Latent ion tracks were finally observed in diamond

Amekura, Hiroshi*; Chettah, A.*; Narumi, Kazumasa*; Chiba, Atsuya*; Hirano, Yoshimi*; Yamada, Keisuke*; Yamamoto, Shunya*; Leino, A. A.*; Djurabekova, F.*; Nordlund, K.*; et al.

Nature Communications (Internet), 15, p.1786_1 - 1786_10, 2024/02

https://doi.org/10.1038/s41467-024-45934-4

Injecting high-energy heavy ions in the electronic stopping regime into solids can create cylindrical damage zones called latent ion tracks. Although these tracks form in many materials, none have ever been observed in diamond, even when irradiated with high-energy GeV uranium ions. Here we report the first observation of ion track formation in diamond irradiated with 2-9 MeV C fullerene ions. Depending on the ion energy, the mean track length (diameter) changed from 17 (3.2) nm to 52 (7.1) nm. High resolution scanning transmission electron microscopy (HR-STEM) indicated the amorphization in the tracks, in which -bonding signal from graphite was detected by the electron energy loss spectroscopy (EELS).

Neutron reflectivity study on the suppression of interfacial water accumulation between a polypropylene thin film and Si substrate using a silane-coupling agent

Shimokita, Keisuke*; Yamamoto, Katsuhiro*; Miyata, Noboru*; Arima-Osonoi, Hiroshi*; Nakanishi, Yohei*; Takenaka, Mikihito*; Shibata, Motoki*; Yamada, Norifumi*; Seto, Hideki*; Aoki, Hiroyuki; et al.

Langmuir, 38(41), p.12457 - 12465, 2022/10

https://doi.org/10.1021/acs.langmuir.2c01599

Sodium-cooled Fast Reactors

Ohshima, Hiroyuki; Morishita, Masaki*; Aizawa, Kosuke; Ando, Masanori; Ashida, Takashi; Chikazawa, Yoshitaka; Doda, Norihiro; Enuma, Yasuhiro; Ezure, Toshiki; Fukano, Yoshitaka; et al.

Sodium-cooled Fast Reactors; JSME Series in Thermal and Nuclear Power Generation, Vol.3, 631 Pages, 2022/07

https://shop.elsevier.com/books/sodium-cooled-fast-reactors/morishita/978-0-12-824076-2

This book is a collection of the past experience of design, construction, and operation of two reactors, the latest knowledge and technology for SFR designs, and the future prospects of SFR development in Japan. It is intended to provide the perspective and the relevant knowledge to enable readers to become more familiar with SFR technology.

Measurements of intensity of produced light in water during irradiations of electron beams with energies above and below the Cerenkov-light threshold

Yamamoto, Seiichi*; Nagao, Yuto*; Kurita, Keisuke; Yamaguchi, Mitsutaka*; Kawachi, Naoki*

Journal of Instrumentation (Internet), 16(1), p.P01007_1 - P01007_9, 2021/01

https://doi.org/10.1088/1748-0221/16/01/P01007

Luminescence of water during irradiation with particles having energies below the Cerenkov-light threshold was recently found for various types of radiations. However, the relation between the intensities of Cerenkov light and of the luminescence of water at the beam energy below the Cherenkov threshold is not well known. To clarify this point, we measured the produced light irradiating a water sample with electron beams having maximum energies above and below the Cerenkov-light threshold.

Neutron reflectivity on the mobile surface and immobile interfacial layers in the poly(vinyl acetate) adsorption layer on a Si substrate with deuterated toluene vapor-induced swelling

Miyazaki, Tsukasa*; Shimokita, Keisuke*; Yamamoto, Katsuhiro*; Aoki, Hiroyuki; Yamada, Norifumi*; Miyata, Noboru*

Langmuir, 36(49), p.15181 - 15188, 2020/12

https://doi.org/10.1021/acs.langmuir.0c03025

Defect structure analysis of heterointerface between Pt and CeO promoter on Pt electro-catalyst

Fugane, Keisuke*; Mori, Toshiyuki*; Yan, P.*; Masuda, Takuya*; Yamamoto, Shunya; Ye, F.*; Yoshikawa, Hideki*; Auchterlonie, G.*; Drennan, J.*

ACS Applied Materials & Interfaces, 7(4), p.2698 - 2707, 2015/02

https://doi.org/10.1021/am507754w

no abstracts in English

Accurate structure analyses of polymer crystals on the basis of wide-angle X-ray and neutron diffractions

Tashiro, Koji*; Hanesaka, Makoto*; Yamamoto, Hiroko*; Wasanasuk, K.*; Jayaratri, P.*; Yoshizawa, Yoshinori*; Tanaka, Ichiro*; Niimura, Nobuo*; Kusaka, Katsuhiro*; Hosoya, Takaaki*; et al.

