Controlling the dissociative ionization of ethanol with 800 and 400 nm two-color femtosecond laser pulses

Yazawa, Hiroki*; Shioyama, Tadamasa*; Suda, Yoshitaka*; Yamanaka, Mio*; Kannari, Fumihiko*; Itakura, Ryuji; Yamanouchi, Kaoru*

Journal of Chemical Physics, 127(12), p.124312_1 - 124312_5, 2007/09

https://doi.org/10.1063/1.2780156

Ethanol molecules were irradiated with a pair of temporally overlapping ultrashort intense laser pulses (10-10 W/cm with different colors of 400 and 800 nm, and the dissociative ionization processes have been investigated. The yield ratio of the C-O bond breaking with respect to the C-C bond breaking was varied in the range of 0.17-0.53 sensitively depending on the delay time between the two laser pulses, and the absolute value of the yield of the C-O bond breaking was found to be increased largely when the Fourier-transform limited 800 nm laser pulse overlaps the stretched 400 nm laser pulse, demonstrating an advantage of the two-color intense laser fields in controlling chemical bond breaking processes.