies that the major morphologies of U and other -nuclides were differed in the sediment of stagnant water in the torus room of FDiNPS's Unit 2 reactor.
Ouchi, Kazuki; Tsukahara, Takehiko*; Brandt, A.*; Muto, Yuki*; Nabatame, Nozomi*; Kitatsuji, Yoshihiro
Analytical Sciences, 37(12), p.1789 - 1794, 2021/12
Times Cited Count：1 Percentile：6.71(Chemistry, Analytical)We attempted to scale down a separation process of uranium (U) using the microchip column loaded with anion exchange resin to develop safety and waste-reducing separation technique. The ideal separation performance of U was obtained by the properly design of a microchannel. The concentration of U in seawater as a real-world sample could be quantified with the prepared microchip column. It indicates that the microchip column is sufficiently practical. Compared to separation of U with a general column, the column size was successfully scaled down to 
1/5000.
Ouchi, Kazuki; Komatsu, Atsushi; Takao, Koichiro*; Kitatsuji, Yoshihiro; Watanabe, Masayuki
Chemistry Letters, 50(6), p.1169 - 1172, 2021/06
Times Cited Count：1 Percentile：6.77(Chemistry, Multidisciplinary)The electrochemical behavior of uranium (IV) tetrachloride in ionic liquid-DMF mixture was studied for first time in order to build a redox flow battery (RFB) using U as an electrode active material. We found a quasi-reversible U
/U
couple that could be applied to the anode reaction of the RFB.
Cs in water and phyto- and zooplankton in a reservoir affected by the Fukushima Daiichi Nuclear Power Plant AccidentTsuji, Hideki*; Nakagawa, Megumi*; Iijima, Kazuki; Funaki, Hironori; Yoshimura, Kazuya; Sakuma, Kazuyuki; Hayashi, Seiji*
Global Environmental Research (Internet), 24(2), p.115 - 127, 2021/06
Lake water, phytoplankton and zooplankton were sampled by a total of 12 quarterly surveys from August 2014 to May 2017 at a dam lake in the Fukushima nuclear disaster area, and variations of dissolved form of Cs and planktonic Cs were observed. Seasonal variations in dissolved Cs concentration with high in summer and low in winter were observed in the upstream, midstream and downstream areas of the lake, but no seasonal or site specific differences in planktonic Cs concentrations and dominant species were found. The amount of planktonic form of Cs in the water was less than 1.4% of the total Cs in the lake water, therefore the effect of plankton on the dynamics of Cs in the lake was minimal.
for modelling dissolved Cs concentrations in Fukushima river water; Case study of the upstream Ota RiverSakuma, Kazuyuki; Tsuji, Hideki*; Hayashi, Seiji*; Funaki, Hironori; Malins, A.; Yoshimura, Kazuya; Kurikami, Hiroshi; Kitamura, Akihiro; Iijima, Kazuki; Hosomi, Masaaki*
Journal of Environmental Radioactivity, 184-185, p.53 - 62, 2018/04
Times Cited Count：2 Percentile：7.2(Environmental Sciences)A study is presented on the applicability of the distribution coefficient () absorption/desorption model to simulate dissolved Cs concentrations in Fukushima river water. The simulation results were in good agreement with the observations on water and suspended sediment fluxes, and on particulate bound Cs concentrations under both ambient and high flow conditions. By contrast the measured concentrations of dissolved Cs in the river water were much harder to reproduce with the simulations. By tuning the values for large particles, it was possible to reproduce the mean dissolved Cs concentrations during base flow periods (observation: 0.32 Bq/L, simulation: 0.36 Bq/L). However neither the seasonal variability in the base flow dissolved Cs concentrations (0.14-0.53 Bq/L), nor the peaks in concentration that occurred during storms (0.18-0.88 Bq/L, mean: 0.55 Bq/L), could be reproduced with realistic simulation parameters.
Ouchi, Kazuki; Otobe, Haruyoshi; Kitatsuji, Yoshihiro; Yamamoto, Masahiro
ECS Transactions, 75(27), p.51 - 57, 2017/01
Times Cited Count：1 Percentile：38.46(Electrochemistry)We investigated the deposition of U(IV) following a valence change of U as electrodeposition using an electrochemical quartz crystal microbalance (EQCM). When measurements of the reduction of U(VI) in a weak acid solution were performed, deposits of U(IV) were observed on the electrode surface. From deposition rates, pH dependence of them, and oxidation potentials of deposits, we proposed the following deposition mechanism. The deposition is divided into the three phases; First, in the induction phase, U(IV) produced by the disproportionation forms U(IV) hydroxide nucleus. Next, in the growth phase, U(IV) deposits begin to grow. In this phase, the deposits catalyze the reduction of U(V) to U(IV), resulting an increase of the reduction current. Finally, in the transformation phase, U(IV) hydroxide species transform into U dioxide having more stable state.
