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Journal Articles

Heavy fermion state of YbNi$$_2$$Si$$_3$$ without local inversion symmetry

Nakamura, Shota*; Hyodo, Kazushi*; Matsumoto, Yuji*; Haga, Yoshinori; Sato, Hitoshi*; Ueda, Shigenori*; Mimura, Kojiro*; Saiki, Katsuyoshi*; Iso, Kosei*; Yamashita, Minoru*; et al.

Journal of the Physical Society of Japan, 89(2), p.024705_1 - 024705_5, 2020/02

 Times Cited Count:0 Percentile:100(Physics, Multidisciplinary)

Journal Articles

Spectroscopic evidence of band Jahn-Teller distortion upon martensitic phase transition in Heusler-type Ni-Fe(Co)-Ga ferromagnetic shape-memory alloy films

Sumida, Kazuki*; Shirai, Kaito*; Zhu, S.-Y.*; Taniguchi, Masaki*; Ye, M.*; Ueda, Shigenori*; Takeda, Yukiharu; Saito, Yuji; Aseguinolaza, I. R.*; Barandiar$'a$n, J. M.*; et al.

Physical Review B, 91(13), p.134417_1 - 134417_6, 2015/04

 Times Cited Count:4 Percentile:72.81(Materials Science, Multidisciplinary)

Journal Articles

Role of residual transition-metal atoms in oxygen reduction reaction in cobalt phthalocyanine-based carbon cathode catalysts for polymer electrolyte fuel cell

Kobayashi, Masaki*; Niwa, Hideharu*; Harada, Yoshihisa*; Horiba, Koji*; Oshima, Masaharu*; Ofuchi, Hironori*; Terakura, Kiyoyuki*; Ikeda, Takashi; Koshigoe, Yuka*; Ozaki, Junichi*; et al.

Journal of Power Sources, 196(20), p.8346 - 8351, 2011/10

 Times Cited Count:27 Percentile:30.32(Chemistry, Physical)

The electronic structure of Co atoms in CoPc-based carbon catalysts, which were prepared by pyrolyzing a mixture of CoPc and phenol resin polymer up to 1000$$^circ$$C, has been investigated using XAFS analysis and HXPES. The Co K XAFS spectra show that most of the Co atoms are in the metallic state and small quantities of oxidized Co components are present in the samples even after acid washing to remove Co atoms. Based on the difference in probing depth between XAFS and HXPES, it was found that after acid washing, the surface region with the aggregated Co clusters is primarily composed of metallic Co. Since the electrochemical properties remain almost unchanged even after the acid washing process, the residual metallic and oxidized Co atoms themselves will hardly contribute to the ORR activity of the CoPc-based carbon cathode catalysts, implying that the active sites of the CoPc-based catalysts primarily consist of light elements such as C and N.

Journal Articles

Conduction-band electronic states of YbInCu$$_4$$ studied by photoemission and soft X-ray absorption spectroscopies

Utsumi, Yuki*; Sato, Hitoshi*; Kurihara, Hidenao*; Maso, Hiroyuki*; Hiraoka, Koichi*; Kojima, Kenichi*; Tobimatsu, Komei*; Okochi, Takuo*; Fujimori, Shinichi; Takeda, Yukiharu; et al.

Physical Review B, 84(11), p.115143_1 - 115143_7, 2011/09

 Times Cited Count:6 Percentile:66.41(Materials Science, Multidisciplinary)

We have studied conduction-band (CB) electronic states of a typical valence-transition compound YbInCu$$_4$$ by means of temperature-dependent hard X-ray photoemission spectroscopy (HX-PES), soft X-ray absorption spectroscopy (XAS), and soft X-ray photoemission spectroscopy (SX-PES) of the valence band. We have described the valence transition in YbInCu$$_4$$ in terms of the charge transfer from the CB to Yb 4$$f$$ states.

Journal Articles

X-ray photoemission spectroscopy analysis of N-containing carbon-based cathode catalysts for polymer electrolyte fuel cells

Niwa, Hideharu*; Kobayashi, Masaki*; Horiba, Koji*; Harada, Yoshihisa*; Oshima, Masaharu*; Terakura, Kiyoyuki*; Ikeda, Takashi; Koshigoe, Yuka*; Ozaki, Junichi*; Miyata, Seizo*; et al.

Journal of Power Sources, 196(3), p.1006 - 1011, 2011/02

 Times Cited Count:76 Percentile:7.29(Chemistry, Physical)

We report on the electronic structure of three different types of N-containing carbon-based cathode catalysts for polymer electrolyte fuel cells observed by hard X-ray photoemission spectroscopy. C 1s spectra show the importance of $$sp^{2}$$ carbon network formation for the oxygen reduction reaction (ORR) activity. Samples having high oxygen reduction reaction activity in terms of oxygen reduction potential contain high concentration of graphite-like nitrogen. Based on a quantitative analysis of our results, the oxygen reduction reaction activity of the carbon-based cathode catalysts will be improved by increasing concentration of graphite-like nitrogen in a developed $$sp^{2}$$ carbon network.

Journal Articles

Soft X-ray beamline for spectroscopy of solids at SPring-8

Saito, Yuji; Kimura, Hiroaki*; Suzuki, Yoshio*; Nakatani, Takeshi*; Matsushita, Tomohiro*; Muro, Takayuki*; Miyahara, Tsuneaki*; Fujisawa, M.*; Soda, Kazuo*; Ueda, Shigenori*; et al.

Nuclear Instruments and Methods in Physics Research A, 467-468(Part.1), p.553 - 556, 2001/07

 Times Cited Count:23 Percentile:15.46

no abstracts in English

Journal Articles

Magnetic circular dichroism in Mn 2p core absorption of Ga$$_{1-x}$$Mn$$_{x}$$As

Ueda, Shigenori*; Imada, Shin*; Muro, Takayuki*; Saito, Yuji; Suga, Shigemasa*; Matsukura, F.*; Ono, Hideo*

Physica E, 10(1-3), p.210 - 214, 2001/05

 Times Cited Count:23 Percentile:25.33

no abstracts in English

Journal Articles

Performance of a very high resolution soft X-ray beamline BL25SU with a twin-helical undulator at SPring-8

Saito, Yuji; Kimura, Hiroaki*; Suzuki, Yoshio*; Nakatani, Takeshi*; Matsushita, Tomohiro*; Muro, Takayuki*; Miyahara, Tsuneaki*; Fujisawa, M.*; Soda, Kazuo*; Ueda, Shigenori*; et al.

Review of Scientific Instruments, 71(9), p.3254 - 3259, 2000/09

 Times Cited Count:178 Percentile:0.88(Instruments & Instrumentation)

no abstracts in English

Oral presentation

Effect of electrochemical pre-treatment and interface structure between Pt and CeO$$_{x}$$ for improvement of oxygen reduction reaction activity on Pt-CeO$$_{x}$$ model electro catalysis

Fugane, Keisuke*; Mori, Toshiyuki*; Wu, Y. Y.*; Yamamoto, Shunya; Maekawa, Yasunari; Yoshikawa, Hideki*; Yamashita, Yoshiyuki*; Ueda, Shigenori*; Vladimir, M.*; Suzuki, Akira*; et al.

no journal, , 

no abstracts in English

Oral presentation

Charge transfer and negative thermal expansion of Bi$$_{1-x}$$Pb$$_{x}$$NiO$$_{3}$$

Nakano, Kiho*; Nabetani, Koichiro*; Azuma, Masaki*; Oka, Kengo*; Mizumaki, Masaichiro*; Agui, Akane; Ueda, Shigenori*

no journal, , 

no abstracts in English

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