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Journal Articles

Organization of malonamides from the interface to the organic bulk phase

Micheau, C.; Ueda, Yuki; Motokawa, Ryuhei; Akutsu, Kazuhiro*; Yamada, Norifumi*; Yamada, Masako*; Moussaoui, S. A.*; Makombe, E.*; Meyer, D.*; Berthon, L.*; et al.

Journal of Molecular Liquids, 401, p.124372_1 - 124372_12, 2024/05

Supramolecular organization of extractant molecules impacts metal ions separation behavior. Probing bulk and interfacial structures of the relevant systems is expected to provide key insights into the metal ion selectivity and kinetic aspects. The supramolecular features of two solvent extraction systems based on malonamide extractants THMA in toluene and DBMA in n-heptane were studied using small-angle X-ray scattering for the organic bulk phases, as well as interfacial tension and neutron reflectivity measurements for the interfaces. In the bulk solution, THMA forms dimeric/trimeric associates but no aggregates in toluene, while DBMA forms large aggregates in n-heptane. On the other hand, THMA accumulates in a diffuse layer at the interface at high THMA concentration, whereas DBMA forms a compact but thinner layer. After Pd(II) extraction, the thickness of interfacial layers decreases in the case of THMA, and totally vanishes in the case of DBMA. Based on these new structural information, two mechanisms are proposed for Pd(II) and Nd(III) extraction with malonamides. In toluene, THMA associates slightly accumulate in the vicinity of the interface, then coordinate Pd(II) and diffuse into the organic bulk phase. In n-heptane, DBMA aggregates adsorb at the interface then pick up Nd(III) cations in their polar cores and finally diffuse into the bulk.

Journal Articles

Benchmark analysis by Beremin model and GTN model in CAF Subcommittee

Nagoshi, Yasuto*; Fukahori, Takuya*; Okada, Hiroshi*; Takahashi, Akiyuki*; Shimodaira, Masaki; Ueda, Takashi*; Ogawa, Takuya*; Yashirodai, Kenji*; Takahashi, Yukio*; Ohata, Mitsuru*

Transactions of the 27th International Conference on Structural Mechanics in Reactor Technology (SMiRT 27) (Internet), 9 Pages, 2024/03

no abstracts in English

Journal Articles

Upgrade of the small-angle neutron scattering diffractometer SANS-J at JRR-3

Kumada, Takayuki; Motokawa, Ryuhei; Oba, Yojiro; Nakagawa, Hiroshi; Sekine, Yurina; Micheau, C.; Ueda, Yuki; Sugita, Tsuyoshi; Birumachi, Atsushi; Sasaki, Miki; et al.

Journal of Applied Crystallography, 56(6), p.1776 - 1783, 2023/12

 Times Cited Count:1 Percentile:65.66(Chemistry, Multidisciplinary)

The combination of the existing position-sensitive photomultiplier and the 3He main detector with focusing devices, and the newly installed front detectors in SANS-J at JRR-3 covers small-angle neutron scattering signals in the range of the magnitude of the scattering vector Q from 0.002 to 6 nm-1 gaplessly with three standard device layouts. The installation of the front detector and a graphical user interface system largely improved the usability of SANS-J.

Journal Articles

Occurrence of radioactive cesium-rich micro-particles (CsMPs) in a school building located 2.8 km south-west of the Fukushima Daiichi Nuclear Power Plant

Fueda, Kazuki*; Komiya, Tatsuki*; Minomo, Kenta*; Horie, Kenji*; Takehara, Mami*; Yamasaki, Shinya*; Shiotsu, Hiroyuki; Onuki, Toshihiko*; Grambow, B.*; Law, G. T. W.*; et al.

Chemosphere, 328, p.138566_1 - 138566_12, 2023/07

 Times Cited Count:1 Percentile:52.26(Environmental Sciences)

Journal Articles

Foam flotation of clay particles using a bifunctional amine surfactant

Micheau, C.; Ueda, Yuki; Motokawa, Ryuhei; Bauduin, P.*; Girard, L.*; Diat, O.*

Langmuir, 39(31), p.10965 - 10977, 2023/07

 Times Cited Count:0 Percentile:0(Chemistry, Multidisciplinary)

Journal Articles

A Novel method for processing noisy magnetotelluric data based on independence of signal sources and continuity of response functions

Ogawa, Hiroki; Asamori, Koichi; Negi, Tateyuki*; Ueda, Takumi*

Journal of Applied Geophysics, 213, p.105012_1 - 105012_17, 2023/06

 Times Cited Count:0 Percentile:0.02(Geosciences, Multidisciplinary)

