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Yanagisawa, Kayo*; Odashima, Mizuki*; Matsueda, Makoto; Furukawa, Makoto*; Takagai, Yoshitaka*
Talanta, 244, p.123442_1 - 123442_7, 2022/07
Times Cited Count:1 Percentile:59.33(Chemistry, Analytical)The determination of a low concentration of Sr was achieved by the combination of online SPE-ICP-QMS and ID method using
Sr/
Sr ratio. No requirement of radioactive standard material and the preparation process of the calibration curve was in the quantification process and data acquisition can be in one-shot sample injection. The proposed method allowed the rapid (within 15 min/sample) quantification of
Sr in the presence of significant interferences such as isobaric
Zr and other elements. The LOD for
Sr was 5.6 Bq/L for a 10 mL injection and this could be improved by simply increasing the sample volume injected.
Koarai, Kazuma; Matsueda, Makoto; Aoki, Jo; Yanagisawa, Kayo*; Fujiwara, Kenso; Terashima, Motoki
KEK Proceedings 2021-2, p.140 - 145, 2021/12
Strontium-90 and Y, its daughter nuclide, adverse effects on the bone marrow. Monitoring of
Sr in the bones have been required after the Fukushima-Daiichi Nuclear Power Plant accident. However, conventional radioactivity measurement method for
Sr requires a complicated separation of
Y and a time-consuming measurement. ICP-MS system has been applied to
Sr concentration survey of water, soil, and edible part of fish. We developed measurement method of
Sr with ICP-MS and applied the method for cattle bones. We determined
Sr in the hard tissues of animals that collected in the Fukushima prefecture. Limit of detection in the measurement was 19 Bq/kg.
Koarai, Kazuma; Matsueda, Makoto; Aoki, Jo; Yanagisawa, Kayo*; Terashima, Motoki; Fujiwara, Kenso; Kino, Yasushi*; Oka, Toshitaka; Takahashi, Atsushi*; Suzuki, Toshihiko*; et al.
Journal of Analytical Atomic Spectrometry, 36(8), p.1678 - 1682, 2021/08
Times Cited Count:2 Percentile:44.59(Chemistry, Analytical)Rapid analysis of Sr in bone and tooth samples of cattle were achieved by an inductively coupled plasma mass spectrometry (ICP-MS) coupled with mass shift and solid phase extraction techniques. Limit of detection (LOD) in the ICP-MS measurement of 0.1 g samples was lower than that of the radioactivity measurement. Analytical time of the ICP-MS method was reduced from 20 days to 11 hours, compared with the radiometric method. Therefore, the ICP-MS method can be rapid and useful procedure of
Sr in small bone and tooth samples derived from terrestrial animals.
Matsueda, Makoto; Yanagisawa, Kayo*; Koarai, Kazuma; Terashima, Motoki; Fujiwara, Kenso; Abe, Hironobu; Kitamura, Akihiro; Takagai, Yoshitaka*
ACS Omega (Internet), 6(29), p.19281 - 19290, 2021/07
Times Cited Count:1 Percentile:15.16(Chemistry, Multidisciplinary)Online solid-phase extraction-inductively coupled plasma-quadrupole mass spectrometry with oxygen dynamic reaction cell (online SPE-ICP-MS-DRC) was shown to be a thorough automatic analytical system, circumventing the need for human handling. At three stepwise separations (SPE-DRC-Q mass filters), we showed that interference materials allowed the coexistence of abundance ratios of 1.510
for
Tc/Mo. Using this optimized system, a detection limit of
Tc was 9.3 pg/L (5.9 mBq/L) for a 50 mL injection and sequential measurements were undertaken at a cycle of 24 min/sample.
Koarai, Kazuma; Matsueda, Makoto; Aoki, Jo; Yanagisawa, Kayo*; Fujiwara, Kenso; Terashima, Motoki; Kitamura, Akihiro; Abe, Hironobu
KEK Proceedings 2020-4, p.180 - 185, 2020/11
Strontium-90 and Y, its daughter nuclide, adverse effects on the bone marrow. Monitoring of
Sr in the bones have been required after the Fukushima-Daiichi Nuclear Power Plant accident. However, conventional radioactivity measurement method for
Sr requires a complicated separation of
Y and a time-consuming measurement. ICP-MS system has been applied to
Sr concentration survey of water, soil, and edible part of fish. We applied the ICP-MS system for the bones for the first time. In this study, reference bone (JSAC 0785 fish bone) was used as measurement samples. Sample preparation of the bone was performed using a microwave digestion instrument. After sample preparation,
Sr was determined using ICP-MS system with cascade separation steps based on on-line column separation and oxygen reaction. Strontium-90 in the bones was successfully separated from Ca, Ba, Y, Zr, Fe, Se, and Ge, which interfered in ICP-MS measurement, in the separation steps.
