Experimental study on modeling of Pu sorption onto quartz

Hemmi, Ko; Walker, A.*; Yamaguchi, Tetsuji

Radiochimica Acta, 109(7), p.539 - 546, 2021/07

https://doi.org/10.1515/ract-2020-0068

Plutonium(IV) sorption onto quartz in carbonate solutions was systematically investigated under anaerobic conditions to analyze the sorption behaviors of Pu(IV) with a non-electrostatic model (NEM). Pu(IV) sorption data was obtained from batch sorption experiments as a function of pH and carbonate concentration. The Pu(IV) sorption onto quartz showed similar tendencies to Th(IV), which is considered to be chemically analogous as a tetravalent actinoid. The distribution coefficient, d, of Pu(IV) onto quartz showed inverse proportionality to the square of the total carbonate concentration under the investigated pH conditions of 8 to 11. The modeling study, however, revealed a Th(IV) sorption model, which is SOTh(OH) and SOThOH(CO), could not be applied to simulate the Pu(IV) sorption onto quartz. It was inferred that the electrostatic repulsion between negatively charged ligands limited the formation of SOM(OH) and SOMOH(CO) for Pu(IV) with smaller ionic radii than Th(IV). The Pu(IV) sorption model was developed as SOPu(OH) and SOPu(OH). In addition, data of Pu(IV) sorption onto muscovite was obtained in order to be compared with data for quartz.

Systematic measurements and analyses for lead void reactivity worth in a plutonium core and two uranium cores with different enrichments

Fukushima, Masahiro; Goda, J.*; Oizumi, Akito; Bounds, J.*; Cutler, T.*; Grove, T.*; Hayes, D.*; Hutchinson, J.*; McKenzie, G.*; McSpaden, A.*; et al.

Nuclear Science and Engineering, 194(2), p.138 - 153, 2020/02

https://doi.org/10.1080/00295639.2019.1663089

To validate lead (Pb) nuclear cross sections, a series of integral experiments to measure lead void reactivity worth was conducted systematically in three fast spectra with different fuel compositions on the Comet critical assembly of the National Criticality Experiments Research Center. Previous experiments in a high-enriched uranium (HEU)/Pb and a low-enriched uranium (LEU)/Pb systems had been performed in 2016 and 2017, respectively. A follow-on experiment in a plutonium (Pu)/Pb system has been completed. The Pu/Pb system was constructed using lead plates and weapons grade plutonium plates that had been used in the Zero Power Physics Reactor (ZPPR) of Argonne National Laboratory until the 1990s. Furthermore, the HEU/Pb system was re-examined on the Comet critical assembly installed newly with a device that can guarantee the gap reproducibility with a higher accuracy and precision, and then the experimental data was re evaluated. Using the lead void reactivity worth measured in these three cores with different fuel compositions, the latest nuclear data libraries, JENDL 4.0 and ENDF/B VIII.0, were tested with the Monte Carlo calculation code MCNP version 6.1. As a result, the calculations by ENDF/B-VIII.0 were confirmed to agree with lead void reactivity worth measured in all the cores. It was furthermore found that the calculations by JENDL 4.0 overestimate by more than 20% for the Pu/Pb core while being in good agreements for the HEU/Pb and LEU/Pb cores.

Port-based plasma diagnostic infrastructure on ITER

Pitcher, C. S.*; Barnsley, R.*; Bertalot, L.*; Encheva, A.*; Feder, R.*; Friconneau, J. P.*; Hu, Q.*; Levesy, B.*; Loesser, G. D.*; Lyublin, B.*; et al.

Fusion Science and Technology, 64(2), p.118 - 125, 2013/08

https://doi.org/10.13182/FST13-A18065

The port-based plasma diagnostic infrastructure on ITER is described, including the port plugs, the interspace support structure and port cell structure. These systems are modular in nature with standardized dimensions. The design of the equatorial and upper port plugs and their modules is discussed, as well as the dominant loading mechanisms. The port infrastructure design has now matured to the point that port plugs are now being populated with multiple diagnostics supplied by a number of ITER partners - two port plug examples are given.

Nuclear technology aspects of ITER vessel-mounted diagnostics

Vayakis, G.*; Bertalot, L.*; Encheva, A.*; Walker, C.*; Brichard, B.*; Cheon, M. S.*; Chitarin, G.*; Hodgson, E.*; Ingesson, C.*; Ishikawa, Masao; et al.

Journal of Nuclear Materials, 417(1-3), p.780 - 786, 2011/10

https://doi.org/10.1016/j.jnucmat.2011.01.081

Plasma boundary and first-wall diagnostics in ITER

Pitcher, C. S.*; Andrew, P.*; Barnsley, R.*; Bertalot, L.*; Counsell, G. G.*; Encheva, A.*; Feder, R. E.*; Hatae, Takaki; Johnson, D. W.*; Kim, J.*; et al.

