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論文

Complementary layer thickness effects of Q235 and SUS304 layers of multilayered steels for improving of tensile strength and plasticity simultaneously

Lin, Z. M.*; Liu, B. X.*; Ming, K. S.*; 徐 平光; Yin, F. X.*; Zheng, S. J.*

Scripta Materialia, 263, p.116692_1 - 116692_7, 2025/07

 被引用回数:2 パーセンタイル:66.69(Nanoscience & Nanotechnology)

Complementary layer thickness effects on strength and plasticity in Q235 and SUS304 steels provide a novel strategy to realize high strength and high plasticity of heterogeneous Q235/SUS304 multilayered steel. In this work, the tensile deformation behaviors and fracture characteristics of vacuum hot-rolled Q235/SUS304 multilayered steel with various layer thicknesses ranging from 223 $$mu$$m to 5 $$mu$$m were deeply investigated. The tensile strength improved with the reduction of layer thickness, and the uniform elongation were first increasing and then decreasing with the decrease of layer thickness, and the peak value appeared at the layer thickness of 20 $$mu$$m. Interestingly, the fracture elongation forms a high plateau value within the 10$$sim$$20 $$mu$$m range. Further analysis reveals that the severe strain localization in the brittle SUS304 thin layers is delayed by the ductile Q235 layers, which is mainly attributed to the different texture evolution and dislocation configuration characteristics during tensile deformation.

論文

Strong low-energy rattling modes enabled liquid-like ultralow thermal conductivity in a well-ordered solid

Liu, P.-F.*; Li, X.*; Li, J.*; Zhu, J.*; Tong, Z.*; 古府 麻衣子*; 楡井 真実; Xu, J.*; Yin, W.*; Wang, F.*; et al.

National Science Review, 11(12), p.nwae216_1 - nwae216_10, 2024/12

 被引用回数:26 パーセンタイル:91.10(Multidisciplinary Sciences)

Crystalline solids exhibiting inherently low lattice thermal conductivity ($$kappa_{rm L}$$) are of great importance in applications such as thermoelectrics and thermal barrier coatings. However, $$kappa_{rm L}$$ cannot be arbitrarily low and is limited by the minimum thermal conductivity related to phonon dispersions. In this work, we report the liquid-like thermal transport in a well-ordered crystalline CsAg$$_5$$Te$$_3$$, which exhibits an extremely low $$kappa_{rm L}$$ value of $$sim$$ 0.18 Wm$$^{-1}$$K$$^{-1}$$. On the basis of first-principles calculations and inelastic neutron scattering measurements, we find that there are lots of low-lying optical phonon modes at $$sim$$ 3.1 meV hosting the avoided-crossing behavior with acoustic phonons. These strongly localized modes are accompanied by weakly bound rattling Ag atoms with thermally induced large amplitudes of vibrations. Using the two-channel model, we demonstrate that coupling of the particle-like phonon modes and the heat-carrying wave-like phonons is essential for understanding the low $$kappa_{rm L}$$, which is heavily deviated from the $$1/T$$ temperature dependence of the standard Peierls theory. In addition, our analysis indicates that the soft structural framework with liquid-like motions of the fluctuating Ag atoms is the underlying cause that leads to the suppression of the heat conduction in CsAg$$_5$$Te$$_3$$. These factors synergistically account for the ultralow $$kappa_{rm L}$$ value. Our results demonstrate that the liquid-like heat transfer could indeed exist in a well-ordered crystal.

論文

Enhancing mechanical properties of medium Mn steel by warm rolling based on laminated elemental segregation

Chen, H. F.*; Liu, B. X.*; 徐 平光; Fang, W.*; Tong, H. C.*; Yin, F. X.*

Journal of Materials Research and Technology, 32, p.3060 - 3069, 2024/09

 被引用回数:7 パーセンタイル:48.24(Materials Science, Multidisciplinary)

The hot-rolled microstructure of medium Mn steel has coarse grains and severe elemental segregation, resulting in low strength and plasticity. Constructing a multiphase structure, refining the microstructure, and regulating elemental segregation enhance the mechanical properties. In this study, liquid nitrogen treatment created a layered distribution of austenite and martensite. Warm rolling was then used to reduce layer thickness and refine grain structure. After liquid nitrogen and warm rolling treatments, the strength and plasticity of medium Mn steel increased to 1270 MPa and 23.3%, respectively, far exceeding the hot-rolled state (724 MPa, 12.8%). Warm rolling also triggers austenite reverted transformation (ART) and introduces high-density dislocations, further improving austenite stability. This strengthening effect is higher than that from intercritical annealing alone. Improved austenite stability delays the transformation induced plasticity (TRIP) effect, preventing brittle fracture and enhancing deformation coordination between layers, significantly increasing the plastic deformation capacity of medium Mn steel.

