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Journal Articles

Specific cooperative effect of a macrocyclic receptor for metal ion transfer into an ionic liquid

Okamura, Hiroyuki; Ikeda, Atsushi*; Saito, Takumi*; Aoyagi, Noboru; Naganawa, Hirochika; Hirayama, Naoki*; Umetani, Shigeo*; Imura, Hisanori*; Shimojo, Kojiro

Analytical Chemistry, 84(21), p.9332 - 9339, 2012/11

 Times Cited Count:23 Percentile:62.59(Chemistry, Analytical)

Journal Articles

Cooperative intramolecular interaction of diazacrown ether bearing $$beta$$-diketone fragments on an ionic liquid extraction system

Shimojo, Kojiro; Okamura, Hiroyuki; Hirayama, Naoki*; Umetani, Shigeo*; Imura, Hisanori*; Naganawa, Hirochika

Dalton Transactions, 2009(25), p.4850 - 4852, 2009/07

A novel extractant $$beta$$-diketone-substituted diaza-18-crown-6 demonstrated very efficient extraction of Sr$$^{2+}$$ due to an intramolecular synergistic effect on the ionic liquid extraction system and recovery of Sr$$^{2+}$$ from the ionic liquid was successfully achieved under acidic conditions.

Journal Articles

Comparison of four bidentate phosphoric and diamide compounds for the extractability of actinides

Sasaki, Yuji; Umetani, Shigeo*

Journal of Nuclear Science and Technology, 43(7), p.794 - 797, 2006/07

 Times Cited Count:11 Percentile:60.35(Nuclear Science & Technology)

Using four bidentate phosphonate and diamide ligands (L), the extraction of Am(III), Th(IV), Np(V) and U(VI) was studied and their extraction species and extractability in these extractants were discussed. The extractant containing the phosphoric oxygen has stronger chelation than that with the carbonyl oxygen atoms. The molar ratios in the main chemical forms extracted are 1:3 for Am:L, 1:1 for Th:L and Np:L and 1:2 for U:L from the relationship between log D(An) and log [L]. The order of D in actinides with the different oxidation states is U(VI) $$>$$ Th(IV) $$>$$ Am(III) $$>$$ Np(V), which shows the different order from that for HDEHP and HTTA, namely Th(IV) $$>$$ U(VI) $$>$$ Am(III) $$>$$ Np(V). It is clear that BDPPM, a diphosphoric dioxide extractant, has high extractability towards all An used here.

Oral presentation

Extractability of diamides and organophosphorus oxides for actinides

Sasaki, Yuji; Kimura, Takaumi; Umetani, Shigeo*

no journal, , 

no abstracts in English

Oral presentation

Extraction behavior of lanthanides with a diamide ligand into ionic liquids

Kurahashi, Kensuke; Shimojo, Kojiro; Naganawa, Hirochika; Umetani, Shigeo*; Sorin, Yoshiki*

no journal, , 

no abstracts in English

Oral presentation

Extraction behavior of lanthanides into ionic liquids using a diamide-type ligand TODGA

Kurahashi, Kensuke; Shimojo, Kojiro; Naganawa, Hirochika; Umetani, Shigeo*; Sorin, Yoshiki*

no journal, , 

no abstracts in English

Oral presentation

Intramolecular synergistic effect in ionic liquid extraction system of metal ions

Okamura, Hiroyuki; Shimojo, Kojiro; Hirayama, Naoki*; Umetani, Shigeo*; Imura, Hisanori*; Naganawa, Hirochika

no journal, , 

no abstracts in English

Oral presentation

Intramolecular synergistic extraction using crown ether bearing b-diketone fragments in an ionc liquid

Okamura, Hiroyuki; Shimojo, Kojiro; Hirayama, Naoki*; Umetani, Shigeo*; Imura, Hisanori*; Naganawa, Hirochika

no journal, , 

no abstracts in English

Oral presentation

Intramolecular synergy effect of crown ether bearing b-diketone fragments and development of ionic liquids extraction system

Shimojo, Kojiro; Okamura, Hiroyuki; Hirayama, Naoki*; Umetani, Shigeo*; Imura, Hisanori*; Naganawa, Hirochika

no journal, , 

no abstracts in English

Oral presentation

Intramolecular synergistic effect on an ionic liquid extraction system using crown ether bearing $$beta$$-diketone fragments

Okamura, Hiroyuki; Shimojo, Kojiro; Hirayama, Naoki*; Umetani, Shigeo*; Imura, Hisanori*; Naganawa, Hirochika

no journal, , 

no abstracts in English

Oral presentation

Structure analysis of complex extracted into an ionic liquid with X-ray absorption spectroscopy

Okamura, Hiroyuki; Shimojo, Kojiro; Ikeda, Atsushi; Hirayama, Naoki*; Umetani, Shigeo*; Imura, Hisanori*; Naganawa, Hirochika

no journal, , 

no abstracts in English

Oral presentation

Intramolecular synergistic effect on ionic liquid extraction system with crownn ether bearing $$beta$$-diketone fragments

Shimojo, Kojiro; Okamura, Hiroyuki; Ikeda, Atsushi; Saito, Takumi*; Hirayama, Naoki*; Umetani, Shigeo*; Imura, Hisanori*; Naganawa, Hirochika

no journal, , 

no abstracts in English

Oral presentation

Effective extraction of strontium(II) into an ionic liquid by cooperative intramolecular interaction

Okamura, Hiroyuki; Shimojo, Kojiro; Ikeda, Atsushi*; Saito, Takumi*; Aoyagi, Noboru; Hirayama, Naoki*; Umetani, Shigeo*; Imura, Hisanori*; Naganawa, Hirochika

no journal, , 

13 (Records 1-13 displayed on this page)
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