Journal of Nuclear Materials, 415(Suppl.1), p.S1127 - S1132, 2011/08

https://doi.org/10.1016/j.jnucmat.2011.01.111

Identified charged hadron production in collisions at = 200 and 62.4 GeV

Adare, A.*; Afanasiev, S.*; Aidala, C.*; Ajitanand, N. N.*; Akiba, Yasuyuki*; Al-Bataineh, H.*; Alexander, J.*; Aoki, Kazuya*; Aphecetche, L.*; Armendariz, R.*; et al.

Physical Review C, 83(6), p.064903_1 - 064903_29, 2011/06

https://doi.org/10.1103/PhysRevC.83.064903

Transverse momentum distributions and yields for , and in collisions at = 200 and 62.4 GeV at midrapidity are measured by the PHENIX experiment at the RHIC. We present the inverse slope parameter, mean transverse momentum, and yield per unit rapidity at each energy, and compare them to other measurements at different collisions. We also present the scaling properties such as and scaling and discuss the mechanism of the particle production in collisions. The measured spectra are compared to next-to-leading order perturbative QCD calculations.

Overview of high priority ITER diagnostic systems status

Walsh, M.*; Andrew, P.*; Barnsley, R.*; Bertalot, L.*; Boivin, R.*; Bora, D.*; Bouhamou, R.*; Ciattaglia, S.*; Costley, A. E.*; Counsell, G.*; et al.

Proceedings of 23rd IAEA Fusion Energy Conference (FEC 2010) (CD-ROM), 8 Pages, 2011/03

http://www-naweb.iaea.org/napc/physics/FEC/FEC2010/html/node50.htm#12730

Neutron-proton pairing competition in nuclei; Metastable state decays in the proton dripline nuclei Nb and Tc

Garnsworthy, A. B.*; Regan, P. H.*; Cceres, L.*; Pietri, S.*; Sun, Y.*; Rudolph, D.*; Grska, M.*; Podolyk, Z.*; Steer, S. J.*; Hoischen, R.*; et al.

Physics Letters B, 660(4), p.326 - 330, 2008/02

https://doi.org/10.1016/j.physletb.2008.01.017

The low-lying structures of the self-conjugate () nuclei Nb and Tc have been investigated using isomeric-decay spectroscopy following the projectile fragmentation of a Ag beam. These represent the heaviest odd-odd nuclei in which internal decays have been identified to date. The resulting level schemes shed light on the shape evolution along the line between the doubly-magic systems Ni and Sn and support a preference for states in odd-odd nuclei at low excitation energies associated with a neutron-proton pairing gap. Comparison with Projected Shell Model calculations suggests that the decay in Nb may be interpreted as an isospin-changing isomer.

Recent results in fragmentation isomer spectroscopy with rising

Pietri, S.*; Regan, P. H.*; Podolyk, Zs.*; Rudolph, D.*; Steer, S. J.*; Garnsworthy, A. B.*; Werner-Malento, E.*; Hoischen, R.*; Grska, M.*; Gerl, J.*; et al.

Nuclear Instruments and Methods in Physics Research B, 261(1-2), p.1079 - 1083, 2007/08

https://doi.org/10.1016/j.nimb.2007.04.219

The first results from the stopped beam RISING experimental campaign performed at the GSI laboratory in Darmstadt, Germany, are presented. RISING constitutes a major new experimental program in European nuclear structure physics research aimed at using relativistic energy (typically around 1 GeV per nucleon) projectile fragmentation reactions to populate nuclei with highly exotic proton-to-neutron ratios compared to the line of beta stability. In its high-efficiency stopped beam configuration, the RISING -ray spectrometer consists of 105 individual germanium crystals which view a focal plane in which the exotic nuclei are brought to rest. Here, decays from metastable states with half-lives in the nano to milliseconds range can be observed. Results of initial commissioning experiments are also shown and details of the planned future experimental program are given.

Isomer spectroscopy using relativistic projectile fragmentation at the N=Z line for A8090

Regan, P. H.*; Garnsworthy, A. B.*; Pietri, S.*; Caceres, L.*; Grska, M.*; Rudolph, D.*; Podolyk, Zs.*; Steer, S. J.*; Hoischen, R.*; Gerl, J.*; et al.

Nuclear Physics A, 787(1), p.491c - 498c, 2007/05

https://doi.org/10.1016/j.nuclphysa.2006.12.073

Relativistic energy projectile fragmentation of Pb has been used to produce neutron-rich nuclei with N126. The nuclei of interest were studied by detecting delayed rays following the decay of isomeric states. Experimental information on the excited states of the neutron-rich Pt N=126 nucleus, following internal decay of two isomeric states, was obtained for the first time. Raw experimental data and shell-model calculations are presented.