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Uchida, Masaki*; Maekawa, Takashi*; Tanaka, Hitoshi*; Ide, Shunsuke; Takase, Yuichi*; Watanabe, Fumitake*; Nishi, Seiji*
Nuclear Fusion, 51(6), p.063031_1 - 063031_9, 2011/06
Times Cited Count:15 Percentile:51.92(Physics, Fluids & Plasmas)Uchida, Masaki*; Maekawa, Takashi*; Tanaka, Hitoshi*; Ide, Shunsuke; Takase, Yuichi*; Watanabe, Fumitake*; Nishi, Seiji*
Proceedings of 23rd IAEA Fusion Energy Conference (FEC 2010) (CD-ROM), 8 Pages, 2010/10
Konishi, Hiroyuki; Yamashita, Masato*; Mizuki, Junichiro; Uchida, Hitoshi*
Characterization of Corrosion Products on Steel Surfaces, p.199 - 222, 2006/00
no abstracts in English
Matsuoka, Hiromitsu; Hashimoto, Kazuyuki; Hishinuma, Yukio*; Ishikawa, Koji*; Terunuma, Hitoshi*; Tatenuma, Katsuyoshi*; Uchida, Shoji*
Journal of Nuclear and Radiochemical Sciences, 6(3), p.189 - 191, 2005/12
Applicability of Mo adsorbent PZC(Poly Zirconium Compound) for W/
Re generator was investigated. Long term stability of adsorption of
W to the PZC column, elution of
Re from PZC column, desorption of
from PZC column, and labeling of Hydroxyethylidene Diphosphonic Acid(HEDP) and Mercaptoacetyltriglycine(MAG3) with
Re eluted from PZC column were tested. The PZC generator gave reproducible
Re elution yields with low
W parent breakthrough for a long period of time(about 5 months), that is the
W/
Re generator using PZC has a potential for practical use.
Konishi, Hiroyuki; Yamashita, Masato*; Uchida, Hitoshi*; Mizuki, Junichiro
Proceedings of 16th International Corrosion Congress (CD-ROM), 6 Pages, 2005/09
XANES measurements of rust layers formed on Fe, Fe-Cr alloys and Fe-Ni alloys exposed to a Cl-rich atmosphere have been performed using synchrotron radiation in order to clarify the relation between the structural properties of the rust layer on weathering steel and anticorrosive alloying elements and/or chloride ions. The XANES spectra around Cl K-edge revealed that the rust layer on the Fe-based binary alloys contains unidentified chloride in addition to akaganiteite. The Fe K-edge XANES results indicated that the rust layers are composed mainly of well-known iron oxides, goethite, akagan
ite, lepidocrocite and magnetite. In particular, the mole ratio of akagan
ite in the rust layers on the Fe-Ni alloys is relatively higher than that of the Fe-Cr alloys. The Cr K-edge XANES spectra of the rust layers on the Fe-Cr alloys depends on the Cr alloy content. Therefore, the local structure of Cr in the rust layer is variable with the Cr density. In contrast, the Ni K-edge XANES results show that the local structure of Ni in the rust layer are unique in a certain Ni content range.
Kato, Tomoko; Suzuki, Yuji*; Makino, Hitoshi; Uchida, Masahiro; Naito, Morimasa; Wakasugi, Keiichiro*; Takahashi, Yoshiaki*
JNC TN1400 2005-024, 14 Pages, 2005/08
Biosphere assessment is positioned as part of an important factor in safety assessment to convert nuclide release rates into surface environment to measures of effect for human, such as radiation dose. In general, a lot of data are handled in the biosphere assessment, and they are based on the feature of specific site. Therefore, it is reasonable to screen parameters in order to manage the limited resource and develop the biosphere assessment effectively. JNC and NUMO established
Konishi, Hiroyuki; Yamashita, Masato*; Uchida, Hitoshi*; Mizuki, Junichiro
Materials Transactions, 46(2), p.337 - 341, 2005/02
Times Cited Count:11 Percentile:60.52(Materials Science, Multidisciplinary)We have performed extended X-ray absorption fine structure (EXAFS) analysis for artificial Cr-goethite to elucidate the local structure around Cr in Cr-goethite. The spectra were obtained using synchrotron radiation X-rays at the Photon Factory in Tsukuba. The first shell contributions were isolated by Fourier filtering the EXAFS data, and the inverse Fourier transformed single-shell data were analyzed using curve fitting method. The results show that Cr is coordinated with (71) O
ions. The protective character of Cr-goethite protective rust layer on weathering steel can be interpreted in terms of the O
coordination around Cr
resulting in creation of negative fixed-charge in the Cr-goethite particles.
