Radiation chemistry provides nanoscopic insights into the role of intermediate phases in CeO mesocrystal formation

Li, Z.*; Piankova, D.*; Yang, Y.*; Kumagai, Yuta; Zschiesche, H.*; Jonsson, M.*; Tarakina, N. V.*; Soroka, I. L.*

Angewandte Chemie; International Edition, 61(6), p.e202112204_1 - e202112204_9, 2022/02

https://doi.org/10.1002/anie.202112204

The role of intermediate phases in CeO mesocrystal formation from aqueous Ce(III) solutions subjected to -radiation was studied. Radiolytically formed hydroxyl radicals convert soluble Ce(III) into less soluble Ce(IV). Transmission electron microscopy and X-ray diffraction studies of samples from different stages of the process allowed the identification of several stages in CeO mesocrystal evolution following the oxidation to Ce(IV): (1) formation of hydrated Ce(IV)-hydroxides, serving as intermediates in the liquid-to-solid phase transformation; (2) CeO primary particle growth inside the intermediate phase; (3) alignment of the primary particles into "pre-mesocrystals" and subsequently to mesocrystals, guided by confinement of the amorphous intermediate phase and accompanied by the formation of mineral bridges. Further alignment of the obtained mesocrystals into supracrystals occurs upon slow drying, making it possible to form complex hierarchical architectures.

Investigation of the ground-state spin inversion in the neutron-rich Cl isotopes

Linh, B. D.*; Corsi, A.*; Gillibert, A.*; Obertelli, A.*; Doornenbal, P.*; Barbieri, C.*; Chen, S.*; Chung, L. X.*; Duguet, T.*; Gmez-Ramos, M.*; et al.

Physical Review C, 104(4), p.044331_1 - 044331_16, 2021/10

https://doi.org/10.1103/PhysRevC.104.044331

no abstracts in English

New -emitting isotope U and abnormal enhancement of -particle clustering in lightest uranium isotopes

Zhang, Z. Y.*; Yang, H. B.*; Andreyev, A. N.; Liu, M. L.*; Ma, L.*; 37 of others*

Physical Review Letters, 126(15), p.152502_1 - 152502_6, 2021/04

https://doi.org/10.1103/PhysRevLett.126.152502

Suppressed lattice disorder for large emission enhancement and structural robustness in hybrid lead iodide perovskite discovered by high-pressure isotope effect

Kong, L.*; Gong, J.*; Hu, Q.*; Capitani, F.*; Celeste, A.*; Hattori, Takanori; Sano, Asami; Li, N.*; Yang, W.*; Liu, G.*; et al.

Advanced Functional Materials, 31(9), p.2009131_1 - 2009131_12, 2021/02

https://doi.org/10.1002/adfm.202009131

The soft nature of organic-inorganic halide perovskites renders their lattice particularly tunable to external stimuli such as pressure, undoubtedly offering an effective way to modify their structure for extraordinary optoelectronic properties. However, these soft materials meanwhile feature a general characteristic that even a very mild pressure will lead to detrimental lattice distortion and weaken the critical light-matter interaction, thereby triggering the performance degradation. Here, using the methylammonium lead iodide as a representative exploratory platform, we observed the pressure-driven lattice disorder can be significantly suppressed via hydrogen isotope effect, which is crucial for better optical and mechanical properties previously unattainable.

= 32 shell closure below calcium; Low-lying structure of Ar

Corts, M. L.*; Rodriguez, W.*; Doornenbal, P.*; Obertelli, A.*; Holt, J. D.*; Menndez, J.*; Ogata, Kazuyuki*; Schwenk, A.*; Shimizu, Noritaka*; Simonis, J.*; et al.

Physical Review C, 102(6), p.064320_1 - 064320_9, 2020/12

https://doi.org/10.1103/PhysRevC.102.064320

Low-lying excited states in the = 32 isotope Ar were investigated by in-beam -ray spectroscopy following proton- and neutron-knockout, multinucleon removal, and proton inelastic scattering at the RIKEN Radioactive Isotope Beam Factory. The energies of the two previously reported transitions have been confirmed, and five additional states are presented for the first time, including a candidate for a 3 state. The level scheme built using coincidences was compared to shell-model calculations in the model space and to predictions based on chiral two- and three-nucleon interactions. Theoretical proton- and neutron-knockout cross sections suggest that two of the new transitions correspond to 2 states, while the previously proposed 4 state could also correspond to a 2 state.