Yanagisawa, Kayo*; Matsueda, Makoto; Furukawa, Makoto*; Takagai, Yoshitaka*
Analytical Sciences, 36(9), p.1131 - 1135, 2020/09
Times Cited Count:4 Percentile:33.36(Chemistry, Analytical)In this paper, we propose an online water infusion system for rapid quantification of radioactive strontium-90 (Sr) with inductively coupled plasma mass spectrometry coupled solid-phase extraction and O
dynamic reaction (cascade ICP-MS). The proposed system automatically provides a higher dilution ratio, which is at most 3.3 times the ratio obtained by the previous method, without increasing the analysis time (within 15 min). A detection limit of 2.7 Bq/kg wet (0.54 pg/kg wet) was achieved. The recovery test results were consistent with two different spiked values.
Fujiwara, Kenso; Yanagisawa, Kayo*; Iijima, Kazuki
Environmental Radiochemical Analysis VI, p.89 - 96, 2019/09
Since Strontium-90 (Sr-90) is one of the high yield and hazardous fission products, accurate and low-level detection of Sr-90 is essential for environmental samples. Especially, in case of nuclear power plant accidents, rapid and precise assessment of Sr-90 for environmental monitoring and health physics is required. In order to evaluate the migration of radionuclides in the environment, not only Sr-90 in water but also those in soil and biological samples should be measured. A new method for rapid quantification of Sr-90 by online solid phase extraction coupled with inductively coupled plasma mass spectrometry (SPE-ICP-MS) has been developed. In this method, it is unavoidable to eliminate the interference by polyatomic ion (e.g., ArCa, Ca) induced by isotopes and matrices in fishes and soil. In this study, SPE-ICP-MS method was applied to the measurement of Sr-90 in fishes, and the influence of the Sr isotopes and coexisting ions such as Ca was evaluated.
Saegusa, Jun; Yanagisawa, Kayo; Hasumi, Atsushi; Shimizu, Takenori; Uchida, Yoshiaki*
Radiation Physics and Chemistry, 137, p.210 - 215, 2017/08
Times Cited Count:1 Percentile:11.8(Chemistry, Physical)Following the Fukushima Daiichi Nuclear Power Plant (NPP) accident, large-scale radiation monitoring and environmental clean-up activities have been conducted throughout the Fukushima region. Outside air temperatures there reach 40C in summer and -20
C in winter, which are beyond the quoted range of many radiation survey instruments. For the purpose, temperature performances of four types of portable Japanese survey instruments which are widely used in Fukushima were experimentally investigated with a temperature-controlled chamber.
Saegusa, Jun; Yanagisawa, Kayo; Yamaguchi, Toshio; Manabe, Sachi; Yoda, Tomoyuki; Maeda, Satoshi; Utsumi, Azusa; Shibamichi, Masaru; Ejiri, Akira; Kurita, Yoshiyuki; et al.
no journal, ,
no abstracts in English
Kuwata, Haruka*; Hagiwara, Hiroki; Yanagisawa, Kayo; Manabe, Sachi*; Takeishi, Minoru; Watanabe, Hitoshi; Uezu, Yasuhiro
no journal, ,
no abstracts in English
Yanagisawa, Kayo*; Kuwata, Haruka*; Hagiwara, Hiroki; Uezu, Yasuhiro
no journal, ,
no abstracts in English
Kuwata, Haruka*; Hagiwara, Hiroki; Yanagisawa, Kayo*; Manabe, Sachi*; Takeishi, Minoru; Watanabe, Hitoshi; Uezu, Yasuhiro
no journal, ,
Hagiwara, Hiroki; Yanagisawa, Kayo*; Kuwata, Haruka*; Tanabe, Tsutomu; Uezu, Yasuhiro
no journal, ,
no abstracts in English
Fujiwara, Kenso; Yanagisawa, Kayo*; Iijima, Kazuki
no journal, ,
Since Sr-90 is one of the high yield and hazardous fission products, accurate and low-level detection of Sr-90 is essential for environmental samples. Especially, in case of nuclear power plant accidents, rapid and precise assessment of Sr-90 for environmental monitoring and health physics is required. In order to evaluate the migration of radionuclides in the environment, not only Sr-90 in water but also those in soil and biological samples should be measured. A new method for rapid quantification of Sr-90 by online solid phase extraction coupled with inductively coupled plasma mass spectrometry (SPE-ICP-MS) has been developed. In this method, it is unavoidable to eliminate the interference by polyatomic ion (e.g., ArCa, Ca) induced by isotopes and matrices in fishes and soil. In this study, SPE-ICP-MS method was applied to the measurement of Sr-90 in fishes, and the influence of the Sr isotopes and coexisting ions such as Ca was evaluated.
