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Journal Articles

Origin of magnetically dead layers in spinel ferrites $$M$$Fe$$_2$$O$$_4$$ grown on Al$$_2$$O$$_3$$; Effects of postdeposition annealing studied by XMCD

Nonaka, Yosuke*; Wakabayashi, Yuki*; Shibata, Goro; Sakamoto, Shoya*; Ikeda, Keisuke*; Chi, Z.*; Wan, Y.*; Suzuki, Masahiro*; Tanaka, Arata*; Tanaka, Masaaki*; et al.

Physical Review Materials (Internet), 7(4), p.044413_1 - 044413_10, 2023/04

 Times Cited Count:0 Percentile:0(Materials Science, Multidisciplinary)

Journal Articles

Production of $$^{266}$$Bh in the $$^{248}$$Cm($$^{23}$$Na,5$$n$$)$$^{266}$$Bh reaction and its decay properties

Haba, Hiromitsu*; Fan, F.*; Kaji, Daiya*; Kasamatsu, Yoshitaka*; Kikunaga, Hidetoshi*; Komori, Yukiko*; Kondo, Narumi*; Kudo, Hisaaki*; Morimoto, Koji*; Morita, Kosuke*; et al.

Physical Review C, 102(2), p.024625_1 - 024625_12, 2020/08

 Times Cited Count:6 Percentile:59.56(Physics, Nuclear)

Journal Articles

Complex chemistry with complex compounds

Eichler, R.*; Asai, Masato; Brand, H.*; Chiera, N. M.*; Di Nitto, A.*; Dressler, R.*; D$"u$llmann, Ch. E.*; Even, J.*; Fangli, F.*; Goetz, M.*; et al.

EPJ Web of Conferences, 131, p.07005_1 - 07005_7, 2016/12

 Times Cited Count:3 Percentile:72.98(Chemistry, Inorganic & Nuclear)

In recent years gas-phase chemical studies assisted by physical pre-separation allowed for the productions and investigations of fragile single molecular species of superheavy elements. The latest highlight is the formation of very volatile hexacarbonyl compound of element 106, Sg(CO)$$_{6}$$. Following this success, second-generation experiments were performed to measure the first bond dissociation energy between the central metal atom and the surrounding ligand. The method using a tubular decomposition reactor was developed and successfully applied to short-lived Mo(CO)$$_{6}$$, W(CO)$$_{6}$$, and Sg(CO)$$_{6}$$.

Journal Articles

Decomposition studies of group 6 hexacarbonyl complexes, 1; Production and decomposition of Mo(CO)$$_6$$ and W(CO)$$_6$$

Usoltsev, I.*; Eichler, R.*; Wang, Y.*; Even, J.*; Yakushev, A.*; Haba, Hiromitsu*; Asai, Masato; Brand, H.*; Di Nitto, A.*; D$"u$llmann, Ch. E.*; et al.

Radiochimica Acta, 104(3), p.141 - 151, 2016/03

 Times Cited Count:31 Percentile:95.03(Chemistry, Inorganic & Nuclear)

Conditions of the production and decomposition of hexacarbonyl complexes of short-lived Mo and W isotopes were investigated to study thermal stability of the heaviest group 6 hexacarbonyl complex Sg(CO)$$_6$$. A tubular flow reactor was tested to decompose the hexacarbonyl complexes and to extract the first bond dissociation energies. A silver was found to be the most appropriate reaction surface to study the decomposition of the group 6 hexacarbonyl. It was found that the surface temperature at which the decomposition occurred was correlated to the first bond dissociation energy of Mo(CO)$$_6$$ and W(CO)$$_6$$, indicating that the first bond dissociation energy of Sg(CO)$$_6$$ could be determined with this technique.

Journal Articles

In situ synthesis of volatile carbonyl complexes with short-lived nuclides

Even, J.*; Ackermann, D.*; Asai, Masato; Block, M.*; Brand, H.*; Di Nitto, A.*; D$"u$llmann, Ch. E.*; Eichler, R.*; Fan, F.*; Haba, Hiromitsu*; et al.

Journal of Radioanalytical and Nuclear Chemistry, 303(3), p.2457 - 2466, 2015/03

 Times Cited Count:15 Percentile:77.56(Chemistry, Analytical)

Rapid In situ synthesis of metal carbonyl complexes has been demonstrated using short-lived isotopes produced in nuclear fission and fusion reactions. The short-lived isotopes with high recoil energy directly react with carbon-monoxides and form carbonyl complexes. Only highly volatile complexes were fast transported in a gas stream to counting and chemistry devices. Short-lived Mo, Tc, Ru, Rh, W, Re, Os, and Ir were found to form volatile carbonyl complexes, while no volataile complex of Hf and Ta were detected. This technique has been applied to a chemical investigation of the superheavy element Sg (atomic number 106), and will be applicable to various fields of nuclear science with short-lived transition metal isotopes.

