High-efficiency synthesis and properties of latent pigment red 272DPP-BOC by microwave irradiation

Oishi, Tomoji*; Kimura, Yu*; Nakajima, Kiyohiko*; Watanabe, Masayuki; Aoyagi, Noboru

Materials Sciences and Applications, 11(3), p.195 - 203, 2020/03

https://doi.org/10.4236/msa.2020.113013

A high-efficiency synthesis method for a latent pigment of red pigment diketo-pyrrolo-pyrrole (Pig. Red 272:272DPP), which is important as a functional organic pigment, was investigated, and the investigation results revealed that irradiation of microwaves (MWs) for several seconds to 272 DPP in NMP (N-methyl-2-pyrrolidone) solvent yielded DPP latent pigment (272DPP-BOC) at a high yield of 86.2%. Two kinds of latent-pigment crystals, namely, red and yellow, were obtained by recrystallization, and it was found that the fluorescence-emission properties of the two kinds differ significantly. Single-crystal X-ray structural analysis showed that the difference in the fluorescence-emission properties of the two types is derived from the difference in their crystal structures.

Highlight of recent sample environment at J-PARC MLF

Kawamura, Seiko; Hattori, Takanori; Harjo, S.; Ikeda, Kazutaka*; Miyata, Noboru*; Miyazaki, Tsukasa*; Aoki, Hiroyuki; Watanabe, Masao; Sakaguchi, Yoshifumi*; Oku, Takayuki

Neutron News, 30(1), p.11 - 13, 2019/05

https://doi.org/10.1080/10448632.2019.1605790

In Japanese neutron scattering facilities, some SE equipment that are frequently used at an instrument, such as the closed-cycle refrigerator (CCR), have been prepared for the instrument as standard SE. They are operated for user experiments by the instrument group. The advantage of this practice is that they can optimize the design of the SE for the instrument and can directly respond to users' requests. On the other hand, the SE team in the Materials and Life Science Experimental Facility (MLF) in J-PARC has managed commonly used SE to allow neutron experiments with more advanced SE. In this report, recent SE in the MLF is introduced. Highlighted are the SE in BL11, BL19, BL21 and BL17 and other SE recently progressed by the SE team.

Progress in long-pulse production of powerful negative ion beams for JT-60SA and ITER

Kojima, Atsushi; Umeda, Naotaka; Hanada, Masaya; Yoshida, Masafumi; Kashiwagi, Mieko; Tobari, Hiroyuki; Watanabe, Kazuhiro; Akino, Noboru; Komata, Masao; Mogaki, Kazuhiko; et al.

Nuclear Fusion, 55(6), p.063006_1 - 063006_9, 2015/06

https://doi.org/10.1088/0029-5515/55/6/063006

Significant progresses in the extension of pulse durations of powerful negative ion beams have been made to realize the neutral beam injectors for JT-60SA and ITER. In order to overcome common issues of the long pulse production/acceleration of negative ion beams in JT-60SA and ITER, the new technologies have been developed in the JT-60SA ion source and the MeV accelerator in Japan Atomic Energy Agency. As for the long pulse production of high-current negative ions for JT-60SA ion source, the pulse durations have been successfully increased from 30 s at 13 A on JT-60U to 100 s at 15 A by modifying the JT-60SA ion source, which satisfies the required pulse duration of 100 s and 70% of the rated beam current for JT-60SA. This progress was based on the R&D efforts for the temperature control of the plasma grid and uniform negative ion productions with the modified tent-shaped filter field configuration. Moreover, the each parameter of the required beam energy, current and pulse has been achieved individually by these R&D efforts. The developed techniques are useful to design the ITER ion source because the sustainment of the cesium coverage in large extraction area is one of the common issues between JT-60SA and ITER. As for the long pulse acceleration of high power density beams in the MeV accelerator for ITER, the pulse duration of MeV-class negative ion beams has been extended by more than 2 orders of magnitude by modifying the extraction grid with a high cooling capability and a high-transmission of negative ions. A long pulse acceleration of 60 s has been achieved at 70 MW/m (683 keV, 100 A/m) which has reached to the power density of JT-60SA level of 65 MW/m.

Report for "FY 2013 Evaluation of Decontamination Technology Demonstrations Projects for the environmental remediation with radioactive materials discharged from the Fukushima Daiichi Nuclear Power Plant Accident" (Contract research)

Watanabe, Masahisa; Tagawa, Akihiro; Umemiya, Noriko; Maruyama, Noboru; Yoshida, Mami; Kawase, Keiichi; Noguchi, Shinichi; Sakazume, Yoshinori; Watanabe, Masanori; Hiraga, Hayato; et al.