A number of schemes for processing magnetotelluric (MT) data have been reported aiming at suppressing the strong effect of artificial electromagnetic noise, especially coherent noise that is correlated between electric and magnetic time series. Many of the recent denoising schemes are based on decomposing MT data into the responses of the natural signal and noise. Meanwhile, it is crucial to distinguish the natural signal from noise stably without depending on any empirical choice of parameter setting. In addition, improper subtraction of values from the separated signal can lead to the loss of useful values of the natural signal or missing noise-affected values, which may result in failure in deriving the true MT responses. We propose a novel data-processing method that applies frequency-domain independent component analysis (FDICA) to both the local MT data and the reference magnetic data. Among the separated signal, the proposed method can quantitatively distinguish the natural signal from the noise-affected components by calculating the ratio of cross-power spectrum with the reference data to the auto-power spectrum for each component. When determining which values to subtract from the separated signal, we introduce an evaluation index with respect to two characteristics of the MT response function: stationary in the time domain and smoothness in the frequency domain. We conduct the experiments both with MT time series severely contaminated by synthetic coherent noises and with MT field data interfered with DC (direct current) railways. Consequently, we confirm the superiority of the proposed method in the noise-suppression performance over the conventional methods of MT data processing.

Journal Articles

Investigation of niobium surface roughness and hydrogen content with different polishing conditions for performance recovery of superconducting QWRs in JAEA Tokai-Tandem Accelerator

Kamiya, Junichiro; Nii, Keisuke*; Kabumoto, Hiroshi; Kondo, Yasuhiro; Tamura, Jun; Harada, Hiroyuki; Matsui, Yutaka; Matsuda, Makoto; Moriya, Katsuhiro; Ida, Yoshiaki*; et al.

e-Journal of Surface Science and Nanotechnology (Internet), 21(4), p.344 - 349, 2023/05

no abstracts in English

Journal Articles

Hierarchical aggregation in a complex fluid; The Role of isomeric interconversion

Massey, D.*; Williams, C. D.*; Mu, J.*; Masters, A. J.*; Motokawa, Ryuhei; Aoyagi, Noboru; Ueda, Yuki; Antonio, M. R.*

Journal of Physical Chemistry B, 127(9), p.2052 - 2065, 2023/03

 Times Cited Count:0 Percentile:0(Chemistry, Physical)

Journal Articles

Deuterated malonamide synthesis for fundamental research on solvent extraction systems

Micheau, C.; Ueda, Yuki; Akutsu, Kazuhiro*; Bourgeois, D.*; Motokawa, Ryuhei

Solvent Extraction and Ion Exchange, 41(2), p.221 - 240, 2023/02

 Times Cited Count:1 Percentile:51.1(Chemistry, Multidisciplinary)

Journal Articles

Reports of electro-polishing implementation for quarter-wave resonators, 2

Nii, Keisuke*; Ida, Yoshiaki*; Ueda, Hideki*; Yamaguchi, Takanori*; Kabumoto, Hiroshi; Kamiya, Junichiro; Kondo, Yasuhiro; Tamura, Jun; Harada, Hiroyuki; Matsui, Yutaka; et al.

Proceedings of 19th Annual Meeting of Particle Accelerator Society of Japan (Internet), p.601 - 604, 2023/01

no abstracts in English

Journal Articles

Tough yet flexible superelastic alloys meet biomedical needs

Xu, X.*; Odaira, Takumi*; Xu, S.*; Hirata, Kenji*; Omori, Toshihiro*; Ueki, Kosuke*; Ueda, Kyosuke*; Narushima, Takayuki*; Nagasako, Makoto*; Kainuma, Ryosuke*; et al.

Advanced Materials & Processes, 180(7), p.35 - 37, 2022/10

Journal Articles

Flexible and tough superelastic Co-Cr alloys for biomedical applications

Odaira, Takumi*; Xu, S.*; Hirata, Kenji*; Xu, X.*; Omori, Toshihiro*; Ueki, Kosuke*; Ueda, Kyosuke*; Narushima, Takayuki*; Nagasako, Makoto*; Harjo, S.; et al.

Advanced Materials, 34(27), p.2202305_1 - 2202305_11, 2022/07

 Times Cited Count:12 Percentile:87.73(Chemistry, Multidisciplinary)

Journal Articles

Polymer photonic crystals prepared by triblock copolymerization-induced ${it in situ}$ microphase separation

Isozaki, Yuka*; Higashiharaguchi, Seiya*; Kaneko, Naoya*; Yamazaki, Shun*; Taniguchi, Tatsuo*; Karatsu, Takashi*; Ueda, Yuki; Motokawa, Ryuhei

Chemistry Letters, 51(6), p.625 - 628, 2022/06

 Times Cited Count:2 Percentile:29.84(Chemistry, Multidisciplinary)

Journal Articles

Urea-introduced ionic liquid for the effective extraction of Pt(IV) and Pd(II) ions

Ueda, Yuki; Eguchi, Ayano; Tokunaga, Kohei; Kikuchi, Kei*; Sugita, Tsuyoshi; Okamura, Hiroyuki; Naganawa, Hirochika

Industrial & Engineering Chemistry Research, 61(19), p.6640 - 6649, 2022/05

 Times Cited Count:1 Percentile:12.67(Engineering, Chemical)

no abstracts in English

Journal Articles

Volatilization of B$$_{4}$$C control rods in Fukushima Daiichi nuclear reactors during meltdown; B-Li isotopic signatures in cesium-rich microparticles

Fueda, Kazuki*; Takami, Ryu*; Minomo, Kenta*; Morooka, Kazuya*; Horie, Kenji*; Takehara, Mami*; Yamasaki, Shinya*; Saito, Takumi*; Shiotsu, Hiroyuki; Onuki, Toshihiko*; et al.