Konishi, Hiroyuki; Yamashita, Masato*; Uchida, Hitoshi*; Mizuki, Junichiro
Materials Transactions, 46(2), p.329 - 336, 2005/02
Times Cited Count:31 Percentile:81.21(Materials Science, Multidisciplinary)Chloride in atmosphere considerably reduces the corrosion resistance of conventional weathering steel containing a small amount of Cr. Ni is an effective anticorrosive element for improving the corrosion resistance of steel in a Cl-rich environment. In order to clarify the structure of the protective rust layer of weathering steel, Cl and Fe K-edge X-ray absorption near edge structure (XANES) spectra of atmospheric corrosion products (rust) formed on Fe, Fe-Ni and Fe-Cr alloys exposed to Cl-rich atmosphere were measured. The Fe K-XANES measurements enable the characterization of a mixture of iron oxides such as rust. The chemical composition of the rust was determined by performing pattern fitting of the measured spectra. All the rust is composed mainly of goethite, akaganite, lepidocrocite and magnetite. Among these iron oxides, akagan
ite in particular is the major component in the rust. Additionally, the amount of akagan
ite in the rust of Fe-Ni alloy is much greater than that in rust of Fe-Cr alloy. Akagan
ite is generally considered to facilitate the corrosion of steel, but our results indicate that akagan
ite in the rust of Fe-Ni alloy is quantitatively different from that in rust of Fe-Cr alloy and does not facilitate the corrosion of steel. The shoulder peak observed in Cl K-XANES spectra reveals that the rust contains a chloride other than akagan
ite. The energy of the shoulder peak does not correspond to that of any well-known chlorides. In the measured spectra, there is no proof that Cl, by combining with the alloying element, inhibits the alloying element from acting in corrosion resistance. The shoulder peak appears only when the content of the alloying element is lower than a certain value. This suggests that the generation of the unidentified chloride is related to the corrosion rate of steel.
Konishi, Hiroyuki; Yamashita, Masato*; Uchida, Hitoshi*; Mizuki, Junichiro
Materials Transactions, 46(1), p.136 - 139, 2005/01
Times Cited Count:3 Percentile:32.57(Materials Science, Multidisciplinary)The rust layer formed on weathering steel possesses a strong protective ability against corrosives in an atmosphere. This ability is related to the structure of the rust layer. The difference in the protective ability of a rust layer in a Cl-rich environment between conventional weathering steel containing Cr and advanced weathering steel containing Ni is believed to be caused by the differences in local structural and chemical properties between alloying elements, Cr and Ni, in the rust layer. In order to examine the effect of these alloying elements on the structure of the rust layer formed on steel in a Cl-rich environment, we have performed Cr and Ni K-edge X-ray absorption near-edge structure (XANES) measurements for the rust layer of Fe-Cr and Fe-Ni binary alloys exposed to a Cl-rich atmosphere using synchrotron radiation. The results of the Cr K-edge XANES measurements for the rust layer of Fe-Cr binary alloys show that the atomic geometry around Cr depends on the concentration of Cr. Therefore, it is expected that the local structure around Cr in the rust layer is unstable. On the other hand, from the results of the Ni K-edge XANES measurements for the rust layer of Fe-Ni binary alloys, Ni is considered to be positioned at a specific site in the crystal structure of a constituent of the rust layer, such as akaganite or magnetite. As a consequence, Ni negligibly interacts with Cl
ions in the rust layer.
Konishi, Hiroyuki; Yamashita, Masato*; Uchida, Hitoshi*; Mizuki, Junichiro
Materials Transactions, 45(12), p.3356 - 3359, 2004/12
Times Cited Count:10 Percentile:52.31(Materials Science, Multidisciplinary)Cl K-edge XANES measurements of atmospheric corrosion products (rust) formed on Fe, Fe-Ni and Fe-Cr alloys in chloride pollution have been performed using synchrotron radiation in order to clarify roles of anticorrosive alloying elements and of Cl in the corrosion resistance of weathering steel. The spectra of binary alloys show a shoulder structure near the absorption edge. The intensity of the shoulder peak depends on the kind and amount of the alloying element, whereas the energy position is invariant. This indicates that Cl is not combined directly with alloying elements in the rust.
Shibata, Katsushi; Makino, Hitoshi; Wakasugi, Keiichiro; Uchida, Masahiro
Saikuru Kiko Giho, (21), p.79 - 88, 2003/12
R&D of geological disposal of high-level radioactive waste consists of three fields (site investigation, repository design and safety assessment). It is necessary to deal with an increase in quantity of , and growing diversity and complexity of technical information caused by progress of R&D at each field and accelerated iteration within these three fields. To deal with this problem, it is necessary to prepare the computational environment that can catalogue and share the technical information efficiently and effectively. This report introduces concept and approach for developing a "JNC Geological Disposal Technical Information Integration System (JGIS)"
Kato, Tomoko; Suzuki, Yuji*; Makino, Hitoshi; Uchida, Masahiro
Proceedings of International Symposium on Radioecology and Environmental Dosimetry, p.465 - 472, 2003/10
Considering a wide range of Japanese geological environments in generic context, some biosphere models were developed using an approach consistent with the BIOMASS Methodology. Moreover, sensitivity analysis for the biosphere models was performed to evaluate and understand the relative importance of parameters.