JAEA-Review 2014-028, 184 Pages, 2014/10

JAEA-Review-2014-028.pdf:37.79MB

JAEA received technical proposals from private enterprise about techniques that can be used for decontamination work, and "Decontamination Technology Demonstrations Projects" was commissioned from the Ministry of the Environment to verifies the decontamination effect, economy feasibility, safety, and other factors. By the "FY 2013 Decontamination Technology Demonstrations Projects" JAEA carried out technical advice of demonstration test and evaluation of 11 technologies (e.g., decontamination of soils and green space and wastes and washing of fly ash).

Progress in development and design of the neutral beam injector for JT-60SA

Hanada, Masaya; Kojima, Atsushi; Tanaka, Yutaka; Inoue, Takashi; Watanabe, Kazuhiro; Taniguchi, Masaki; Kashiwagi, Mieko; Tobari, Hiroyuki; Umeda, Naotaka; Akino, Noboru; et al.

Fusion Engineering and Design, 86(6-8), p.835 - 838, 2011/10

https://doi.org/10.1016/j.fusengdes.2011.04.068

Neutral beam (NB) injectors for JT-60 Super Advanced (JT-60SA) have been designed and developed. Twelve positive-ion-based and one negative-ion-based NB injectors are allocated to inject 30 MW D beams in total for 100 s. Each of the positive-ion-based NB injector is designed to inject 1.7 MW for 100s at 85 keV. A part of the power supplies and magnetic shield utilized on JT-60U are upgraded and reused on JT-60SA. To realize the negative-ion-based NB injector for JT-60SA where the injection of 500 keV, 10 MW D beams for 100s is required, R&Ds of the negative ion source have been carried out. High-energy negative ion beams of 490-500 keV have been successfully produced at a beam current of 1-2.8 A through 20% of the total ion extraction area, by improving voltage holding capability of the ion source. This is the first demonstration of a high-current negative ion acceleration of 1 A to 500 keV. The design of the power supplies and the beamline is also in progress. The procurement of the acceleration power supply starts in 2010.

Achievement of 500 keV negative ion beam acceleration on JT-60U negative-ion-based neutral beam injector

Kojima, Atsushi; Hanada, Masaya; Tanaka, Yutaka*; Kawai, Mikito*; Akino, Noboru; Kazawa, Minoru; Komata, Masao; Mogaki, Kazuhiko; Usui, Katsutomi; Sasaki, Shunichi; et al.

Nuclear Fusion, 51(8), p.083049_1 - 083049_8, 2011/08

https://doi.org/10.1088/0029-5515/51/8/083049

Hydrogen negative ion beams of 490 keV, 3 A and 510 keV, 1 A have been successfully produced in the JT-60 negative ion source with three acceleration stages. These successful productions of the high-energy beams at high current have been achieved by overcoming the most critical issue, i.e., a poor voltage holding of the large negative ion sources with the grids of 2 m for JT-60SA and ITER. To improve voltage holding capability, the breakdown voltages for the large grids was examined for the first time. It was found that a vacuum insulation distance for the large grids was 6-7 times longer than that for the small-area grid (0.02 m). From this result, the gap lengths between the grids were tuned in the JT-60 negative ion source. The modification of the ion source also realized a significant stabilization of voltage holding and a short conditioning time. These results suggest a practical use of the large negative ion sources in JT-60SA and ITER.

Demonstration of 500 keV beam acceleration on JT-60 negative-ion-based neutral beam injector

Kojima, Atsushi; Hanada, Masaya; Tanaka, Yutaka*; Kawai, Mikito*; Akino, Noboru; Kazawa, Minoru; Komata, Masao; Mogaki, Kazuhiko; Usui, Katsutomi; Sasaki, Shunichi; et al.