Spallation and fragmentation cross sections for 168 MeV/nucleon Xe ions on proton, deuteron, and carbon targets

Sun, X. H.*; Wang, H.*; Otsu, Hideaki*; Sakurai, Hiroyoshi*; Ahn, D. S.*; Aikawa, Masayuki*; Fukuda, Naoki*; Isobe, Tadaaki*; Kawakami, Shunsuke*; Koyama, Shumpei*; et al.

Physical Review C, 101(6), p.064623_1 - 064623_12, 2020/06

https://doi.org/10.1103/PhysRevC.101.064623

The spallation and fragmentation reactions of Xe induced by proton, deuteron and carbon at 168 MeV/nucleon were studied at RIKEN Radioactive Isotope Beam Factory via the inverse kinematics technique. The cross sections of the lighter products are larger in the carbon-induced reactions due to the higher total kinetic energy of carbon. The energy dependence was investigated by comparing the newly obtained data with previous results obtained at higher reaction energies. The experimental data were compared with the results of SPACS, EPAX, PHITS and DEURACS calculations. These data serve as benchmarks for the model calculations.

Fine structure in the decay of U

Sun, M. D.*; Liu, Z.*; Huang, T. H.*; Zhang, W. Q.*; Andreyev, A. N.; Ding, B.*; Wang, J. G.*; Liu, X. Y.*; Lu, H. Y.*; Hou, D. S.*; et al.

Physics Letters B, 800, p.135096_1 - 135096_5, 2020/01

https://doi.org/10.1016/j.physletb.2019.135096

Identifying the and as -wave bottom baryons of

Cui, E.-L.*; Yang, H.-M.*; Chen, H.-X.*; Hosaka, Atsushi

Physical Review D, 99(9), p.094021_1 - 094021_15, 2019/05

https://doi.org/10.1103/PhysRevD.99.094021

Molecular binding sites are located near the interface of intrinsic dynamics domains (IDDs)

Li, H.*; Sakuraba, Shun; Chandrasekaran, A.*; Yang, L.-W.*

Journal of Chemical Information and Modeling, 54(8), p.2275 - 2285, 2014/08

https://doi.org/10.1021/ci500261z

We provide evidence supporting that protein-protein and protein-ligand docking poses are functions of protein shape and intrinsic dynamics. Over sets of 68 protein-protein complexes and 240 non-homologous enzymes, we recognize common predispositions for binding sites to have minimal vibrations and angular momenta while two interacting proteins orient so as to maximize the angle between their rotation/bending axes (). The findings are then used to define quantitative criteria to filter out docking decoys less likely to be the near-native poses, hence the chances to find near-native hits can be doubled. With the novel approach to partition a protein into `domains' of robust but disparate intrinsic dynamics, 90% of catalytic residues in enzymes can be found within the first 50% of the residues closest to the interface of these dynamics domains. The results suggest an anisotropic rather than isotropic distribution of catalytic residues near the mass centers of enzymes.

Characteristics of the first H-mode discharges in KSTAR

Yoon, S. W.*; Ahn, J.-W.*; Jeon, Y. M.*; Suzuki, Takahiro; Hahn, S. H.*; Ko, W. H.*; Lee, K. D.*; Chung, J. I.*; Nam, Y. U.*; Kim, J.*; et al.

Nuclear Fusion, 51(11), p.113009_1 - 113009_9, 2011/11

https://doi.org/10.1088/0029-5515/51/11/113009

Typical ELMy H-mode discharges have been achieved on the KSTAR tokamak with the combined auxiliary heating of NBI and ECRH. The minimum external heating power required is about 1.1 MW at a line-averaged density higher than 1.410 m and a toroidal field of 2 T. There is a clear indication of the increase of the L-H threshold power at densities lower than . The initial analysis of energy confinement time () predicted that was higher than the prediction of multi-machine scaling laws by a factor 1.4-1.6. However, when the contribution of fast ion confinement to the total energy was taken into account, better agreed with the scaling results. A clear increase of electron and ion temperature in the pedestal was observed in the H-mode phase but the core ion temperature did not change significantly. On the other hand, the toroidal rotation also increased over all radii in the H-mode phase. The measured ELM frequency was from 30-50 Hz and the drop of total energy appeared to be less than 5%. Between large ELM spikes, small/grassy ELMs were also identified when mixed heating of NBI and ECRH was applied.