Kato, Tomoko; Suzuki, Yuji*; Makino, Hitoshi; Uchida, Masahiro
Heisei-15-Nendo Kankyoken Kokusai Kento Iinkai "Hoshasei Seitaigaku To Kankyo No Hoshasen Hibaku Ni Kansuru Kokusai Shimpojiumu", 35 Pages, 2003/00
JNC has an on-going programme of research and development relating to the safety assessment of the deep geological system of high-level radioactive waste. This paper summarises the approach used for the deriviation of "flux to dose conversion factors" for the range of geosphere-biosphere interfaces and potential exposure groups and discussion on key parameters in JNC' biosphere assessment.
Uchida, Masahiro; Makino, Hitoshi; Wakasugi, Keiichiro; Shibata, Katsushi
OECD/NEA Amigo Project Dai-1-Kai Wakushoppu, 0 Pages, 2003/00
None
Makino, Hitoshi; ; Kato, Tomoko; ; Uchida, Masahiro
JNC TN8450 2001-012, 11 Pages, 2002/02
JNC (Japan Nuclear Cycle Development Institute) had proceeded R&D activities to provide a scientific and technical basis for geological disposal of HLW in Japan. The second progress report (H12) documented the progress of R&D and the Japanese version was submitted to the AEC (the Atomic Energy Commission) in November 1999. This report summarizes the calculation results for nuclide migration in "Synthesis of Calculation Cases Illustrating Overall System Performance", which are performed to examine the safety of the geological disposal concept in Japan in the Safety Assessment in H12 Report. In addition, a set of calculation result for nuclide migration through each pathway in one-dimensional multiple pathway model (a set of 48 segments) are summarized for the Reference Case in H12 Report, and calculated dose conversion factors are also summarized against the combinations of potential Geosphere-Biosphere Interfaces (GBI) and potential exposure groups. Digital data of the calculation results are summarized in Appendix CD-ROM as Microsoft EXCEL files.
Yamashita, Masato*; Konishi, Hiroyuki; Takahashi, Masamitsu; Mizuki, Junichiro; Uchida, Hitoshi*
Materials Science Research International, Special Technical Publication, 1, p.398 - 401, 2001/05
A rust layer on a weathering low-alloy steel has strong protective ability for atmospheric corrosion of the steel. In order to control the rust layer on steels, it is so important to know the detailed structure of rust and relate it to the protective ability of the rust layer. Especially, the position of atoms of the alloying elements in the rust layer directly control the structure and properties of the rust layer. We tried to find the atomic arrangement of the rust layer of Fe-Cr alloy film covered with thin film of electrolyte using synchrotron radiation. Grazing incidence X-ray diffraction and Mssbauer spectra showed that the rust layer was composed of
-FeOOH and ultra-fine
-FeOOH. By examining EXAFS spectra, Cr coming from Fe-Cr alloy film would be present in the
-FeOOH. Some of Cr would be present between Fe-0-OH octahedron as interstitial atoms, as well as substituting Fe lattice site in the octahedron.
Kume, Tamikazu; Matsuhashi, Shimpei; Ito, Hitoshi; G.W.Roeb*; Ishioka, Noriko; Osa, Akihiko; Matsuoka, Hiromitsu; Sekine, Toshiaki; Uchida, Hiroshi*; Tsuji, Atsunori*; et al.
JAERI-Review 97-015, p.51 - 53, 1997/11
no abstracts in English
Kume, Tamikazu; Matsuhashi, Shimpei; ; Ito, Hitoshi; Fujimura, Takashi; ; Uchida, Hiroshi*; Ishioka, Noriko; Matsuoka, Hiromitsu; Osa, Akihiko; et al.
Applied Radiation and Isotopes, 48(8), p.1035 - 1043, 1997/00
Times Cited Count:54 Percentile:94.91(Chemistry, Inorganic & Nuclear)no abstracts in English
Kume, Tamikazu; Matsuhashi, Shimpei; ; Ito, Hitoshi; Uchida, Hiroshi*; Tsuji, Atsunori*; Ishioka, Noriko; Matsuoka, Hiromitsu; Osa, Akihiko; Sekine, Toshiaki
Plant Nutrition for Sustainable Food Production and Environment, 0, p.169 - 170, 1997/00
no abstracts in English
Saegusa, Yu; Nishino, Saki; Horie, Koji; Yatabe, Hitoshi; Yamada, Takashi; Oyama, Daisuke; Uchida, Naoki
no journal, ,
All the spent fuel stored in the Tokai Reprocessing Plant is transported to the overseas reprocessing plant. When spent fuel transportation, we use dry type cask instead of wet type cask. Therefore, equipment of the wet type cask is not used. And the equipment is some possibility of interfere with cask because the equipment is stored in the transport route. So, we were dismantled receiving and storage process equipment as preparation work for spent fuel transportation. In dismantlement work, we selected cutting equipment after scrutinizing size and shape of equipment, contamination and workability. Moreover, we have taken safety measures during work such as fire prevention and contamination control. As a result, the work was completed as originally planned.