Proceedings of 23rd IAEA Fusion Energy Conference (FEC 2010) (CD-ROM), 8 Pages, 2011/03

http://www-naweb.iaea.org/napc/physics/FEC/FEC2010/html/node294.htm#62473

Hydrogen negative ion beams of 490keV, 3A and 510 keV, 1A have been successfully produced in the JT-60 negative ion source with three acceleration stages. These successful productions of the high-energy beams at high current have been achieved by overcoming the most critical issue, i.e., a poor voltage holding of the large negative ion sources with the grids of 2 m for JT-60SA and ITER. To improve voltage holding capability, the breakdown voltages for the large grids was examined for the first time. It was found that a vacuum insulation distance for the large grids was 6-7 times longer than that for the small-area grid (0.02 m). From this result, the gap lengths between the grids were tuned in the JT-60 negative ion source. The modification of the ion source also realized a significant stabilization of voltage holding and a short conditioning time. These results suggest a practical use of the large negative ion sources in JT-60 SA and ITER.

Development and design of the negative-ion-based NBI for JT-60 Super Advanced

Hanada, Masaya; Akino, Noboru; Endo, Yasuei; Inoue, Takashi; Kawai, Mikito; Kazawa, Minoru; Kikuchi, Katsumi; Komata, Masao; Kojima, Atsushi; Mogaki, Kazuhiko; et al.

Journal of Plasma and Fusion Research SERIES, Vol.9, p.208 - 213, 2010/08

http://www.jspf.or.jp/JPFRS/PDF/Vol9/jpfrs2010_09-207.pdf

A large negative ion source with an ion extraction area of 110 cm 45 cm has been developed to produce 500 keV, 22 A D ion beams required for JT-60 Super Advanced. To realize the JT-60SA negative ion source, the JT-60 negative ion source has been modified and tested on the negative-ion-based neutral beam injector on JT-60U. A 500 keV H ion beam has been produced at 3 A without a significant degradation of beam optics. This is the first demonstration of a high energy negative ion acceleration of more than one-ampere to 500 keV in the world. The beam current density of 90 A/m is being increased to meet 130 A/m of the design value for JT-60SA by tuning the operation parameters. A long pulse injection of 30 s has been achieved at a injection D power of 3 MW. The injection energy, defined as the product of the injection time and power, reaches 80 MJ by neutralizing a 340 keV, 27 A D ion beam produced with two negative ion sources.

Distinctive features in neutronic performance of JSNS

Maekawa, Fujio; Oikawa, Kenichi; Harada, Masahide; Teshigawara, Makoto; Kai, Tetsuya; Kasugai, Yoshimi; Meigo, Shinichiro; Oi, Motoki; Futakawa, Masatoshi; Watanabe, Noboru*; et al.

Proceedings of 19th Meeting of the International Collaboration on Advanced Neutron Sources (ICANS-19) (CD-ROM), 8 Pages, 2010/07

Efforts have been made to characterize neutronic performance of JSNS. A NOBORU instrument was mainly used for this purpose while some other instruments were used when needed. The followings were confirmed. (1) Judging from a measured spectral shape, a para-hydrogen fraction in the hydrogen moderator was very close to unity as expected due to introduction of catalyst in a hydrogen circulation system. (2) Measured data for absolute spectral intensity and pulse shapes agreed very well with simulation calculations, and suggested adequacy of the neutron source designs. (3) The world's highest resolution of 0.035 % was recorded at the powder diffractometer SuperHRPD. (4) A total neutron flux of 3 10n/s/cm was confirmed at the chopper instrument 4SEASONS when it was normalized to 1 MW. The flux is the world's highest among existing spallation neutron sources, and is comparable to fluxes at intense reactor sources even in time-averaged value.

Imaging experiments on NOBORU at MLF

Harada, Masahide; Oikawa, Kenichi; Oi, Motoki; Kai, Tetsuya; Sakai, Kenji; Maekawa, Fujio; Watanabe, Noboru*; Shinohara, Takenao; Takata, Shinichi

Proceedings of 19th Meeting of the International Collaboration on Advanced Neutron Sources (ICANS-19) (CD-ROM), 10 Pages, 2010/07

A neutron beam line NOBORU built at MLF in J-PARC is suitable for imaging experiments due to a large beam size, a short distance from the moderator to the sample position and an adequate experimental room. In order to evaluate suitability for the imaging experiments, we measured neutron spectral intensities and flux distributions at the sample position of NOBORU. We also measured those quantities with use of some filters, collimators and slits equipped on NOBORU. As preliminary experiments for imaging, we measured Bragg edge transmission of some alloys and resonance absorption of some elements. The result showed welded and non-welded areas in an alloy could be clearly distinguished by the Bragg edge transmission. It was also found that several elements in the sample could be distinguished clearly by the resonance absorption method. It could be concluded that NOBORU was very suitable for the imaging experiments at J-PARC.