Journal of Hazardous Materials, 428, p.128214_1 - 128214_10, 2022/04

 Times Cited Count:6 Percentile:68.71(Engineering, Environmental)

Journal Articles

Development and evaluation of XRF imaging instrument for moving objects

Fuchita, Tomoki*; Urata, Taisei*; Matsuyama, Tsugufumi*; Murakami, Masashi; Yoshida, Yukihiko; Ueda, Akihiko; Machida, Masahiko; Sasaki, Toshiki; Tsuji, Koichi*

Advances in X-Ray Chemical Analysis, Japan, 53, p.77 - 87, 2022/03

X-ray fluorescence (XRF) analysis is an analytical method to obtain elemental information by detecting fluorescence X-rays emitted from a sample irradiated with X-rays. It is possible to obtain two-dimensional elemental distribution images by scanning a sample with micro X-ray beam. In this study, we developed an XRF analytical instrument to rapidly obtain the elemental distributions for moving samples on a belt conveyor by applying the micro XRF technique. X-rays were widely irradiated to the belt conveyor. The elemental distributions were measured by scanning an X-ray detector, crossing above the belt conveyor. A collimator was attached to the top of the detector to limit the analyzing area. Both detection limit and spatial resolutions for moving directions of the detector and the belt conveyor were evaluated. Finally, it was demonstrated that the multi-elemental imaging was possible with the developed XRF instrument.

Journal Articles

New design of a sample cell for neutron reflectometry in liquid-liquid systems and its application for studying structures at air-liquid and liquid-liquid interfaces

Akutsu-Suyama, Kazuhiro*; Yamada, Norifumi*; Ueda, Yuki; Motokawa, Ryuhei; Narita, Hirokazu*

Applied Sciences (Internet), 12(3), p.1215_1 - 1215_10, 2022/02

 Times Cited Count:1 Percentile:28.33(Chemistry, Multidisciplinary)

no abstracts in English

Journal Articles

A Proposal of optimum calculation settings of continuous wavelet transform in magnetotelluric data processing

Ogawa, Hiroki; Hama, Yuki*; Asamori, Koichi; Ueda, Takumi*

Butsuri Tansa, 75, p.38 - 55, 2022/00

In the magnetotelluric (MT) method, so as to identify the subsurface resistivity structure, the apparent resistivity and phase profiles are calculated by transforming time-series data into spectral data. The continuous wavelet transform (CWT) is well known as a new method of time-frequency analysis instead of the short-time Fourier transform. The CWT is superior in processing non-stationary wideband signals like the MT signal by adjusting the size of the wavelet according to the value of frequency. However, the calculation settings of the CWT, such as the type of basis function and the wavelet parameter, are often determined empirically because of the arbitrariness of the shape of the wavelet. Although there might be differences between the calculated MT responses and the true responses due to improper settings of the CWT, there are no detailed studies considering the effect of numerical errors derived from spectral transforms on MT data. In this study, focusing on the frequency band between 0.001 Hz and 1 Hz, we examined the optimum calculation settings of the CWT in processing MT data in terms of suppressing the numerical errors caused by the spectral transform of time-series data. We also show the validity of the proposed calculation settings by applying the CWT to MT survey data of different types. Superiority of the CWT with proposed settings is suggested especially when the signal-to-noise ratio of observed data is low. Consequently, the proposed calculation settings were confirmed to strike a balance between the resolutions of the time and frequency domains well and will therefore be effective in obtaining reliable MT responses.

Journal Articles

Effective extraction of Pt(IV) as [PtCl$$_{6}$$]$$^{2-}$$ from hydrochloric acid using a simple urea extractant

Ueda, Yuki; Morisada, Shintaro*; Kawakita, Hidetaka*; Wenzel, M.*; Weigand, J. J.*; Oto, Keisuke*

Separation and Purification Technology, 277, p.119456_1 - 119456_8, 2021/12

 Times Cited Count:5 Percentile:30.31(Engineering, Chemical)

no abstracts in English

Journal Articles

Reports of electropolishing implementation for quarter-wave resonators

Nii, Keisuke*; Ida, Yoshiaki*; Ueda, Hideki*; Yamaguchi, Takanori*; Kabumoto, Hiroshi; Kamiya, Junichiro; Kondo, Yasuhiro; Tamura, Jun; Harada, Hiroyuki; Matsui, Yutaka; et al.

Proceedings of 18th Annual Meeting of Particle Accelerator Society of Japan (Internet), p.334 - 337, 2021/10

no abstracts in English

241 (Records 1-20 displayed on this page)