Fundamental study of perfluoro oil degradative treatment by subcritical water reaction and design of bench-scale equipment

Funakoshi, Tomomasa; Watanabe, So; Arai, Yoichi; Iwamoto, Toshihiro; Watanabe, Masayuki; Nishimoto, Yoshihiro*; Yasuda, Makoto*

Mechanical Engineering Journal (Internet), 11(2), p.23-00445_1 - 23-00445_7, 2024/04

https://doi.org/10.1299/mej.23-00445

Validation of the Be ground-state molecular structure using Be()He triple differential reaction cross-section measurements

Li, P. J.*; Beaumel, D.*; Lee, J.*; Assi, M.*; Chen, S.*; Franchoo, S.*; Gibelin, J.*; Hammache, F.*; Harada, T.*; Kanada-En'yo, Yoshiko*; et al.

Physical Review Letters, 131(21), p.212501_1 - 212501_7, 2023/11

https://doi.org/10.1103/PhysRevLett.131.212501

The cluster structure of the neutron-rich isotope Be has been probed via the () reaction. The triple differential cross-section was extracted and compared to distorted-wave impulse approximation reaction calculations performed in a microscopic framework using the Tohsaki-Horiuchi-Schuck-Rpke wave function and the wave function deduced from Antisymmetrized Molecular Dynamics calculations. The remarkable agreement between calculated and measured cross-sections in both shape and magnitude validates the description of the Be ground-state as a rather compact nuclear molecule.

Interlaboratory comparison of electron paramagnetic resonance tooth enamel dosimetry with investigations of the dose responses of the standard samples

Toyoda, Shin*; Inoue, Kazuhiko*; Yamaguchi, Ichiro*; Hoshi, Masaharu*; Hirota, Seiko*; Oka, Toshitaka; Shimazaki, Tatsuya*; Mizuno, Hideyuki*; Tani, Atsushi*; Yasuda, Hiroshi*; et al.

Radiation Protection Dosimetry, 199(14), p.1557 - 1564, 2023/09

https://doi.org/10.1093/rpd/ncad150

Interlaboratory comparison studies are important for radiation dosimetry in order to demonstrate how the technique is universally available. The set of standard samples are examined in each participating laboratory in the present study. After a set of standard samples together with the samples with unknown doses, which were prepared in the same laboratory as the standard samples, are measured at a participating laboratory, those samples are sent to another participating laboratory for next measurement. There is some small difference observed in the sensitivity (the slope of the dose response line) of the standard samples while the differences in the obtained doses for the samples with unknown doses are rather systematic, implying that the difference is mostly due to the samples but not to measurements.

First observation of O

Kondo, Yosuke*; Achouri, N. L.*; Al Falou, H.*; Atar, L.*; Aumann, T.*; Baba, Hidetada*; Boretzky, K.*; Caesar, C.*; Calvet, D.*; Chae, H.*; et al.

Nature, 620(7976), p.965 - 970, 2023/08

https://doi.org/10.1038/s41586-023-06352-6

no abstracts in English

Intruder configurations in Ne at the transition into the island of inversion; Detailed structure study of Ne

Wang, H.*; Yasuda, Masahiro*; Kondo, Yosuke*; Nakamura, Takashi*; Tostevin, J. A.*; Ogata, Kazuyuki*; Otsuka, Takaharu*; Poves, A.*; Shimizu, Noritaka*; Yoshida, Kazuki; et al.

Physics Letters B, 843, p.138038_1 - 138038_9, 2023/08

https://doi.org/10.1016/j.physletb.2023.138038

Detailed -ray spectroscopy of the exotic neon isotope Ne has been performed using the one-neutron removal reaction from Ne. Based on an analysis of parallel momentum distributions, a level scheme with spin-parity assignments has been constructed for Ne and the negative-parity states are identified for the first time. The measured partial cross sections and momentum distributions reveal a significant intruder p-wave strength providing evidence of the breakdown of the N = 20 and N = 28 shell gaps. Only a weak, possible f-wave strength was observed to bound final states. Large-scale shell-model calculations with different effective interactions do not reproduce the large p-wave and small f-wave strength observed experimentally, indicating an ongoing challenge for a complete theoretical description of the transition into the island of inversion along the Ne isotopic chain.

Development plan for coupling technology between high temperature gas-cooled reactor HTTR and hydrogen production facility, 1; Overview of the HTTR heat application test plan to establish high safety coupling technology

Nomoto, Yasunobu; Mizuta, Naoki; Morita, Keisuke; Aoki, Takeshi; Okita, Shoichiro; Ishii, Katsunori; Kurahayashi, Kaoru; Yasuda, Takanori; Tanaka, Masato; Isaka, Kazuyoshi; et al.