Journal Articles

Synthesis and detection of a Seaborgium carbonyl complex

Even, J.*; Yakushev, A.*; D$"u$llmann, Ch. E.*; Haba, Hiromitsu*; Asai, Masato; Sato, Tetsuya; Brand, H.*; Di Nitto, A.*; Eichler, R.*; Fan, F. L.*; et al.

Science, 345(6203), p.1491 - 1493, 2014/09

 Times Cited Count:63 Percentile:83.28(Multidisciplinary Sciences)

A new superheavy element complex, a seaborgium carbonyl, has been successfully synthesized, and its adsorption property has been studied using a cryo-thermochromatography and $$alpha$$-detection apparatus COMPACT. Nuclear reaction products of short-lived $$^{265}$$Sg preseparated with a gas-filled recoil ion separator GARIS at RIKEN were directly injected into a gas cell filled with He/CO mixture gas, and chemical reaction products of volatile carbonyl complexes were trasported to COMPACT. The Sg carbonyl complex detected with COMPACT was found to be very volatile with adsorption enthalpy of $$-$$50 kJ/mol, from which we have concluded that this complex should be a Sg hexacarbonyl Sg(CO)$$_{6}$$. This is the first synthesis of organometallic compounds of transactinide elements for which only simple inorganic comounds have been synthesized so far.

Journal Articles

The Rectal temperature estimation method based on tympanic temperature for workers wearing protective clothing in nuclear facilities

Takahashi, Naoki; Lee, J.-Y.*; Wakabayashi, Hitoshi*; Tochihara, Yutaka*

Hoken Butsuri, 47(1), p.54 - 65, 2012/03

no abstracts in English

Journal Articles

Prediction and verification of rectal temperature from measured infrared tympanic temperature in workers wearing impermeable protective clothing in nuclear facilities

Takahashi, Naoki; Lee, J.-Y.*; Wakabayashi, Hitoshi*; Tochihara, Yutaka*

Proceedings of 4th International Conference on Human-Environment System (ICHES 2011) (USB Flash Drive), p.745 - 750, 2011/10

no abstracts in English

Journal Articles

Prediction and verification of rectal temperature from measured infrared tympanic temperature in workers wearing impermeable protective clothing in nuclear facilities

Takahashi, Naoki; Lee, J.-Y.*; Wakabayashi, Hitoshi*; Tochihara, Yutaka*

Nihon Seiri Jinrui Gakkai-Shi, 16(Suppl.1), p.92 - 93, 2011/06

no abstracts in English

Journal Articles

Study of stellar reactions in explosive hydrogen burning with CRIB

Kubono, Shigeru*; Teranishi, Takashi*; Notani, Masahiro*; Yamaguchi, Hidetoshi*; Saito, Akito*; He, J. J.*; Wakabayashi, Yasuo*; Fujikawa, Hisashi*; Amadio, G.*; Baba, Hidetada*; et al.

Nuclear Physics A, 758, p.733 - 736, 2005/07

 Times Cited Count:1 Percentile:14.45(Physics, Nuclear)

With using $$^{17}F$$ RNB from CRIB, proton inelastic scattering was observed. From this experiment, some resonance parameters have been deduced for the key reaction, $$^{14}O(alpha,p)^{17}F$$ at the explosive hydrogen burning stage in stars. Proton inelastic scattering of $$^{23}Mg$$ are also reported.

Oral presentation

Inventive methods and examinations to decrease body stress of nuclear plant workers wearing protective clothes

Takahashi, Naoki; Isomae, Hidemi; Kurita, Tsutomu; Yoshimoto, Katsunobu; Takahashi, Yoshiharu*; Nago, Toshihide*; Tochihara, Yutaka*; Wakabayashi, Hitoshi*; Lee, J.-Y.*

no journal, , 

no abstracts in English

Oral presentation

Development and operational results of a real-time remote biological information monitoring device for the workers wearing protective clothes at a nuclear facility

Takahashi, Naoki; Lee, J.-Y.*; Wakabayashi, Hitoshi*; Tochihara, Yutaka*

no journal, , 

Workers must wear a protective clothing to prevent contamination by radioactive materials when carrying out certain inspection and maintenance activities at nuclear facilities. Temperature and humidity increase with time within the protective clothing during such work. This is because the protective clothing is necessarily impermeable so that heat and perspiration caused by physical labor remain. Therefore, the worker's body temperature and related heatstroke risk gradually increase. We developed remote biological information monitoring device and use it under actual working conditions.

Oral presentation

Heat stroke remote monitoring technology for the workers wearing impermeable protective clothing in the nuclear facility

Takahashi, Naoki; Kobayashi, Daisuke; Yoshimoto, Katsunobu; Lee, J.-Y.*; Wakabayashi, Hitoshi*; Tochihara, Yutaka*; Yamada, Minoru*; Tanaka, Hideki*

no journal, , 

no abstracts in English

13 (Records 1-13 displayed on this page)
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