Matsueda, Makoto; Yanagisawa, Kayo*; Fujiwara, Kenso; Kitamura, Akihiro
no journal, ,
Strontium-90 (Sr) is one of the fission products and required a long time in the conventional radioactivity analysis (about a month). Therefore, we introduced the mass spectrometry analysis system combined inductively coupled plasma mass spectrometry (ICP-MS) and pretreatment units to determine
Sr more quickly. This system was mainly used for low matrix samples such as rainwater, but this time we report the measurement results of
Sr in fishes containing a lot of matrix (such as calcium).
Koarai, Kazuma; Matsueda, Makoto; Yanagisawa, Kayo*; Fujiwara, Kenso; Kitamura, Akihiro
no journal, ,
Strontium-90 and Y, its daughter nuclide, adverse effects on the bone marrow. Monitring of
Sr have been required after the Fukushima-Daiichi Nuclear Power Plant. However, radioactivity measurement method requires a complicated separation and a time-consuming
-ray measurement. ICP-MS system has been applied to
Sr contamination survey of soil and water samples. We applied the ICP-MS system for the bones for the first time. In this study, reference bone was used as measurement samples. After sample preparation,
Sr was determined using ICP-MS system with cascade separation steps based on on-line column separation and oxygen reaction. Strontium-90 in the bones was successfully separated from Ca, Ba, Y, Zr, Fe, and Ge, which interfered in ICP-MS measurement, in the separation steps. We found that the ICP-MS system could be applied to the rapid measurement of
Sr in the bones.
Koarai, Kazuma; Matsueda, Makoto; Yanagisawa, Kayo*; Fujiwara, Kenso; Kitamura, Akihiro
no journal, ,
Strontium-90 (Sr) is one of an artificial radionuclide after the Fukushima-Daiichi Nuclear Power Plant accident. The ICP-MS system for
Sr have been developed. The ICP-MS system could apply to measurement of
Sr in soils and water. In this study, solid phase extraction method of
Sr was optimized the ICP-MS system for bones. After MW digestion, fish bone was dissolved in 2.6 M nitric acid. Sr resin was used for solid phase extraction of
Sr in a flow-injection system. Sr and interference elements were determined with ICP-MS. Chemical yield of Sr was over 90% in the solid phase extraction system. Interference elements were removed in the extraction. The extraction method could applied to the ICP-MS system for
Sr. The method required only 30 minutes. The ICP-MS system would be rapid method for
Sr measurement in bones.
Matsueda, Makoto; Koarai, Kazuma; Yanagisawa, Kayo*; Fujiwara, Kenso; Kitamura, Akihiro
no journal, ,
Sr-90 accumulates in hard tissues such as bones and teeth in the case of uptake into the human or animal bodies. Therefore, the analysis of these hard tissues from the viewpoint of exposure evaluation has required, but the conventional radioactivity analysis requires a period of about one month, it is difficult to process a large number of samples. From this thing, we tried to apply application of the online solid phase extraction/ICP-MS method which can be measured quickly compared to radioactivity analysis. This method has mainly been utilizing as the analysis of Sr-90 contained in the water samples such as rainwater, and it has already equipped the correction functions corresponding to the shift of recovery rate at the Sr resin and the sensitivity shift in ICP-MS. However, hard tissues contain a large amount of matrix. Therefore, we investigated whether the isobaric interference, stable Sr, and other high matrix influence to Sr-90 values and attempted to correct the values.
Koarai, Kazuma; Matsueda, Makoto; Aoki, Jo; Yanagisawa, Kayo*; Fujiwara, Kenso; Terashima, Motoki; Kitamura, Akihiro; Abe, Hironobu
no journal, ,
Strontium-90 and Y, its daughter nuclide, adverse effects on the bone marrow. Monitoring of
Sr in the bones have been required after the Fukushima-Daiichi Nuclear Power Plant accident. However, conventional radioactivity measurement method for
Sr requires a complicated separation of
Y and a time-consuming measurement. ICP-MS system has been applied to
Sr concentration survey of water, soil, and edible part of fish. We applied the ICP-MS system for the bones. We determined
Sr in the hard tissues of animals that collected in the Fukushima prefecture. Limit of detection in the measurement was 19 Bq/kg.
Koarai, Kazuma; Matsueda, Makoto; Aoki, Jo; Yanagisawa, Kayo*; Fujiwara, Kenso; Terashima, Motoki; Kino, Yasushi*; Oka, Toshitaka; Okutsu, Kenichi*; Yamashita, Takuma*; et al.
no journal, ,
We demonstrated a method of Sr measurement in small pieces of hard tissues with radioactivity measurement or ICP-MS measurement. Interference elements of the measurements were removed by chemical separation. We could determine
Sr in 0.1 g of hard tissues by radioactivity measurement method and ICP-MS method. Limit of detection of the ICP-MS method was lower than that of the radioactivity measurement. The ICP-MS method is adequate method for distribution analysis of
Sr in the hard tissues.