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Okubo, Takahiro*; Yamazaki, Akio*; Fukatsu, Yuta; Tachi, Yukio
Microporous and Mesoporous Materials, 313, p.110841_1 - 110841_11, 2021/01
Times Cited Count：5 Percentile：29.65(Chemistry, Applied)Pore distributions in water-saturated Ca-montmorillonite were investigated using 
H NMR measurements under various dry densities (0.8 - 1.6 g/cm
) and porewater salinity conditions (deionized water, 0.1 and 1 M CaCl
), at the temperature range of 233 - 303 K. The volume fractions of the interlayer pore including two and three hydrated layers and the non-interlayer pore in compacted Ca-montmorillonite were quantified by NMR relaxometry including 
and 
distribution analysis, and were compared with NMR cryoporometry and X-ray diffractometry. These analysis provided consistent pictures on the pore distributions in compacted Ca-montmorillonite, in contrast to Na-montmorillonite. The main factor affecting the pore distribution in compacted Ca- and Na-montmorillonite is the density, whereas the effect of porewater salinity is relatively smaller. The effect of interlayer cations is also relatively smaller at higher density, although the differences in the pore structures are significant at low density.
Matsukado, Koji*; Esirkepov, T. Z.; Kinoshita, Kenichi*; Daido, Hiroyuki; Utsumi, Takayuki*; Li, Z.*; Fukumi, Atsushi*; Hayashi, Yukio; Orimo, Satoshi; Nishiuchi, Mamiko; et al.
Physical Review Letters, 91(21), p.215001_1 - 215001_4, 2003/11
Times Cited Count：136 Percentile：95.25(Physics, Multidisciplinary)no abstracts in English
Yoshinaga, Makio; Nakamura, Takehiko; Yamazaki, Toshi*
JAERI-Tech 2000-017, p.59 - 0, 2000/03
JAERI-Tech-2000-017.pdf:2.31MB
no abstracts in English
Yamazaki, Akio*; Okubo, Takahiro*; Iwadate, Yasuhiko*; Tachi, Yukio
no journal, ,
A structural analysis of water-filled pores in saturated compacted sodium montmorillonite was conducted by 1H NMR spectroscopy. The pore structure including interlayer and intraparticle pores in compacted montmorillonite was characterized by relaxation time and freezing point observed by 1H NMR and their correlations with water-filled pore sizes.
Yamazaki, Akio*; Okubo, Takahiro*; Iwadate, Yasuhiko*; Tachi, Yukio
no journal, ,
A structural analysis of water-filled pores in saturated compacted Ca-type montmorillonite was conducted by 1H NMR spectroscopy. The pore structure including interlayer and intraparticle pores in Ca-type compacted montmorillonite was characterized by relaxation time observed by 1H NMR and their correlations with water-filled pore sizes.