Proceedings of 30th International Conference on Nuclear Engineering (ICONE30) (Internet), 7 Pages, 2023/05

Long and oriented graphene nanoribbon synthesis from well-ordered 10,10'-dibromo-9,9'-bianthracene monolayer on crystalline Au surfaces

Yano, Masahiro; Yasuda, Satoshi; Fukutani, Katsuyuki; Asaoka, Hidehito

RSC Advances (Internet), 13(21), p.14089 - 14096, 2023/05

https://doi.org/10.1039/D2RA07570A

Bottom-up synthesis on metal surfaces has attracted attention for the fabrication of graphene nanoribbons (GNRs) with atomically-precise chemical structures to realize novel electronic devices. However, control of length and orientation on surfaces during GNR synthesis is difficult, thus, achieving longer and aligned GNR growth is a significant challenge. Herein, we report GNR synthesis from a well-ordered dense monolayer on Au crystalline surfaces for long and oriented GNR growth. Scanning tunneling microscopy showed that 10,10'-dibromo-9,9'-bianthracene (DBBA) precursors deposited on Au(111) at room temperature self-assembled into a well-ordered dense monolayer, and the straight molecular wire structure was formed where Br atoms in each precursor were adjacent along the wire axis. The DBBAs in the monolayer were found to be hardly desorbed from the surface under subsequent heating and efficiently polymerize along with the molecular arrangement, resulting in more long and oriented GNR growth compared to the conventional growth method. The result is attributed to be suppression of random diffusion and desorption of the DBBAs on the Au surface during polymerization due to the densely-packed DBBA structure. Additionally, an investigation of the effect of the Au crystalline plane on the GNR growth revealed further anisotropic GNR growth on Au(100) compared to Au(111) due to the stronger interactions of DBBA with Au(100). These findings provide fundamental knowledge for controlling GNR growth from a well-ordered precursor monolayer to achieve more long and oriented GNRs.

Event report of JHPS Symposium 2022

Yasuoka, Yumi*; Fujita, Hiroki; Tsuji, Tomoya; Tsujiguchi, Takakiyo*; Sasaki, Michiya*; Miyazaki, Tomoyuki*; Hashima, Shun*; Yasuda, Hiroshi*; Shimada, Kazumasa; Hirota, Seiko*

Hoken Butsuri (Internet), 57(3), p.146 - 155, 2022/12

https://doi.org/10.5453/jhps.57.146

no abstracts in English

Extended neutron orbital and the shell closure in Ca

Enciu, M.*; Liu, H. N.*; Obertelli, A.*; Doornenbal, P.*; Nowacki, F.*; Ogata, Kazuyuki*; Poves, A.*; Yoshida, Kazuki; Achouri, N. L.*; Baba, Hidetada*; et al.

Physical Review Letters, 129(26), p.262501_1 - 262501_7, 2022/12

https://doi.org/10.1103/PhysRevLett.129.262501

The one-neutron knockout from Ca was performed at 230 MeV/nucleon combined with prompt spectroscopy. The momentum distributions corresponding to the removal of and neutrons were measured. The cross sections are consistent with a shell closure at the neutron number , found as strong as at and in Ca isotopes from the same observables. The analysis of the momentum distributions leads to a difference of the root-mean-square radii of the neutron and orbitals of 0.61(23) fm, in agreement with the modified-shell-model prediction of 0.7 fm suggesting that the large root-mean-square radius of the orbital in neutron-rich Ca isotopes is responsible for the unexpected linear increase of the charge radius with the neutron number.

Efficient hydrogen isotope separation by tunneling effect using graphene-based heterogeneous electrocatalysts in electrochemical hydrogen isotope pumping

Yasuda, Satoshi; Matsushima, Hisayoshi*; Harada, Kenji*; Tanii, Risako*; Terasawa, Tomoo; Yano, Masahiro; Asaoka, Hidehito; Gueriba, J. S.*; Dio, W. A.*; Fukutani, Katsuyuki

ACS Nano, 16(9), p.14362 - 14369, 2022/09

https://doi.org/10.1021/acsnano.2c04655

The fabrication of hydrogen isotope enrichment system is essential for the development of industrial, medical, life science, and nuclear fusion fields, therefore alternative enrichment techniques with high separation factor and economic feasibility have been still explored. Herein, we report the fabrication of heterogeneous electrode with layered structures consisting of palladium and graphene layers for polymer electrolyte membrane electrochemical hydrogen pumping for the hydrogen isotope enrichment. We demonstrated significant bias voltage dependence of hydrogen/deuterium (H/D) separation ability and its high H/D at lower bias voltage. Theoretical analysis also demonstrated that the observed high H/D at low bias voltage stems from hydrogen isotopes tunneling through atomically-thick graphene during the electrochemical reaction, and the bias dependent H/D results in a transition from the quantum tunneling regime to classical over- barrier regime for hydrogen isotopes transfer via the graphene. These findings provide new insight for a novel economical methodology of efficient hydrogen isotope enrichment.