Oe, Kazuhiro*; Attallah, M. F.*; Asai, Masato; Goto, Naoya*; Gupta, N. S.*; Haba, Hiromitsu*; Huang, M.*; Kanaya, Jumpei*; Kaneya, Yusuke*; Kasamatsu, Yoshitaka*; et al.
Journal of Radioanalytical and Nuclear Chemistry, 303(2), p.1317 - 1320, 2015/02
Times Cited Count：10 Percentile：64.63(Chemistry, Analytical)A new technique for continuous dissolution of nuclear reaction products transported by a gas-jet system was developed for superheavy element (SHE) chemistry. In this technique, a hydrophobic membrane is utilized to separate an aqueous phase from the gas phase. With this technique, the dissolution efficiencies of short-lived radionuclides of 
Mo and 
W were measured. Yields of more than 80% were observed for short-lived radionuclides at aqueous-phase flow rates of 0.1-0.4 mL/s. The gas flow-rate had no influence on the dissolution efficiency within the studied flow range of 1.0-2.0 L/min. These results show that this technique is applicable for on-line chemical studies of SHEs in the liquid phase.
Kuramitsu, Yasuhiro*; Nakanii, Nobuhiko*; Kondo, Kiminori; Sakawa, Yoichi*; Mori, Yoshitaka*; Miura, Eisuke*; Tsuji, Kazuki*; Kimura, Kazuya*; Fukumochi, Shuji*; Kashihara, Mamoru*; et al.
Physical Review E, 83(2), p.026401_1 - 026401_6, 2011/02
Times Cited Count：16 Percentile：65.74(Physics, Fluids & Plasmas)An energy distribution function of energetic particles in the universe or cosmic rays is well represented by a power-law spectrum, therefore, nonthermal acceleration is essential to understand the origin of cosmic rays. A possible candidate for the origin of cosmic rays is wakefield acceleration at relativistic astrophysical perpendicular shocks. Substituting an intensive laser pulse for the large amplitude light waves, we performed a model experiment of the shock environments in a laboratory plasma.
Kuramitsu, Yasuhiro*; Nakanii, Nobuhiko*; Kondo, Kiminori; Sakawa, Yoichi*; Mori, Yoshitaka*; Miura, Eisuke*; Tsuji, Kazuki*; Kimura, Kazuya*; Fukumochi, Shuji*; Kashihara, Mamoru*; et al.
Physics of Plasmas, 18(1), p.010701_1 - 010701_4, 2011/01
Times Cited Count：19 Percentile：62.41(Physics, Fluids & Plasmas)Substituting an intensive laser pulse for the large amplitude light waves, we performed a model experiment of the shock environments in a laboratory plasma. An intensive laser pulse was propagated in a plasma tube created by imploding a hollow polystyrene cylinder, as the large amplitude light waves propagated in the upstream plasma at an astrophysical shock. Nonthermal electrons were generated, and the energy distribution functions of the electrons have a power-law component with an index of 2.
Nakanii, Nobuhiko*; Kondo, Kiminori; Kuramitsu, Yasuhiro*; Mori, Yoshitaka*; Miura, Eisuke*; Tsuji, Kazuki*; Kimura, Kazuya*; Fukumochi, Shuji*; Kashihara, Mamoru*; Tanimoto, Tsuyoshi*; et al.
Applied Physics Letters, 93(8), p.081501_1 - 081501_3, 2008/08
Times Cited Count：4 Percentile：18.78(Physics, Applied)Energetic electrons were generated by the interaction of a high-intensity laser pulse with a plasma preformed from a hollow plastic cylinder via laser-driven implosion. The spectra of a comparatively high-density plasma had a bump around 10 MeV. Simple numerical calculations explained the spectra obtained in this experiment. This indicates that the plasma tube has sufficient potential to convert a Maxwellian spectrum to a comparatively narrow spectrum.
Nakanii, Nobuhiko*; Kondo, Kiminori; Yabuuchi, Toshinori*; Tsuji, Kazuki*; Tanaka, Kazuo*; Suzuki, Shinsuke*; Asaka, Takao*; Yanagida, Kenichi*; Hanaki, Hirofumi*; Kobayashi, Takashi*; et al.