論文

The BCC $$rightarrow$$ FCC hierarchical martensite transformation under dynamic impact in FeMnAlNiTi alloy

Li, C.*; Fang, W.*; Yu, H. Y.*; Peng, T.*; Yao, Z. T.*; Liu, W. G.*; Zhang, X.*; 徐 平光; Yin, F.*

Materials Science & Engineering A, 892, p.146096_1 - 146096_11, 2024/02

 被引用回数:7 パーセンタイル:68.83(Nanoscience & Nanotechnology)

The quasi-static superelastic responses and hierarchical martensite transformation from body-centered cubic (BCC) to face-centered cubic (FCC) under dynamic impact in Fe$$_{42}$$Mn$$_{34}$$Al$$_{15}$$Ni$$_{7.5}$$Ti$$_{1.5}$$ alloys were investigated. Polycrystalline and oligocrystalline alloys were produced through solution heat treatment and cyclic heat treatment processes, respectively. The results show the volume fraction of residual martensite for oligocrystalline alloys is lower, which exhibits better superelastic responses compared with polycrystalline alloys. Dynamic impact tests indicate that, despite the weakening of the grain boundary strengthening effect, the ultimate strength of the oligocrystalline alloys closely matches that of the polycrystalline alloys under dynamic impact. The martensite transformation of the FeMnAlNiTi alloy is characterized as hierarchical under dynamic impact, and increasing strain rates and grain sizes can enhance the BCC $$rightarrow$$ FCC martensite transformation, resulting in higher martensite phase fractions for oligocrystalline alloys. The increase in ultimate strength is attributed to the dynamic Hall-Petch effect introduced by more martensite phase interfaces under dynamic impact.

論文

Comparison of nuclear medicine therapeutics targeting PSMA among alpha-emitting nuclides

兼田 加珠子*; 白神 宜史*; 角永 悠一郎*; 渡部 直史*; 大江 一弘*; Yin, X.*; 羽場 宏光*; 白崎 謙次*; 菊永 英寿*; 塚田 和明; et al.

International Journal of Molecular Sciences (Internet), 25(2), p.933_1 - 933_14, 2024/01

 被引用回数:9 パーセンタイル:80.45(Biochemistry & Molecular Biology)

Currently, targeted alpha therapy (TAT) is a new therapy involving the administration of a therapeutic drug that combines a substance of $$alpha$$-emitting nuclides that kill cancer cells and a drug that selectively accumulates in cancer cells. We labeled the compounds targeting prostate specific membrane antigen (PSMA) with $$^{211}$$At and $$^{225}$$Ac. PSMA is a molecule that has attracted attention as a theranostic target for prostate cancer, and several targeted radioligands have already shown therapeutic effects in patients. The results showed that $$^{211}$$At, which has a much shorter half-life, is no less cytotoxic than $$^{225}$$Ac. In $$^{211}$$At labeling, our group has also developed an original method (Shirakami Reaction). We have succeeded in obtaining a highly purified labeled product in a short timeframe using this method.

論文

Stacking fault driven phase transformation in CrCoNi medium entropy alloy

He, H.*; Naeem, M.*; Zhang, F.*; Zhao, Y.*; Harjo, S.; 川崎 卓郎; Wang, B.*; Wu, X.*; Lan, S.*; Wu, Z.*; et al.

Nano Letters, 21(3), p.1419 - 1426, 2021/02

 被引用回数:102 パーセンタイル:97.20(Chemistry, Multidisciplinary)

In CrCoNi, a so-called medium-entropy alloy, an fcc-to-hcp phase transformation has long been anticipated. Here, we report an in situ loading study with neutron diffraction, which revealed a bulk fcc-to-hcp phase transformation in CrCoNi at 15 K under tensile loading. By correlating deformation characteristics of the fcc phase with the development of the hcp phase, it is shown that the nucleation of the hcp phase was triggered by intrinsic stacking faults. The confirmation of a bulk phase transformation adds to the myriads of deformation mechanisms available in CrCoNi, which together underpin the unusually large ductility at low temperatures.

口頭

Deformation texture and dislocation density evolution for multilayer metals with laminate/network interface during in situ tensile deformation

Liu, B. X.*; Lin, Z. M.*; 佐藤 成男*; 徐 平光; Yin, F. X.*

no journal, , 

The warm rolled multilayer steel presents laminate/network coupling interface and ultrafine fiber/ultrafine grain structure. It achieves high strength, high cryogenic Charpy V-notch impact toughness and excellent reverse temperature effect. This is close related to the delamination of heterogeneous interface, ultrafine fiber grains, deformation texture and dislocation density characteristics of multilayer steel. In the study, the in situ neutron diffraction based on iMATERIA was employed to deeply monitor the deformation textrure and dislocation density evolution behavior during tensile deformation of multilayer metals. The Brass {110}$$<$$112$$>$$ texture in the FCC layers and the rotated cube {100}$$<$$110$$>$$ texture in the BCC layers suggest clearly the heterogeneous deformation crystallographic texture evolution behavior of multilayer metals with laminate/network coupling in SUS430/SUS304 steels during tensile deformation. The dislocation density in the BCC phase increases with the tensile deformation but no significant change appears in the FCC phase. The grain size of the BCC layers decreases during the tensile deformation, however, the grain size in FCC phase also decreases during the tensile deformation. Such interesting phenomenon is related to the martensitic transformation of FCC phase induced by the tensile deformation.

口頭

異なる中性子回折装置を用いた鉄鋼材料バルク集合組織の評価と比較

徐 平光; 鈴木 裕士; 目時 直人; 塩田 佳徳; 鈴木 徹也*; Yin, F. X.*; 秋田 貢一

no journal, , 

中性子回折は金属材料のバルク集合組織を測定できるが、測定精度は中性子回折装置に依存している。以前より原子力機構では、中性子応力測定装置RESA, RESAIIを利用することによりバルク材の集合組織測定を行ってきたが、近年の集合組織測定に対するニーズ増加に対応するため、他の回折装置で良好な集合組織測定が可能であるか検討した。多目的単色熱中性子ビームポートMUSASIを利用した集合組織測定を行った結果、集合組織測定実験への応用が十分可能であることを確認した。

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