Kobunshi Rombunshu, 71(11), p.508 - 526, 2014/11

https://doi.org/10.1295/koron.71.508

The crystal structure analysis of various polymer substances has been reviewed on the basis of wide-angle high-energy X-ray and neutron diffraction data. The progress in structural analytical techniques of polymer crystals have been reviewed at first. The structural models proposed so far were reinvestigated and new models have been proposed for various kinds of polymer crystals including polyethylene, poly(vinyl alcohol), poly(lactic acid) and its stereocomplex etc. The hydrogen atomic positions were also clarified by the quantitative analysis of wide-angle neutron diffraction data, from which the physical properties of polymer crystals have been evaluated theoretically. The bonded electron density distribution has been estimated for a polydiacetylene single crystal on the basis of the so-called X-N method or by the combination of structural information derived from X-ray and neutron diffraction data analysis. Some comments have been added about future developments in the field of structure-property relationship determination.

A Study of the generation of U in UO and MOX fuels

Yamamoto, Kento; Okumura, Keisuke

Journal of Nuclear Science and Technology, 51(4), p.568 - 573, 2014/04

https://doi.org/10.1080/00223131.2014.882803

To clarify the generation pathway of U in burned fuels, which is an important nuclide for dose evaluation at various stages in fuel cycle, concentrations of U generated through various pathways were evaluated for UO and MOX fuels at 45 GWd/t using the ORIGEN2.2 code. It was found that the difference of U concentrations in UO and MOX fuel are mainly derived from the difference of the initial compositions of U, U and U and the contribution of plutonium and americium isotopes in MOX fuels is not so large compared with that of uranium isotopes. The results clarified that the capture cross sections of Th, Pa, U and U and (,2) cross sections of Np and U have a large effect on generation of U. The additional investigation showed that not only time after irradiation but also time before irradiation has a strong effect on U concentration.

Sorption of Eu(III) on granite; EPMA, LA-ICP-MS, batch and modeling studies

Fukushi, Keisuke*; Hasegawa, Yusuke*; Maeda, Koshi*; Aoi, Yusuke*; Tamura, Akihiro*; Arai, Shoji*; Yamamoto, Yuhei*; Aosai, Daisuke*; Mizuno, Takashi

Environmental Science & Technology, 47(22), p.12811 - 12818, 2013/11

https://doi.org/10.1021/es402676n

Eu(III) sorption on granite was examined by the combined microscopic and macroscopic approaches. Polished thin sections of the granite were reacted with solutions containing 10 M of Eu(III) and analyzed using EPMA and LA-ICP-MS. The Eu enrichment up to 6 wt.% was observed on most of the biotite grains. The Eu-enriched parts commonly lose K, which is the interlayer cation of biotite, indicating that the sorption mode is cation exchange in the interlayer. Batch Eu(III) sorption experiments on granite and biotite powders were conducted. The macroscopic sorption behavior of biotite was consistent with that of granite. The obtained sorption edges can be reproduced reasonably by the modeling considering single-site cation exchange reactions. Granite is complex mineral assemblages. However, the combined microscopic and macroscopic approaches revealed that elementary reactions by single phase can be representative for the bulk sorption reaction in complex mineral assemblages.

Estimation of groundwater recharge rate and spatial distribution of hydrological quantities in surface hydrogeological investigation basin of Horonobe URL Project; From December 2004 to November 2009

Yamamoto, Yoichi; Maekawa, Keisuke; Yokota, Hideharu; Yamazaki, Masanori

JAEA-Research 2011-042, 97 Pages, 2012/02

JAEA-Research-2011-042.pdf:11.05MB

The surface hydrogeological investigation has been carried out in and around the Horonobe Underground Research Laboratory area as a part of Horonobe URL project. Observations of meteorological, river flux, water quality, soil moisture and groundwater level have been continued in order to understand the groundwater recharge rate and groundwater flow in the shallow part, which are required for the setting of boundary and initial condition of the groundwater flow analysis. This report shows the summary of the surface hydrogeological investigation and results of recharge rates of investigation basins from December 2004 to November 2009 are calculated by using the water budget method. Spatial estimation of hydrological quantities for the groundwater recharge rate is demonstrated by the runoff analysis. As a result, average of the groundwater recharge rate of whole basins is estimated to 131mm/yr. Suggestive observations related to hydraulic properties of the geology and faults are obtained from consideration to the groundwater recharge rate for each basin.