Review of Scientific Instruments, 79(6), p.166102_1 - 066102_3, 2008/06
An imaging plate has been used as a useful detector of energetic electrons in laser electron acceleration and laser fusion studies. The absolute sensitivity of an imaging plate was calibrated at 1 GeV electron energy using the injector Linac of SPring-8. The sensitivity curve obtained up to 100 MeV in a previous study was extended successfully to GeV range.
Kaji, Yoshiyuki; Tsuji, Hirokazu; Fujita, Mitsutane*; Xu, Y.*; Yoshida, Kenji*; Mashiko, Shinichi*; Shimura, Kazuki*; Miyakawa, Shunichi*; Ashino, Toshihiro*
Data Science Journal (Internet), 3, p.88 - 94, 2004/07
The distributed material database system named "Data-Free-Way" has been developed by four organizations (the National Institute for Materials Science, the Japan Atomic Energy Research Institute, the Japan Nuclear Cycle Development Institute, and the Japan Science and Technology Corporation) under a cooperative agreement. In order to create additional values of the system, knowledge base system, in which knowledge extracted from the material database is expressed, is planned to be developed for more effective utilization of Data-Free-Way. XML (eXtensible Markup Language) has been adopted as the description method of the retrieved results and the meaning of them. One knowledge note described with XML is stored as one knowledge which composes the knowledge base. This paper describes the current status of Data-Free-Way, the description method of knowledge extracted from the material database with XML and the distributed material knowledge base system.
Kaji, Yoshiyuki; Yoshida, Kenji*; Mashiko, Shinichi*; Fujita, Mitsutane*; Shimura, Kazuki*; Kinugawa, Junichi*; Tsuji, Hirokazu; Miyakawa, Shunichi*; Iwata, Shuichi*
Nihon Genshiryoku Gakkai Wabun Rombunshi, 1(4), p.412 - 418, 2002/12
The distributed material database system named 'Data-Free-Way' has been developed by four organizations (the National Institute for Materials Science, the Japan Atomic Energy Research Institute, the Japan Nuclear Cycle Development Institute, and the Japan Science and Technology Corporation) under a cooperative agreement. In order to create additional values of the system, knowledge base system, in which knowledge extracted from the material database is expressed, is planned to be developed for more effective utilization of Data-Free-Way. XML (eXtensible Markup Language) has been adopted as the description method of the retrieved results and the meaning of them. One knowledge note described with XML is stored as one knowledge which composes the knowledge base. This paper describes the current status of Data-Free-Way, the description method of knowledge extracted from the material database with XML and the distributed material knowledge base system.
Tsuji, Hirokazu; Kaji, Yoshiyuki; Fujita, Mitsutane*; Kinugawa, Junichi*; Yoshida, Kenji*; Mashiko, Shinichi*; Shimura, Kazuki*; Miyakawa, Shunichi*; Iwata, Shuichi*
Proceedings of 10th German-Japanese Workshop on Chemical Information, p.131 - 133, 2002/00
The distributed material database system named "Data-Free-Way" has been developed by four organizations (the National Institute for Materials Science, the Japan Atomic Energy Research Institute, the Japan Nuclear Cycle Development Institute and Japan Science and Technology Corporation) under a cooperative agreement. It is a system which can display the data which the user demands without considering the organization which stores data as a table and a graph. The knowledge of the forte of each organization based on the retrieval result from the fact database is made aiming at more highly developed use of this system. The development of the system by which the user can refer to the knowledge is advanced. Though the retrieval result from the fact database was displayed as a table and a graph, that is, the finding note where they were described and expressed with XML as knowledge.
Kaji, Yoshiyuki; Yoshida, Kenji*; Mashiko, Shinichi*; Fujita, Mitsutane*; Shimura, Kazuki*; Kinugawa, Junichi*; Tsuji, Hirokazu; Miyakawa, Shunichi*; Iwata, Shuichi*
Dai-38-Kai Joho Kagaku Gijutsu Kenkyu Shukai Happyo Yokoushu, p.43 - 47, 2001/00
A distributed database system named Data-Free-Way for advanced nuclear materials has been developed by the National Institute for Materials Science (NIMS), the Japan Atomic Energy Research Institute (JAERI), the Japan Nuclear Cycle Development Institute (JNC), and the Japan Science and Technology Corporation (JST) under a cooperative agreement. In this system, end-users are able to obtain necessary data such as tables or graphs, even if they do not know the sites in which the data are stored. A distributed knowledge database in which each organization makes the knowledge based on the retrieval results from fact database and end-users can get the knowledge, has been developed to make more useful utilization of this system. Though the retrieval results from the fact database were shown in the tables or graphs, the new system constitutes the information notes described the retrieval ones for the knowledge by XML. This paper describes the present status of the Data-Free-Way and the description method of XML for the retrieval results.
